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Luminescence Regulation of Silver-Thiolate Clusters Protected by 1,2-Dithiolate-o-carborane: 《Chinese Journal of Chemistry》2021年第1期81-86,共6页Li-Juan Liu Thomas C.W.Mak Shuang-Quan Zang; This work was supported by the National Science Fund for Distinguished Young Scholars(No.21825106);the National Natural Science Foundation of China(No.21671175);the Program for Innovative Research Team(in Science and Technology)in Universities of Henan Province(No.19IRTSTHN022)and Zhengzhou University.; Engineering the surface of the metal clusters with the core structure maintained and tuning their luminescence in a wide range is still a challenge in the nanomaterial research.We modified six mono-pyridyl ligands wit...; 关键词：Silver clusters Surface modification 1 2-Dithiolate-o-carborane LUMINESCENCE

Synthesis, Characterization and Electrochemistry of 1,2-Bis(diphenylphosphino)benzene-chelated Diiron Ethane-1,2-dithiolate Tetracarbonyl Complex: 《Chinese Journal of Structural Chemistry》2020年第5期927-932,共6页LIN Hui-Min LI Ao IAO Qi-Min LIU Xu-Feng LI Yu-Long LIU Xing-Hai JIANG Zhong-Qing; supported by the Natural Science Foundation of Zhejiang Province(LY19B020002);National Natural Science Foundation of China(21501124);Science&Technology Department of Sichuan Province(2018JY0235);Education Department of Sichuan Province(18ZA0337);Sichuan University of Science&Engineering(S201910622022)。; In this paper,a novel diiron ethane-1,2-dithiolate complex[Fe2(CO)4{κ2-(Ph2P)2(1,2-C6H4)}(μ-SCH2CH2S)]has been prepared and structurally characterized.Treatment of the parent complex[Fe2(CO)6(μ-SCH2CH2S)]with 1 equ...; 关键词：diiron ethane-1 2-dithiolate [FeFe]-hydrogenases diphosphine ligand X-ray crystallography ELECTROCHEMISTRY

Electronic Structure of Thiolate-bridged Diiron Complexes and a Single-electron Oxidation Reaction＂ A Combination of Experimental and Computational Studies: 《Chinese Journal of Chemistry》2016年第9期919-924,共6页Si Chen Lun Luo Yang Li Dawei Yang Jingping Qu Yi Luo; This work was partly supported by the National Natural Science Foundation of China （Nos. 21429201, 21231003, 21571026）. The authors also thank the Network and Information Center of the Dalian University of Technology for part of the computational resources.; Single-electron oxidation of a diiron-sulfur complex [Cpπ＊Fe（μ-bdt）FeCp^＊] （1, Cp^＊=η^5-C5Me5; bdt = benzene-1,2-dithiolate） to [Cp^＊Fe（μ-bdt）FeCp^＊]]^＋（2） has been experimentally conducted. The bdt...; 关键词：density functional theory iron-sulfur cluster benzene-1 2-dithiolate non-innocent ligand single-electron oxidation

Preparation, Structure and Electrochemical Property of a Pyrazole-substituted Diiron Dithiolate Complex: 《Chinese Journal of Structural Chemistry》2012年第11期1650-1656,共7页冯亚南陈瑞平李志华杜少武; supported by the National Basic Research Program of China(973Program,2012CB821702);the National Natural Science Foundation of China(21173221and20903096);the State Key Laboratory of Structural Chemistry(20120015); A pyrazole-substituted diiron dithiolate complex [Fez（p-pdt）（CO）5（3,5-Me2Pz）] （1, 3,5-MezPz = 3,5-dimethylpyrazole） was prepared as a biomimetic model for the active site of [FeFe]-hydrogenase by CO-substituti...; 关键词：bioinorganic chemistry [FeFe]-hydrogenase SUBSTITUTION proton reduction

Reactions of a 16-electron Cp*Co half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand with alkynones HC≡C-C(O)R (R=OMe,Me,Ph)被引量：2: 《Science China Chemistry》2010年第10期2129-2138,共10页GUOYIQIBAYI Gulnisa; the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303); The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...; 关键词：ortho-carborane DITHIOLATE alkynone cobalt complex HALF-SANDWICH crystal structure

