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Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects: 《无机化学学报》2025年第1期201-212,共12页HUANG Rui LIU Shengjie WU Qingyuan ZHENG Nanfeng; 国家自然科学基金(No.92261207,22388102);新基石科学基金;中国博士后科学基金(No.2023M732946);国家资助博士后研究人员计划(No.GZB20230380)资助。; The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts c...; 关键词：halogenated nitroaromatic heterogeneous catalysis HYDROGENATION selectivity control interfacial effect

Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics:A combined experimental and theoretical study: 《Chinese Chemical Letters》2024年第8期514-519,共6页Longlong Geng Huiling Liu Wenfeng Zhou Yong-Zheng Zhang Hongliang Huang Da-Shuai Zhang Hui Hu Chao Lv Xiuling Zhang Suijun Liu; supported by the National Natural Science Foundation of China(Nos.21902022,81903501,21601028);Qingchuang Science and Technology Plan of Shandong Province(No.2021KJ054);the Natural Science Foundation of Shandong Province(Nos.ZR2018LB018,ZR2019QB026,ZR2022QB058,ZR2020KB014);Scientific Research Foundation of Dezhou University(Nos.30101905,30102708,30102701).; Metal-organic frameworks(MOFs)functionalized with open metal sites(OMSs)have received widespread attention in various applications due to their fascinating electronic properties and unique interactions with guest mole...; 关键词：Metal-organic frameworks Open metal sites CATALYSIS Copper node 4-NITROPHENOL

Tough lanthanide luminescent hydrogel for nitroaromatics detection: 《Journal of Rare Earths》2024年第2期293-302,I0003,共11页Shu Xie Fei Li Fengyi Liu Quanqing Xu Xufeng Zhang; Project supported by the National Natural Science Foundation of China(21661034);Reserve Talents Project for Youth and Middle-Aged Academic and Technical Leaders of Yunnan Province(202205AC160032)。; Luminescent hydrogels have received considerable attention in the application of sensors.Nitroaro matics are harmful to human health and can be carcinogenic.Some skin allergies and central nervous system injuries may ...; 关键词：HYDROGELS LANTHANIDE Luminescence NITROAROMATICS Sensors Rare earths

Nanostructured Ni-MoCx:An efficient non-noble metal catalyst for the chemoselective hydrogenation of nitroaromatics被引量：2: 《Nano Research》2023年第7期8919-8928,共10页Yifei Zhang Zhiwen Li Jingjing Zhang Liangliang Xu Zhong-Kang Han Alfons Baiker Gao Li; We thank the National Natural Science Foundation of China for supporting this work(No.22172167);The 1W1B beamline of Beijing Synchrotron Radiation Facility and BL14W1 beamline of Shanghai Synchrotron Radiation Facility are acknowledged for providing the beam time.; Catalysts for chemoselective hydrogenation are of vital importance for the synthesis of various important chemicals and intermediates.Herein we developed a simple method for preparing a highly efficient Ni-MoC_(x)nano...; 关键词：Ni-MoC_(x)nanocomposite carburization of polyoxometalate HYDROGENATION NITROAROMATICS synergistic effect

Magnetic graphene oxide-anchored Ni/Cu nanoparticles with a Cu-rich surface for transfer hydrogenation of nitroaromatics被引量：1: 《Chinese Journal of Chemical Engineering》2022年第10期235-246,共12页Hongbin Shi Qing Liu Xiaofeng Dai Teng Zhang Yuling Shi Tao Wang; supported by the National Natural Science Foundation of China(Grant No.21776161)。; The bimetallic nanoparticles compositing of Ni-rich core and Cu-rich shell(Ni/Cu NPs)were successfully synthesized by a liquid-phase thermal decomposition method.The content of copper and nickel in Ni/Cu NPs was contr...; 关键词：NITROAROMATICS Transfer hydrogenation Copper-nickel bimetals Core–shell nanoparticles Magnetic catalysts

