DIFLUOROMETHYLATION

作品数：20被引量：27H指数：3
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Photoexcitation of Dihydroquinazolinone Anionic Compounds:Difluoroalkylarylation and Difluoroalkylamination of Alkenes被引量：1
《CCS Chemistry》2024年第10期2549-2559,共11页Jian-Xiong Yang Jia-Qing Hu Qi Wen Jie Xu Yan Zhang Heng Jiang 
the National Natural Science Foundation of China(grant nos.22101176 and 22137003).
The direct excitation of dihydroquinazolinone(DHQ)anions by visible light has been demonstrated by photophysical experiments.The excited-state DHQ anion serves as both a potent reductant and a radical precursor in a r...
关键词：excited state anion difluoromethyl radical DIFLUOROMETHYLATION PHOTOCHEMISTRY radical chemistry 
Pentacoordinate Phosphoranes as Versatile Reagents in Fluoroalkylation Reactions
《CCS Chemistry》2024年第1期165-176,共12页Huanhuan Song Weihao Li Xiaoying Wang Kaiteng Wang Jingwen Li Shuai Liu Pin Gao Xin-Hua Duan Jinbo Hu Mingyou Hu 
supported by National Natural Science Foundation of China(grant no.21901196);the Natural Science Basic Research Plan in Shaanxi Province of China(grant nos.2020JQ-016 and 2021GXLH-Z-096);the Fundamental Research Funds for the Central Universities(grant no.xhj032021007-01);Xi’an Jiaotong University(grant no.71211920000001).
A general method for the synthesis of bench-stable bis(difluoromethyl)pentacoordinate phosphoranes has been developed.The reaction is rapid,operationally simple,and easily scalable.The pentacoordinate phosphoranes can...
关键词：pentacoordinate phosphorane difluoromethyl radical DIFLUOROCARBENE DIFLUOROMETHYLATION FLUOROALKYLATION 
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