The catalytic hydrogenation of halonitroarenes to haloanilines is a green and sustainable process for the production of key nitrogen-containing intermediates in fine chemical industry.Chemoselective hydrogenation pose...
Rh(Ⅲ)-catalyzed, chelation-assisted oxidative C-H imidation of arenes with N-H imide have been realized using PhI(OAc)2 as an oxidant. This transformation exhibits a broad substrate scope and tolerates various functi...
supported by the National Natural Science Foundation of China(21606222,21776270);Liaoning Revitalization Talents Program(XLYC1807068);DNL Cooperation Fund,CAS(180403);US National Science Foundation under CHE-1465057~~
CO oxidation is of great importance in both fundamental study and industrial application.Supported noble metal catalysts are highly active for CO oxidation but suffer from the scarcity and high cost.Single-atom cataly...
supported by the Dalian Institute of Chemical Physics,Chinese Academy of Sciences;the National Natural Science Foundation of China (21525208,21472186)~~
A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(III)‐catalyzed C?H activation of benzamides and[4+1]coupling with propargyl alcohols.This coupling system proceeds with broad substra...
financially supported by the National Natural Science Foundation of China(21273227,20903090)~~
Rh/SiO2 catalysts with tethered-phosphines with different alkyl spacer lengths have been prepared,tested and characterized.Lengthening the alkyl spacer of the tethered-phosphine improved the flexibility of tethered-ph...