The Zn and Fe modified /ZrO2-Al2O3 catalyst (Zn-Fe-SZA) was prepared and mechanisms of deactivation and methods for regeneration of as-prepared catalyst were explored with n-pentane is...
The non-noble metal modified sulfated zirconia was found easy to deactivate.Herein,highly active and highly stable non-noble core-shell Ni-S_(2)O_(8)^(2−)/Al_(2)O_(3)@ZrO_(2) catalysts(Ni-SA@Z-x,x=Al content in wt%)ha...
supported by National Natural Science Foundation of China (52006242);National Natural Science Foundation of China (52192623);Science Foundation of China University of Petroleum,Beijing (ZX20200126);Science and technology program for strategic cooperation of CNPC–China University of Petroleum (ZLZX2020-05)。
The heat transfer of hydrocarbon refrigerant across tube bundles have been widely used in refrigeration.Three-dimensional simulation model using volume of fluid(VOF) was presented to study the effects of tube shapes o...
supported by Program of China National Petroleum Corporation(2020B-2012;2022zS27);the General Program of National Natural Science Foundation of China(22178385).
When converting C_(5) hydrocarbons to light olefins by catalytic pyrolysis,the generation of low value-added methane will affect the atomic utilization efficiency of C_(5) hydrocarbons.To improve the atomic utilizatio...
supported by a Science,Mathematics,and Research for Transformation(SMART)fellowship hosted by U.S.Army’s Combat Capabilities Development Command(CCDC)Ground Vehicle Systems Center。
Recent combustion research has focused on low temperature combustion to meet engine emission regulations and to advance the development of low temperature homogenous compression ignition engines.Autoignition studies i...
The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China(Grant No.21908010);the Education Department of Jilin Province(Grant No.JJKH20191314KJ);the Changchun University of Technology.
In this work,n-pentane catalytic cracking over HZSM-5 zeolites was studied at 650°C under atmosphere pressure.A particular attention was paid to the measurement of n-pentane conversion,light olefins production,produc...
financial support from the National Natural Science Foundation of China(Grant No.21908010);the Education Department of Jilin Province(Grant No.JJKH20191314KJ);Changchun University of Technology。
Modeling light olefin production was one of the main concerns in chemical engineering field.In this paper,machine learning model based on artificial neural networks(ANN)was established to describe the effects of tempe...
Supported by the National Natural Science Foundation of China(21802047);the Scientific Research Funds of Huaqiao University(600005-Z17Y0073).
The isomerization of n-pentane to generate high-quality blending components for clean gasoline was catalyzed by several amide-AlCl3-based ionic liquid(IL) analogs with various amides as donor molecules. The catalytic ...
A mathematical mechanism of the n-pentane pyrolysis process based on free radical reaction model was presented.The kinetic parameters of n-pentane pyrolysis are obtained by quantum chemistry and the reaction network i...
Supported by the Technology Risk Innovation Foundation of China National Petroleum Corporation(07-06D-01-04-03-02)
The effects of adding rare earth(RE) metals,such as Ce,Yb and Pr to Ni-S_2O_8^(2-)/ZrO_2-Al_2O_3(Ni-SZA) on the structure of catalysts as well as their isomerization performance were studied.The prepared catalysts wer...