Financial supports were provided by the NSFC(22271249);the National Key R&D Program of China(2021YFF0701600 and 2021YFA1500200);the Fundamental Research Funds for the Central Universities(226-2022-00224 and 226-2024-00003);Zhejiang Provincial Natural Science Foundation of China(LDQ24B020001).
A mechanistically distinctive visible-light-promoted metal-free aerobic oxidation of alkenyl silanes with alcohols was disclosed to efficiently constructα-alkoxy ketones under mild conditions.The primary,secondary,an...
supported by the National Natural Science Foundation of China (Nos. 22171220);the Fundamental Research Funds of the Central Universities (No. xtr072022003)。
A regioselective C-C bond cleavage/aminocarbonylation cascade is presented. In recent years, tremendous progress has been made in the alkoxyl radical-mediated C-C bond cleavage of unstrained monocarbocycles. In contra...
MEXT World Premier International Research Center Initiative,Japan;Core Research for Evolutional Science and Technology,Grant/Award Number:JPMJCR18R3;Japan Society for the Promotion of Science,Grant/Award Numbers:JP21K14611,JP22H00334,JP23H04027。
Cylinder-shaped macrocycles composed ofπ-panels have attracted special attention as one of the best platforms for the development of organic molecule-based chi-roptical materials.Pillar[n]arenes are a class of macroc...
National Natural Science Foundation of China,Grant/Award Number:52022071;Shenzhen Science and Technology Program,Grant/Award Number:ZDSYS20210623091813040。
Organic scintillators have recently gained considerable attentions in X-ray detection for their potential applications in biomedical radiograph and security inspection.However,the weak X-ray absorption and/or ineffici...
supported by the National Key Research and Development Program of China(2019YFA0705900);the Ministry of Science and Technology,the National Natural Science Foundation of China(51820105003,21734008,52203248,61904181,52173188);the Key Research Program of the Chinese Academy of Sciences(XDPB13);the Basic and Applied Basic Research Major Program of Guangdong Province(2019B030302007)。
The medium-bandgap polymerized small molecule acceptors(PSMAs)have broad application scenarios.However,the effort in the molecular design of the high-performance medium-bandgap PSMAs is limited.In this article,we intr...
This work was supported by the National Natural Science Foundation of China(Nos.52125306,22005347).
Ultra-narrow bandgap(ultra-NBG)small molecule acceptors(SMAs)show great potential in organic solar cells(OSCs)due to the extended near-infrared(NIR)absorption.In this work,a synergetic alkoxy side-chain and chlorine-c...
financially supported by the National Natural Science Foundation of China(22005133,22105096,and 52173171).
CONSPECTUS:Organic electronics has experienced substantial advances in the past decade,driven by the development of high-performance organic semiconductors(OSCs)in combination with device engineering.While the pursuit...
the financial support from the NSFC of China(21772208 and 21633013);Natural Science Foundation of Jiangsu Province(BK20201183);the Key Research Program of Frontier Sciences of Chinese Academy of Sciences(QYZDJSSW-SLH051).
A new approach for radical cross coupling of organic halides and oxalates toward esters has been developed via photoredox nickel dual catalysis.This method has been demonstrated for transformation of a wide range of a...
The mesogenic properties of a homologous series of aromatic ester materials are investigated. Single tail and double tail materials were synthesized to compare with other series we prepared and published earlier. The ...
Fund of Luzhou Government and Southwest Medical University(Nos.2019LZXNYDJ28,2018LZXNYD-ZK33,2018LZXNYD-ZK39);the Open Project of Central Nervous System Drug Key Laboratory of Sichuan Province(No.200023-01SZ);the research fund of Southwest Medical University(Nos.2017-ZRZD-020 and 2017-ZRQN-031).
Main observation and conclusion Alkoxy radical-mediated carbon-carbon bond cleavages have emerged as a powerful strategy to complement traditional ionic-type transformations.However,carbon-carbon cleavage reaction tri...