CAGES

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Stable copper boron-imidazolate cage as Cu-riched enzyme for highly efficient electrocatalytic CO_(2)reduction to ethylene
《Science China Chemistry》2025年第3期943-950,共8页Jun-Qiang Chen Qiao-Hong Li Qin-Long Hong Ping Shao Hai-Xia Zhang Jian Zhang 
the support from the National Key Research and Development Program of China (2021YFA1501500);the National Natural Science Foundation of China (22275192,92161105);the STS Project of Fujian-CAS (2023T3054)。
Single-atom catalyst has garnered widespread attention to mimic mature enzymes due to its well-defined atomic structure and coordination environments.However,since the carbon-carbon(C-C)coupling reactions require syne...
关键词：metal-organic cages CO_(2)reduction single-metal-site catalyst boron-imidazolate cages 
New deltahedral architectures of rhodium-mediated Pn_(7)^(3−)(Pn=Sb and Bi)cages
《Nano Research》2025年第3期666-673,共8页Lei Qiao Chuan-Ling Chen Zhong-Ming Sun 
supported by the National Natural Science Foundation of China(Nos.22425107,92461303,22371140,and 92161102(Z.-M.S.))and(No.22301143(L.Q.)).
The reactions of K_(5)Pn_(4)(Pn=Sb and Bi)and CpRh(PPh_(3))_(2)(Cp=C_(5)H_(5),cyclopentadiene)in ethylenediamine(en)solutions resulted in a series of new Pn_(7)^(3−)−adducts,{Pn_(8)[Rh(PPh_(3))]_(2)}^(2−),{Sb_(7)[Rh(P...
关键词：group 15 clusters heterometallic clusters nanoclusters-based materials electronic structures coordination modes 
Efficient Self-assembly of Isoquinoline-Based Triply Interlocked Cages
《Chinese Journal of Chemistry》2025年第6期607-612,共6页Qiu-Shui Mu Xin-Yu Wang Xiang Gao Guo-Xin Jin 
supported by the National Science Foundation of China(22031003,21720102004,and 22301040);the Shanghai Science Technology Committee(19DZ2270100).
Comprehensive Summary Triple interlocked systems represent highly intricate topological structures,formed by entwining two mechanically interlocked cages.Achieving controlled and straightforward construction of these ...
关键词：Cage compounds Half-sandwich complexes SELF-ASSEMBLY CATENANES Noncovalent interaction 
Acyl-anchored metal-organic cages with interior cryptand-like recognition sites for selective removal of radioactive strontium(Ⅱ)
《Science Bulletin》2025年第5期683-693,共11页Wei Jin Qunyan Wu Yan Lou Zhiwei Huang Feng Liu Bowen Hu Jipan Yu Kongqiu Hu Liyong Yuan Weiqun Shi Lei Mei 
National Natural Science Foundation of China(22122609,22076186 and U20B2019);NationalScienceFund for Distinguished Young Scholars(21925603).
Tailored design of organic linkers or metal nodes can introduce desirable functionalities into metal-organic cages(MOCs),significantly expanding their potential applications.In this study,we present a viable approach ...
关键词：Metal-organic cages Supramolecular recognition Node engineering Radioactive strontium Selective removal 
Piling up multidecker pyrgos[n]cages as antibacterial materials
《Science China Materials》2025年第1期314-316,共3页Miguel A.Liuzzi-Vaamonde Jackson B.Lancaster Samantha A.Mason Yuanning Feng 
The development of antibiotics is regarded as one of the most significant scientific advances in modern medicine. Before the commercialization of antibiotics, infectious diseases were catastrophic throughout history [...
