SPIRO

作品数:171被引量:144H指数:5
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相关领域:理学电气工程更多>>
相关作者:李福民陈冲郑小璐石东王杰更多>>
相关机构:电子科技大学河南大学合肥工业大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划高等学校学科创新引智计划国家高技术研究发展计划更多>>
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Catalytic production of high-energy-density spiro polycyclic jet fuel with biomass derivatives
《Journal of Energy Chemistry》2025年第2期760-768,I0016,共10页Wen-Jing Zhang Yan-Cheng Hu Yan-Hong Tan Jia Li Ning Li Jing-Pei Cao 
supported by the Fundamental Research Funds for the Central Universities(2023QN1009);Xuzhou Basic Research Project(KC23018);China University of Mining and Technology(CUMT)Open Sharing Fund for Large-scale Instruments and Equipment(DYGX-2024-34);Priority Academic Program Development of Jiangsu Higher Education Institutions.
High-energy-density(HED)fuel(e.g.widely used JP-10 and RJ-4),featuring compact 3D polycyclic structure with high strain,is of critical importance for volume-limited military aircraft,since their high density and combu...
关键词:Biomass derivatives High-energy-density Spiro polycyclic fuel Cycloaddition Lewis acidic ionic liquid 
Deciphering fungal metabolon coupling tandem inverse-electrondemand Diels-Alder reaction and semipinacol rearrangement for the biosynthesis of spiro polycyclic alkaloids
《Science China Chemistry》2025年第1期288-296,共9页Shuai Liu Wen-Qiang Xu Ying-Tong Di Man-Cheng Tang Ding-Kang Chen Ming-Ming Cao Yao-Wen Chang Hong-Yu Tang Chun-Mao Yuan Jun-Bo Yang Zhi-Li Zuo Han Guo Zi-Fei Xu Ying Zeng Yun-Dong Wu Xiao-Jiang Hao 
supported by the National Natural Science Foundation of China(U1812403 to Xiao-Jiang Hao,2193304 to Yun-Dong Wu,81573323 and 31770392 to Ying-Tong Di,and 22177050 to Ming-Ming Cao);the Project of Yunnan Characteristic Plant Screening and R&D Service CXO Platform(2022YKZY001);the Yunnan Provincial Science and Technology Department(202003AD150012 to Xiao-Jiang Hao,202201AS070040 and 202302AA310035 to Ying-Tong Di)。
In the intricate process of natural product biosynthesis,a metabolon can enhance metabolic flux by associating sequential enzymes.A fungal metabolon,comprising of flavin-dependent monooxygenase Spe F and P450 monooxyg...
关键词:METABOLON Diels-Alder reaction semipinacol rearrangement biosynthesis notoamides spiro polycyclic alkaloids 
trans-4'a-Methyl-3',4'a,9',10',10'a-hexahydro-spiro[cyclobutane-1,1'(2H)-phenanthrene]的全合成
《有机化学》2024年第11期3386-3391,共6页戴伟昊 霍晨雨 郑天禄 朱道勇 王少华 
国家重点研发计划(No.2023YFA1506404);甘肃省科技计划(Nos.23ZDFA003,23JRRA1144,23JRRA1028,23CXGA0043);兰州市科技计划(Nos.2023-1-17,2023-QN-18);中央高校基本科研业务专项(Nos.lzujbky-2022-ct03,lzujbky-2022-sp09,lzujbky-2023-ct02,lzujbky-2023-pd08);陇药协同创新中心和甘肃省药物研发计划(No.2022GSMPA0010)资助项目。
以苯丙醛为起始原料,通过两种策略的使用完成trans-4'a-methyl-3',4'a,9',10',10'a-hexahydro-spiro[cyclobutane-1,1'(2H)-phenanthrene]的首次全合成.具体的关键步骤分别为金催化的1,3-酰基迁移/串联环化和InI3催化的多烯环化.
关键词:trans-4'a-methyl-3' 4'a 9' 10' 10'a-hexahydro-spiro[cyclobutane-1 1'(2H)-phenanthrene] 全合成 天然产物 
以Spiro-OMeTAD作为空穴传输层的ZnS/SnS太阳能电池模拟研究
《人工晶体学报》2024年第8期1394-1408,共15页唐华著 肖清泉 付莎莎 谢泉 
贵州大学智能制造产教融合创新平台及研究生联合培养基地(2020-520000-83-01-324061);贵州省智慧化服务工程研究中心(2203-520102-04-04-298868);贵阳市科技平台建设项目(筑科合同[2023]7-3)。
硫化亚锡(SnS)因其合适的电学和光学特性而被作为太阳能电池的吸收层进行研究。Spiro-OMeTAD常用作空穴传输层以提高太阳能电池性能。本文采用wxAMPS软件对SnS基太阳能电池ZnS/SnS/Spiro-OMeTAD进行模拟研究。主要研究分析Spiro-OMeTAD...