Zinc modification of Ni-Ti as efficient Ni_(x)Zn_(y)Ti_(1)catalysts with both geometric and electronic improvements for hydrogenation of nitroaromatics: 《Frontiers of Chemical Science and Engineering》2022年第4期461-474,共14页Pingle Liu Yu Liu Yang Lv Wei Xiong Fang Hao Hean Luo; supported by the National Natural Science Foundation of China(Grant Nos.22078277,21908185);Project of Hunan Provincial Education Department(Grant Nos.19B572,20B547);the Collaborative Innovation Center of New Chemical Technolo gies Technolo gies for Environmental Benignity and Efficient Resource Utilization,and the National Department of Education Engineering Research Centre for Chemical Process Simulation and Optimization。; The catalytic hydrogenation of nitroaromatics is an environmentally friendly technology for aniline production,and it is crucial to develop noble-metal-free catalysts that can achieve chemoselective hydrogenation of n...; 关键词：bimetal strategy oxygen vacancy non-noble metal catalyst HYDROGENATION aromatic nitro compounds

Non-contact biomimetic mechanism for selective hydrogenation of nitroaromatics on heterogeneous metal nanocatalysts: 《Science China Chemistry》2022年第4期726-732,共7页Wenting Zhou Laiyang Li Ruixuan Qin Jiaxin Zhu Shengjie Liu Shiguang Mo Zaifa Shi Huihuang Fang Pengpeng Ruan Jun Cheng Gang Fu Nanfeng Zheng; supported by the National Key Research and Development Program of China(2017YFA0207302);the National Nature Science Foundation of China(21890752,21731005,22072116,92045303);support from the Tencent Foundation through the XPLORER PRIZE;the XAFS Station(BL14W1)of the Shanghai Synchrotron Radiation Facility(SSRF)。; While the enzymatic reduction of unsaturated compounds usually has high specificity,highly selective reduction processes are hardly realized by heterogeneous industrial catalysts,which is critical for the green produc...; 关键词：hydrogenation catalysis NITROAROMATICS proton/electron separation non-contact hydrogenation biomimetic mechanism

Cavity-directed nitroaromatics sensing within a carbazole-based luminescent supramolecular M2L3 cage: 《Chinese Chemical Letters》2020年第1期95-98,共4页Tianchi Feng Xuezhao Li Jinguo Wu Cheng He Chunying Duan; the National Natural Science Foundation of China (Nos.21861132004 and 21701019);China Postdoctoral Science Foundation (No.2018M630286); The design and preparation of luminescent M2L3 metal-organic cage via the coordination-driven selfassembly of carbazole-based ligand with a V-shaped geometry is described.The cage Zn-L1 with an open cavity which equip...; 关键词：Metal-organic cage Host-guest recognition Picric acid Fluorescence

General Reductive Amination of Aldehydes and Ketones with Amines and Nitroaromatics under H2 by Recyclable Iridium Catalysts被引量：2: 《Chinese Journal of Chemistry》2017年第9期1371-1377,共7页Dejun Sui Fei Mao Haipeng Fan Zhengliang Qi Jun Huang; Heterogeneous iridium catalysts were prepared and applied for the reductive amination of aldehydes and ketones with nitroaromatics and amines using H2. The iridium catalysts were prepared by pyrolysis of ionic liquid ...; 关键词：reductive amination IRIDIUM AMINES NITROAROMATICS ALDEHYDES

Catalytic Hydrogenation of Aromatic Compounds in the Liquid Phase: 《Journal of Chemistry and Chemical Engineering》2012年第12期1074-1082,共9页Milan Králik Mária Turáková Ivan Macák Stefan Wenchich; Peculiarities of a liquid phase hydrogenation, namely lower diffusivity of components influencing the reaction rate and deactivation of catalysts by leaching, are discussed. A focus is on hydrogenation of aromatic com...; 关键词：HYDROGENATION NITROAROMATICS ANILINE DICYCLOHEXYLAMINE 4-AMINODIPHENYLAMINE slurry reactors.

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