RHODIUM

作品数：162被引量：179H指数：7
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相关领域：理学更多>>
相关作者：王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构：南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Activity promotion of Rh_(1)Ca_(x)/Al_(2)O_(3) single-atom catalyst in 1-octene hydroformylation:a volcano curve exists between Ca adding ratio and catalytic activity被引量：2
《Science China Chemistry》2024年第4期1187-1192,共6页Hao Zhang Xingcong Zhang Xilun Wang Qingdi Sun Hao Liu Hongbing Ji Xiaohui He 
supported by the National Key Research and Development Program Nanotechnology Specific Project(2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(2022B1515020035);Guangdong Provincial Key R&D Program(2019B110206002);the National Natural Science Foundation of China(22078371,21938001,21961160741);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guangdong Province(2020A1515011141);the Science and Technology Project of Guangzhou City,China(202102020461)。
Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous catalysts.Unlike conventional organo-phosphine modification,R...
关键词：HYDROFORMYLATION bimetallic single-atom catalysts RHODIUM heterogeneous catalyst 
Efficient Heterogeneous Hydroformylation over Zeolite-Encaged Isolated Rhodium Ions
《CCS Chemistry》2023年第7期1526-1539,共14页Weixiang Shang Bin Qin Mingyang Gao Xuetao Qin Yuchao Chai Guangjun Wu Naijia Guan Ding Ma Landong Li 
This work was supported by the National Natural Science Fund of China(grant nos.21872072 and 22025203);the Frontiers Science Center for New Organic Matter,Nankai University(grant no.63181206);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.
Alkene hydroformylation is an extremely important industry process currently accomplished via homogeneous catalysis.Heterogeneous hydroformylation is being avidly pursued as a more economical and sustainable process.H...
关键词：ZEOLITE isolated rhodium site heterogeneous catalysis HYDROFORMYLATION mechanism 
Synthesis of rac-α-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalyst被引量：1
《Chinese Chemical Letters》2022年第2期830-834,共5页Peng Gao Miaolin Ke Tong Ru Guanfeng Liang Fen-Er Chen 
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
关键词：Aryl propionaldehydes HYDROFORMYLATION Water-soluble PNP ligands Regioselectivity RHODIUM 
A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts被引量：5
《Frontiers of Chemical Science and Engineering》2018年第1期113-123,共11页Cunyao Li Wenlong Wang Li Yan Yunjie Ding 
Acknowledgements This work was supported by the National Natural Science Foundation of China （Grant Nos. 21273227 and 21403258） and the Strategic Priority Research Program of the Chinese Academy of Science （Grant Nos XDB 17020400）.
Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffer...
关键词：HYDROFORMYLATION porous organic ligand （POL）-supported catalysts heterogeneous catalysis high stability immobilization catalysts 
Highly active rhodium]phosphorus catalytic system for the hydroformylation of α-methylstyrene
《Chinese Chemical Letters》2016年第5期678-680,共3页Xue-Li Zheng Cong-Ye Zheng Fan-Ding Zhou Hai-Yan Fu Mao-Lin Yuan Rui-Xiang Li Bin Xu Hua Chen 
financial support from the National Natural Science Foundation of China (No. 201202108);from the Opening Project of Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education (No. LZJ1402);from the Sichuan university outstanding scholar research fund (No. 2015SCU04A05)
Rhodium catalyzed hydroformylation of α-methylstyrene was investigated in the presence of monodentate phosphine ligands L1-L6. We found that the phosphine with good n-acceptability could efficiently improve the activ...
关键词：α-Methytstyrene Hydroformylation Rh complex Phosphine Pyrrole 
Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO_2 catalyst被引量：5
《Chinese Journal of Catalysis》2016年第2期268-272,共5页刘佳 严丽 姜淼 李存耀 丁云杰 
financially supported by the National Natural Science Foundation of China(21273227,20903090)~~
Rh/SiO2 catalysts with tethered-phosphines with different alkyl spacer lengths have been prepared,tested and characterized.Lengthening the alkyl spacer of the tethered-phosphine improved the flexibility of tethered-ph...
关键词：Tethered phosphine Chain length RHODIUM Silica HYDROFORMYLATION 
Hydroformylation of alkenes over rhodium supported on the metal-organic framework ZlF-8被引量：18
《Nano Research》2014年第9期1364-1369,共6页Chao Hou Guofeng Zhao Yongjun Ji Zhiqiang Niu Dingsheng Wang Yadong Li 
A highly porous and crystalline metal-organic framework （MOF） ZIF-8 has been synthesized and used for the preparation of a supported rhodium nanoparticle catalyst （Rh@ZIF-8）. The material has been characterized by...
关键词：heterogeneous catalysis supported rhodiumcatalyst metal-organic framework ZIF-8 HYDROFORMYLATION 
A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C_(11-12) olefins in aqueous/organic biphasic system被引量：2
《Chinese Chemical Letters》2010年第5期515-518,共4页Zhi Jiang Ji,Jing Yang Jiang,Yan Hua Wang State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012,China 
the financial support from the Program for New Century Excellent Talents in University (No.NCET-07-0138);the Science and Technology Project in Universities from the Education Department of Liaoning Province(No.2008T233).
A novel thermoregulated phosphine ligand PhP(CHCHO)CH(n=22) was synthesized and used for the Rh-catalyzed hydroformylation of mixed Colefins in aqueous/organic biphasic system.Under the optimized conditions,pressure =...
关键词：Thermoregulated phosphine ligand Mixed C11-12 olefins HYDROFORMYLATION RHODIUM 
Phosphite Ligand Modified Supported Rhodium Catalyst for Hydroformylation of Internal Olefins to Linear Aldehydes被引量：2
《Chemical Research in Chinese Universities》2009年第5期738-739,共2页LI Xian-ming DING Yun-jie JIAO Oui-ping LI Jing-wei YAN Li ZHU He-jun 
Supported by the Ministry of Science and Technology of China(No.2009CB623503)
A phosphite ligand modified heterogeneous catalyst was developed for the hydroformylation of internal olefins to linear aldehydes, which showed a high activity and high regioselectivity and could be separated easily b...
关键词：Phosphite ligand HYDROFORMYLATION Internal olefin Shape selective performance 
A novel phosphate ligand used for the Rh-catalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system被引量：1
《Chinese Chemical Letters》2007年第8期933-935,共3页Wei Wei Yan Hua Wang Jing Yang Jiang Zi Lin Jin 
Financial support from Fok Ying Tung Education Foundation(No.91071);the National Natural Science Foundation of China(No.20376013)are gratefully acknowledged.
A novel phosphate ligand, tri-（methoxyl polyethylene glycol）-phosphate （TMPGPA）, has been synthesized and used in the Rhcatalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system. Under the ...
关键词：Thermoregulated PEG biphase system HYDROFORMYLATION Phosphate ligand RHODIUM CYCLOHEXENE 
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