RHODIUM

作品数:162被引量:179H指数:7
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相关领域:理学更多>>
相关作者:王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构:南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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  • 期刊=Chemical Research in Chinese Universitiesx
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Phosphite Ligand Modified Supported Rhodium Catalyst for Hydroformylation of Internal Olefins to Linear Aldehydes被引量:2
《Chemical Research in Chinese Universities》2009年第5期738-739,共2页LI Xian-ming DING Yun-jie JIAO Oui-ping LI Jing-wei YAN Li ZHU He-jun 
Supported by the Ministry of Science and Technology of China(No.2009CB623503)
A phosphite ligand modified heterogeneous catalyst was developed for the hydroformylation of internal olefins to linear aldehydes, which showed a high activity and high regioselectivity and could be separated easily b...
关键词:Phosphite ligand HYDROFORMYLATION Internal olefin Shape selective performance 
Synthesis of Symmetrical Biaryls via Rhodium Catalyzed Dimerization of Arylmercurials and Mechanism of the Dimerization被引量:2
《Chemical Research in Chinese Universities》2000年第2期131-135,共5页WANG Yulan WU Yangjie 
Supported by the Scientific Research Foundation for Returned Overseas Chinese Scholarsof Educational Ministry ofChina
A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO) 2] 2 in hexamethylphosphoramide(HMPA). The mechanism of the [ClRh(CO) 2] 2 catalyzed d...
关键词:Symmetrical biaryls Synthesis Arylmercurials Intermolecular reaction 
Simultaneous Spectrophotometric Determination of Trace Palladium and Rhodium with2,4-TADAT
《Chemical Research in Chinese Universities》1994年第1期31-35,共5页
SimultaneousSpectrophotometricDeterminationofTracePalladiumandRhodiumwith2,4-TADATZHANGXiao-ling;andZHANGGua...
关键词:Thiazolylazo diamino toluene RHODIUM PALLADIUM 
A New Indicator Reaction and Its Application-Catalytic Determination of Ultratrace Amounts of Rhodium with Linear Sweep Voltammetry
《Chemical Research in Chinese Universities》1993年第1期85-90,共6页WANG Li-sheng and JIANG Zhi-liang (Department of Chemistry, Guangxi Normal University, Guilin, 541004) 
Supported by the National Natural Science Foundation of China
Introduction Sensitive linear sweep voltammetry to have been applied to the catalytic kinetic analysis may be helpful for the application of some organic reagents to the analysis of inorganic ones by voltammetry, The ...
关键词:Linear sweep voltammetry Catalyti method RHODIUM Fast green 
Separation and Determination of Cobalt, Rhodium,Nickel and Iridium with 2-(6-Methyl-2-Benzothiazolylazo)-5-Diethylamino Phenol by HPLC
《Chemical Research in Chinese Universities》1993年第1期18-23,共6页LIU Qi-ping, ZHANG Hua-shan and CHENG Jie-ke (Department of Chemistry, Wuhan University, Wuhan, 430072) 
Supported by the National Natural Science Foundation of China
The synthesis and spectrophotometric properties of 2-(6-methyl-2-benzothiazolylazo)-5-diethylamino phenol (MBTAE), and the use of it as a precolumn derivatizing reagent to separate Co(Ⅱ), Ni(Ⅱ), Rh(Ⅲ) and Ir( Ⅳ) c...
关键词:COBALT RHODIUM NICKEL IRIDIUM HPLC 
Studies on Dual-beam Spectrometric Simultaneous Determination of Platinum and Rhodium with Water-Insoluble Porphine T(3-M-4HP)P
《Chemical Research in Chinese Universities》1991年第2期91-95,共5页Li Youfen and Zheng Yanzhi (Department of Chemistry, Xiangtan University, Xiangtan) 
The optimal conditions for the complexation reaction of meso- tetra(3-methoxy-4-hy-droxyphenyl) porphine T(3-M-4HP)P with platinum and rhodium are presented. Beer' s Law is obeyed when the concentration of rhodium is ...
关键词:PLATINUM RHODIUM Spectrophotonletry Meso-tetra(3-M-4HP)P. 
Synthesis of Polymer-Supported Heteronuclear Rhodium- Cobalt Bimetallic Carbonyl Cluster Catalysts and Their Hydroformylation Properties
《Chemical Research in Chinese Universities》1989年第4期357-362,共6页He Binglin(Ho Ping-Lum), Sun Juntan, Li Hong, Sang Junjie and Zhao Fenzhi (Institute of Polymer Chemistry, Nankai University, Tianjin) 
The project supported by National Natural Science Foundation of China
Tetranuclear Rh-Co bimetallic cluster was synthesized and characterized by IR and XPS. The properties of the anchored catalysts, its stability and the ligand effect were also studied. The experimental results show tha...
关键词:Rhodium-cobalt cluster Polymer-supported catalysts HYDROFORMYLATION 
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