关键词:硫化亚锡 硫化锌 Spiro-OMeTAD 空穴传输层 异质结太阳能电池 wxAMPS 缺陷 
ZnO/Spiro-MeOTAD异质结自驱动光电探测器的制备及性能(特邀)
《光子学报》2024年第7期58-67,共10页李朋凡 黄雨欣 俞学伟 冯仕亮 姜岩峰 闫大为 于平平 
国家自然科学基金(No.51802124);江苏省自然科学基金(No.BK20180626)。
ZnO具有高稳定性、低成本、宽带隙等优点,被广泛用于光电探测器但响应速度较慢,采用Zn(TFSI)2和CNT∶TiO_(2)作为混合掺杂剂来代替Li-TFSI,以提高Spiro-MeOTAD的稳定性及光电性能,采用旋涂法制备了ZnO/Spiro-MeOTAD异质结构筑光电探测器...
关键词:光电探测器 异质结 旋涂法 ZNO Spiro-MeOTAD 自驱动 
Photocatalytic Site-Selective Cascade Radical Addition of Biaryl Ynones for the Construction of Spiro-and Fused Carbon Rings
《Chinese Journal of Chemistry》2024年第14期1599-1605,共7页Kairui Liu Chunhang Zhao Liji Gu Xiang Li Jiali Yan Siqi Lao Weiwei Huan Yan Zhang 
the Natural Science Foundation of Zhejiang Province(LY22B020001);the Zhejiang Public Welfare Public Research Program(LGC22B010001);the National Natural Science Foundation of China(32201238)is greatly acknowledged.
Functionalized free radical addition/cyclization reactions represent an efficient way for introducing new functionality or coupling fragments to molecules.Ynones are good regional selectivity radical acceptors in orga...
关键词:YNONES Photocatalysis Cascade cyclization Alkoxycarbonyl radical DEAROMATIZATION BIARYLS Regioselectivity Radical reactions 
Chiral multiple-resonance thermally activated delayed fluorescence materials based on chiral spiro-axis skeleton for efficient circularly polarized electroluminescence被引量:1
《Science China Chemistry》2024年第7期2257-2264,共8页Shi-Quan Song Xiao Han Zhong-Zhong Huo Ching-Fai Yip Xian-Fang Hong Meng-Ning Ding You-Xuan Zheng 
supported by the National Natural Science Foundation of China(92256304,U23A20593)。
Chiral luminescence materials have potential applications in the field of three-dimensional displays due to their circularly polarized luminescence(CPL)characteristics.However,the further development of circularly pol...
关键词:chiral spiro-axis skeleton-based material multiple resonance thermally activated delayed fluorescence circularly polarized electroluminescence dissymmetry factor external quantum efficiency 
Iridium-Catalyzed Asymmetric Hydrogenation of Dialkyl Imines
《CCS Chemistry》2024年第4期905-911,共7页Zheng Wang Xin-Yi Yang Yue Xu Qi-Lin Zhou 
supported by the National Key R&D Program of China(grant no.2022YFA1504302);the National Natural Science Foundation of China(grant nos.22188101,91956000,and 92256301);the Fundamental Research Funds for the Central Universities,and the Haihe Laboratory of Sustainable Chemical Transformations.
Asymmetric hydrogenation of dialkyl imines to chiral amines is difficult because the two alkyls of imines are so similar in spatial and electronic structure that chiral catalysts are difficult to distinguish between t...
关键词:spiro PNP ligand iridium catalyst enantioselective hydrogenation dialkyl imines chiral amines 
Spiro-tiger康复训练对青少年运动性哮喘中长跑运动员肺功能与气道修复的影响
《体育科技文献通报》2024年第3期272-274,共3页马骁 
目的:探讨Spiro-tiger康复训练对青少年运动性哮喘中长跑运动员的肺功能和气道修复的影响。观察对照组和实验组进行的不同康复训练过程,结果发现:①Spiro-tiger康复训练在气道重塑、肺功能和血气指标方面表现出显著的优势。②观察组在9...
关键词:Spiro-tiger康复训练 中长跑 肺功能 
Cobalt-Catalyzed Switchable[4+1]and[4+1+1]Spirocyclization of Aromatic Amides with 2-Diazo-1H-indene-1,3(2H)-dione:Access to Spiro Indene-2,1'-isoindolinones and Spiro Isochroman-3,1'-isoindolinones
《Chinese Journal of Chemistry》2024年第4期363-369,共7页Bin Li Mengmeng Xie Jingyu Li Nana Shen Xinying Zhang Xuesen Fan 
the National Natural Science Foundation of China(22101075,U2004189);Central Plains Science and Technology Innovation Leader Project(224200510009);Postdoctoral Research Grant in Henan Province(202103085);Henan Key Laboratory of Organic Functional Molecules and Drug Innovation,and 111 Project(D17007)for financial support.
Herein,we report a condition-controlled divergent synthesis of spiro indene-2,1'-isoindolinones and spiro isochroman-3,1'-isoindolinones through cobalt-catalyzed formal[4+1]and[4+1+1]spirocyclization of aromatic amide...
关键词:Spiro indene-2 1'-isoindolinones Spiro isochroman-3 1'-isoindolinones 3d Transition metals Cobalt-catalyzed C-H Activation Switchable[4+1]and[4+1+1]spirocyclization Aromatic amides 2-Diazo-1H-indene-1 3(2H)-dione 
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