SPIRO

作品数:174被引量:144H指数:5
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相关领域:理学电气工程更多>>
相关作者:李福民陈冲郑小璐石东王杰更多>>
相关机构:电子科技大学河南大学合肥工业大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划高等学校学科创新引智计划国家高技术研究发展计划更多>>
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Revealing a new doping mechanism of spiro-OMeTAD with tBP participation through the introduction of radicals into HTM
《Chinese Chemical Letters》2025年第3期170-176,共7页Jindan Zhang Zhenghong Li Chi Li Mengqi Zhu Shicheng Tang Kaicong Cai Zhibin Cheng Chulong Liu Shengchang Xiang Zhangjing Zhang 
supported by the National Natural Science Foundation of China(Nos.52001066,21805039,22375045,22373015 and 22271046);the Natural Science Foundation of Fujian Province(No.2023J01500);Young teacher training program of Fujian Normal University(No.SDPY2023013).
Although lots of efforts have been devoted on new less hygroscopic dopants to address problems in hole transport materials(HTM),the long-time post-oxidation and the volatilization of 4-tert-butylpyridine(tBP)are still...
关键词:Perovskite solar cells Hole transport layer DOPANTS Spiro-OMeTAD oxidation Hole mobility conductivity 
Improving redox reactions of Spiro-OMeTAD via p-type molecular scaffold to reduce energy loss at Ag-electrode in perovskite solar cells
《Journal of Energy Chemistry》2025年第3期151-160,共10页Peng Wang Shafidah Shafian Feng Qiu Xiao Zhang Yuping Zhao Bin Wu Kyungkon Kim Yong Hua Lin Xie 
the National Natural Science Foundation of China(22209144);the Project of the Natural Science Foundation of Yunnan;the Yunnan Revitalization Talent Support Program(202201AU070030 and 202201AT070114);the support from the National Natural Science Foundation of China(22065038);the High-Level Talents Introduction in Yunnan Province(C619300A010);the Fund for Excellent Young Scholars of Yunnan(202001AW070008);financial support from the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)under grant number RS-2024-00444389。
2,2',7,7'-Tetrakis(N,N-di(4-methoxyphenyl)amino)-9,9'-spirobifluorene(Spiro)is an essential hole-transport material used in perovskite solar cells(PSCs).However,the redox reaction of Spiro and its impact at the interf...
关键词:Perovskite solar cells Hole transport layer Hole collection Energy alignment Charge recombination 
Catalytic production of high-energy-density spiro polycyclic jet fuel with biomass derivatives
《Journal of Energy Chemistry》2025年第2期760-768,I0016,共10页Wen-Jing Zhang Yan-Cheng Hu Yan-Hong Tan Jia Li Ning Li Jing-Pei Cao 
supported by the Fundamental Research Funds for the Central Universities(2023QN1009);Xuzhou Basic Research Project(KC23018);China University of Mining and Technology(CUMT)Open Sharing Fund for Large-scale Instruments and Equipment(DYGX-2024-34);Priority Academic Program Development of Jiangsu Higher Education Institutions.
High-energy-density(HED)fuel(e.g.widely used JP-10 and RJ-4),featuring compact 3D polycyclic structure with high strain,is of critical importance for volume-limited military aircraft,since their high density and combu...
关键词:Biomass derivatives High-energy-density Spiro polycyclic fuel Cycloaddition Lewis acidic ionic liquid 
Deciphering fungal metabolon coupling tandem inverse-electrondemand Diels-Alder reaction and semipinacol rearrangement for the biosynthesis of spiro polycyclic alkaloids
《Science China Chemistry》2025年第1期288-296,共9页Shuai Liu Wen-Qiang Xu Ying-Tong Di Man-Cheng Tang Ding-Kang Chen Ming-Ming Cao Yao-Wen Chang Hong-Yu Tang Chun-Mao Yuan Jun-Bo Yang Zhi-Li Zuo Han Guo Zi-Fei Xu Ying Zeng Yun-Dong Wu Xiao-Jiang Hao 
supported by the National Natural Science Foundation of China(U1812403 to Xiao-Jiang Hao,2193304 to Yun-Dong Wu,81573323 and 31770392 to Ying-Tong Di,and 22177050 to Ming-Ming Cao);the Project of Yunnan Characteristic Plant Screening and R&D Service CXO Platform(2022YKZY001);the Yunnan Provincial Science and Technology Department(202003AD150012 to Xiao-Jiang Hao,202201AS070040 and 202302AA310035 to Ying-Tong Di)。
In the intricate process of natural product biosynthesis,a metabolon can enhance metabolic flux by associating sequential enzymes.A fungal metabolon,comprising of flavin-dependent monooxygenase Spe F and P450 monooxyg...
关键词:METABOLON Diels-Alder reaction semipinacol rearrangement biosynthesis notoamides spiro polycyclic alkaloids 
De Novo Design of Spiro-Type Hole-Transporting Material:Anisotropic Regulation Toward Efficient and Stable Perovskite Solar Cells
《Research》2024年第4期487-497,共11页Xuran Wang Mingliang Wang Zilong Zhang Dong Wei Shidong Cai Yuheng Li Rui Zhang Liangliang Zhang Ruidan Zhang Chenhui Zhu Xiaozhen Huang Feng Gao Peng Gao Yang Wang Wei Huang 
supported by the National Natural Science Foundation of China(grant no.52002070);the Natural Science Foundation Project of Fujian Province(nos.2023J01527 and 2020J01197);X-ray data were acquired at beamline 7.3.3 at the Advanced Light Source,which is supported by the Director,Office of Science,Office of Basic Energy Sciences,of the U.S.Department of Energy(DE-AC02-05CH11231).