Hydrothermal Synthesis, Crystal Structure and Optical Properties of [M（en）3]（ndt）·H2O （M=Ni^Ⅱ, Co^Ⅱ, Mn^Ⅱ and ndt= 1,5-Naphthalenedithiolate）: 《Chinese Journal of Chemistry》2006年第5期695-700,共6页于景华魏永革丁长江杜洪光阎盛刚郭洪猷; Three novel compounds [Ni（en）3]（ndt）·H2O （1）, [Co（en）3]（ndt）·H2O （2） and [Mn（en）3]（ndt）·H2O （3）（en= ethylenediamine, ndt= 1,5-naphthalenedithiolate） have been synthesized under hydrothermal con...; 关键词：DITHIOLATE tris（ethylenediamine）-metal chelate hydrothermal synthesis crystal structure optical property

Synthesis,Structure and Characterization of Bis(ethylene-1,2-dithiolate)(μ_(2)-di-2-pyridyl-ketone p-phenyldiamine-N,N')-tin(IV)Dichloromethane: 《Chinese Journal of Structural Chemistry》2005年第12期1355-1358,共4页WANG Long-Sheng ZHANG Jian-Jun HU Sheng-Min FU Rui-Biao WU Xin-Tao; supported by the State Key Laboratory of Structural Chemistry,the NNSFC(20273073,20333070,90206040);NSF of Fujian Province(2004J041,2003J042,2004HZ01-1); A new mononuclear tin（Ⅳ） complex [Sn（edt）2L]·CH2Cl2 （edt = ethane-1,2-dithiolate, L = di-2-pyridyl-ketone p-phenyldiamine） was obtained by a one-pot reaction which involves in situ formation of a new Schiff-ba...; 关键词：TIN p-phenyldiamine ethene-1 2-thiolate di-2-pyridyl-ketone Schiff-base

Synthesis and Structural Characterization of a Salt {[Co(Phen)_3][Mo_2S_2(μ-S)_2(edt)_2]}_2·(DMSO)_2·(Et_2O)(Phen = 1,10-Phenanthroline, edt=Ethane-1,2-dithiolate): 《Chinese Journal of Structural Chemistry》2005年第7期773-778,736,共7页ZHANGWen-Hua RENZhi-Gang ZHANGYong; This work was supported by the NNSFC (No. 20271036), the NSF of Jiangsu Province (No. BK2004205) and the State Key Laboratory of Structural Chemistry (030066); Reaction of [Et4N]2[Mo2S2(μ-S)2(edt)2] with CoCl2?6H2O and Phen in MeCN followed by recrystallization in DMSO/Et2O gave rise to dark-red block crystals of {[Co(Phen)3]- [Mo2S2(μ-S)2(edt)2]}2?(DMSO)2?(Et2O) 1 (C88H86...; 关键词：molybdenum cluster sulfur cobalt crystal structure SYNTHESIS

Syntheses and Crystal Structures of Two Mononuclear Tin(IV) Complexes Derived from Sn(edt)_2(edt = Ethane-1,2-dithiolate): 《Chinese Journal of Structural Chemistry》2004年第1期29-32,共4页ZHANGJian-Jun WULi-Ming HUSheng-Min WANGLong-Sheng DUWen-Xin WUXin-Tao; This research was financially supported by the grants from the State Key Laboratory of Structural Chemistry; the National Science and Technology of China (001CB1089); the Chinese Academy of Sciences (CAS); the National Science Foundation of China (20; Two mononuclear tin(IV) complexes, [Sn(pda)2(edt)2] (pda = o-phenylenediamine) (C16H24N4S4Sn, Mr = 519.32) 1 and [Sn(eda)(edt)2] (eda = ethylenediamine) (C6H16N2S4Sn, Mr = 363.14) 2 were synthesized and characterized ...; 关键词：crystal structure tin(IV) ethane-1 2-dithiolato

Cluster-cracking Reaction, a New Method to Synthesize Unsymmetrical Dithiolate Complexes for the Study of Third-Order Nonlinear Optical Properties被引量：1: 《Chinese Journal of Chemistry》2003年第5期537-543,共7页卞国庆朱琴玉戴洁王昕杨巍严泽民孙真荣宗像惠前川雅彦; ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 0 0 710 2 4) ;theEducationCommitteeofJiangsuProvince (No .0 0KJB15 0 0 0 1) .; A new cluster-cracking method to synthesize dithiolate metal complexes was reported and four unsymmetric complexes with formula (Me4N)(2)[M(Ln)(SPh)(2)] (M = Cd and Zn, L1 = dmit = 1, 3-dithiole-2-thione-4, 5-dithiola...; 关键词：synthetic method dmit complexes DITHIOLATE NLO properties

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