Supported by the Ministry of Science and Technology of China(No.2009CB623503)
A phosphite ligand modified heterogeneous catalyst was developed for the hydroformylation of internal olefins to linear aldehydes, which showed a high activity and high regioselectivity and could be separated easily b...
Supported by the Scientific Research Foundation for Returned Overseas Chinese Scholarsof Educational Ministry ofChina
A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO) 2] 2 in hexamethylphosphoramide(HMPA). The mechanism of the [ClRh(CO) 2] 2 catalyzed d...
Supported by the National Natural Science Foundation of China
Introduction Sensitive linear sweep voltammetry to have been applied to the catalytic kinetic analysis may be helpful for the application of some organic reagents to the analysis of inorganic ones by voltammetry, The ...
Supported by the National Natural Science Foundation of China
The synthesis and spectrophotometric properties of 2-(6-methyl-2-benzothiazolylazo)-5-diethylamino phenol (MBTAE), and the use of it as a precolumn derivatizing reagent to separate Co(Ⅱ), Ni(Ⅱ), Rh(Ⅲ) and Ir( Ⅳ) c...
The optimal conditions for the complexation reaction of meso- tetra(3-methoxy-4-hy-droxyphenyl) porphine T(3-M-4HP)P with platinum and rhodium are presented. Beer' s Law is obeyed when the concentration of rhodium is ...
The project supported by National Natural Science Foundation of China
Tetranuclear Rh-Co bimetallic cluster was synthesized and characterized by IR and XPS. The properties of the anchored catalysts, its stability and the ligand effect were also studied. The experimental results show tha...