2,2′,7,7′-Tetrakis(N,N-di-p-methoxyphenyl)-amine-9,9′-spirobifluorene(Spiro-OMeTAD)represents the state-of-the-art hole-transporting material(HTM)in n-i-p perovskite solar cells(PSCs).However,its susceptibility to ...
关键词:Solar PEROVSKITE SKELETON 
trans-4'a-Methyl-3',4'a,9',10',10'a-hexahydro-spiro[cyclobutane-1,1'(2H)-phenanthrene]的全合成
《有机化学》2024年第11期3386-3391,共6页戴伟昊 霍晨雨 郑天禄 朱道勇 王少华 
国家重点研发计划(No.2023YFA1506404);甘肃省科技计划(Nos.23ZDFA003,23JRRA1144,23JRRA1028,23CXGA0043);兰州市科技计划(Nos.2023-1-17,2023-QN-18);中央高校基本科研业务专项(Nos.lzujbky-2022-ct03,lzujbky-2022-sp09,lzujbky-2023-ct02,lzujbky-2023-pd08);陇药协同创新中心和甘肃省药物研发计划(No.2022GSMPA0010)资助项目。
以苯丙醛为起始原料,通过两种策略的使用完成trans-4'a-methyl-3',4'a,9',10',10'a-hexahydro-spiro[cyclobutane-1,1'(2H)-phenanthrene]的首次全合成.具体的关键步骤分别为金催化的1,3-酰基迁移/串联环化和InI3催化的多烯环化.
关键词:trans-4'a-methyl-3' 4'a 9' 10' 10'a-hexahydro-spiro[cyclobutane-1 1'(2H)-phenanthrene] 全合成 天然产物 
以Spiro-OMeTAD作为空穴传输层的ZnS/SnS太阳能电池模拟研究
《人工晶体学报》2024年第8期1394-1408,共15页唐华著 肖清泉 付莎莎 谢泉 
贵州大学智能制造产教融合创新平台及研究生联合培养基地(2020-520000-83-01-324061);贵州省智慧化服务工程研究中心(2203-520102-04-04-298868);贵阳市科技平台建设项目(筑科合同[2023]7-3)。
硫化亚锡(SnS)因其合适的电学和光学特性而被作为太阳能电池的吸收层进行研究。Spiro-OMeTAD常用作空穴传输层以提高太阳能电池性能。本文采用wxAMPS软件对SnS基太阳能电池ZnS/SnS/Spiro-OMeTAD进行模拟研究。主要研究分析Spiro-OMeTAD...
关键词:硫化亚锡 硫化锌 Spiro-OMeTAD 空穴传输层 异质结太阳能电池 wxAMPS 缺陷 
ZnO/Spiro-MeOTAD异质结自驱动光电探测器的制备及性能(特邀)
《光子学报》2024年第7期58-67,共10页李朋凡 黄雨欣 俞学伟 冯仕亮 姜岩峰 闫大为 于平平 
国家自然科学基金(No.51802124);江苏省自然科学基金(No.BK20180626)。
ZnO具有高稳定性、低成本、宽带隙等优点,被广泛用于光电探测器但响应速度较慢,采用Zn(TFSI)2和CNT∶TiO_(2)作为混合掺杂剂来代替Li-TFSI,以提高Spiro-MeOTAD的稳定性及光电性能,采用旋涂法制备了ZnO/Spiro-MeOTAD异质结构筑光电探测器...
关键词:光电探测器 异质结 旋涂法 ZNO Spiro-MeOTAD 自驱动 
Photocatalytic Site-Selective Cascade Radical Addition of Biaryl Ynones for the Construction of Spiro-and Fused Carbon Rings
《Chinese Journal of Chemistry》2024年第14期1599-1605,共7页Kairui Liu Chunhang Zhao Liji Gu Xiang Li Jiali Yan Siqi Lao Weiwei Huan Yan Zhang 
the Natural Science Foundation of Zhejiang Province(LY22B020001);the Zhejiang Public Welfare Public Research Program(LGC22B010001);the National Natural Science Foundation of China(32201238)is greatly acknowledged.
Functionalized free radical addition/cyclization reactions represent an efficient way for introducing new functionality or coupling fragments to molecules.Ynones are good regional selectivity radical acceptors in orga...
关键词:YNONES Photocatalysis Cascade cyclization Alkoxycarbonyl radical DEAROMATIZATION BIARYLS Regioselectivity Radical reactions 
Chiral multiple-resonance thermally activated delayed fluorescence materials based on chiral spiro-axis skeleton for efficient circularly polarized electroluminescence被引量:1
《Science China Chemistry》2024年第7期2257-2264,共8页Shi-Quan Song Xiao Han Zhong-Zhong Huo Ching-Fai Yip Xian-Fang Hong Meng-Ning Ding You-Xuan Zheng 
supported by the National Natural Science Foundation of China(92256304,U23A20593)。
Chiral luminescence materials have potential applications in the field of three-dimensional displays due to their circularly polarized luminescence(CPL)characteristics.However,the further development of circularly pol...
关键词:chiral spiro-axis skeleton-based material multiple resonance thermally activated delayed fluorescence circularly polarized electroluminescence dissymmetry factor external quantum efficiency 
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