National Natural Science Foundation of China(Nos.21971174 and U2267224),PAPD,Cyrus Tang(Zhongying)Scholar,Jiangsu Qing-Lan Project for Young and Middle-aged Academic Leaders(2023)and Soochow University for financialsupport.
Unsymmetric sulfides and selenides have great applications in the pharmaceutical field.Herein,we describe the reductive coupling reaction of xanthate esters with sulfur-containing and selenium-containing compounds(thi...
Project supported by the National Natural Science Foundation of China (No. 20572079), the Natural Science Foundation of Zhejiang Province (Nos. Y205540 and Y404039) and the Wenzhou University Postgraduate Innovation Foundation (No. YCX0514).
Reduced species (HSO2^-, SO2^·-) promoted one-pot synthesis of phenyl alkyl selenides has been developed. This synthetic method was achieved by reactions of diphenyl diselenide with alkyl halides at room temperatur...
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 0 0 62 0 0 2 )
Based on the different reactivity of selanyl and bromo groups,( E)-α- bromovinylselenides can undergo sequential cross coupling reactions with nucleophiles in the presence of transition metal complexes to form two ca...
Areneselenyl or alkaneselenyl magnesium bromide reacts rapidly with diaryliodonium salt to give the corresponding diaryl or alkyl aryl selenide in the presence of catalytic amounts of Pd-(PPh3)4 in good yield.
theEngineeringScienceResearchCenterofZhejiangUniversityofTechnology China
Ytterbium metal reacts with iodine to generate ytterbium diiodide directly, which can react with diselenides to form ytterbium selenolates (RSeYbI2). These species reacted smoothly with allyl bromide to give allylsele...
Project supported by the National Natural Science Foundation of China (Nos.29872010 and 294938004), the Natural Science Foundation of Zhejiang Province and the Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Acade
Allyl and benzyl selenides were synthesized via reactions of allyl and benzyl bromides and diselenides promoted by Sm/Sb-Cl3 system in aqueous media in moderate to good yields.
Project supported by the National Natural Science Foundation of China (No. 29493804);the Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China
This paper describes the progress on the synthesis of organic selenides and tellurides and their application in organic synthesis. Low dent selenium and telluronium compounds having high reducing selectivity can be us...