关键词：DISEASES adapted ANTIBIOTICS 
Fluorine-functionalized zirconium-organic cages for efficient photocatalytic oxidation of thioanisole
《Chinese Chemical Letters》2025年第1期632-636,共5页Jia-Ru Li Ning Li Li-Ling He Jun He 
supported by National Natural Science Foundation of China(Nos.22201046,22371054);Local Innovation Research Team Project of Guangdong Pearl River Talent Plan(No.2017BT01Z032)。
Zirconium-based metal-organic cages(Zr-MOCs)typically exhibit high stability,but their structural and application reports are scarce due to stringent crystallization conditions.We have successfully fluorinated the cla...
关键词：Ultraviolet light FLUORINE Zirconium-based metal-organic cages Sulfide oxidation Multiphase photocatalysis 
Ambient-Pressure Anisotropic Single-Gap Superconductivity in La-Trapped B_(26)Cages with Superior Hardness
《Chinese Physics Letters》2025年第1期177-191,共15页Haoqi Chen Yushan Tang Haowen Jiang Xuehui Jiang Jialin Wang Chengyao Zhang Defang Duan Yanbin Ma Jing Dong 
supported by the National Natural Science Foundation of China(Grant Nos.11904067,12122405,52072188,12274169;51632002)。
Recently,a breakthrough in the high-pressure synthesis of sp^(3)-bonded clathrate-like R-3m-L_(a)B_(8)featuring Latrapped B_(26)cages was achieved.Although the superconducting critical temperature(T_(c))and Vickers ha...
关键词：ANISOTROPIC BREAKTHROUGH 
Steric Control over Interligand Dihedrals and Splay Leads to the Formation of Fe^(II)_(6)L_(6)and Fe^(II)_(8)L_(8)Antiprisms
《CCS Chemistry》2024年第10期2411-2419,共9页Yuchong Yang Yuyin Du Tanya K.Ronson Jonathan R.Nitschke 
supported by the European Research Council(grant no.695009);the UK Engineering and Physical Sciences Research Council(EPSRC,grant nos.EP/T031603/1 and EP/P027067/1).
Macrocycles have found uses in guest capture,sensing,and porous materials,motivating the development of new methods for their synthesis.Here we report the construction of two types of barrelshaped macrocyclic assembli...
关键词：self-assembly metal-organic cages host-guest chemistry redox-responsive materials dihedral control 
Localization−delocalization transitions in non-Hermitian Aharonov−Bohm cages
《Frontiers of physics》2024年第3期39-50,共12页Xiang Li Jin Liu Tao Liu 
T.L.acknowledges the support from the Fundamental Research Funds for the Central Universities(Grant No.2023ZYGXZR020);the Introduced Innovative Team Project of Guangdong Pearl River Talents Program(Grant No.2021ZT09Z109);the Startup Grant of South China University of Technology(Grant No.20210012).
A unique feature of non-Hermitian systems is the extreme sensitivity of the eigenspectrum to boundary conditions with the emergence of the non-Hermitian skin effect (NHSE). A NHSE originates from the point-gap topolog...
关键词：non-Hermitian skin effects DISORDER flat band localization−delocalization transition 
Integrating Levels of Hierarchical Organization in Porous Organic Molecular Materials
《Nano-Micro Letters》2024年第5期134-153,共20页Jesus Ferrando‑Soria Antonio Fernandez 
the MICINN (Spain)(Projects PID2019-104778GB-I00, PID2020-115100GB-I00;Excellence Unit “Maria de Maeztu” CEX2019-000919-M);the Royal Society of Chemistry;funded by Generalitat Valenciana;(PROMETEU/2021/054 and SEJI/2020/034);the “Ramón y Cajal” program (RYC2019-027940-I);the Royal Society (RGSR1221390);Royal Society of Chemistry (R21-5119312833) for the funding.
Porous organic molecular materials(POMMs)are an emergent class of molecular-based materials characterized by the formation of extended porous frameworks,mainly held by non-covalent interactions.POMMs represent a varie...
关键词：Porous organic molecular materials HIERARCHY Hydrogen-bonded organic frameworks Porous cages FULLERENE 
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