the National Natural Science Foundation of China(Nos.21971001 and 21702001);the Natural Science Foundation of Anhui Province(No.1808085MB47),for financial support。
Herein,we report an efficient photochemical method for the synthesis of poly-substituted pyrazoles through a multicomponent reaction of acceptor-only diazoalkanes,alkynes,and solvents(cyclic ethers or nitriles).The ke...
the National Natural Science Foundation of China(Nos.22071242 and 21871260);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);Fujian Natural Science Foundation(No.2018J05035);Science and Technology Research Program of the Education Department of Jiangxi Province(No.GJJ1991151)。
Copper-catalyzed divergent annulations betweenα-diketones and alkynylα-diketones have been achieved,delivering a series of highly functionalized and biologically important cis-hexahydro-2Hcyclopenta[b]furan(HCPF)and...
the financial support from China Postdoctoral Science Foundation(No.2019T120843);Sichuan Science and Technology Program(No.2019YJ0091)。
It is generally recognized that the formation and accumulation of iron oxides on the surface of zero-valent iron(Fe^(0))resulting in significant decrease of contaminant degradation rates during the long-term reactions...
One of the crucial parameters determining the electron transfer rate, Franck-Condon factor, ws evaluated quantitatively for electron exchange reactions involving hexaquo-metal ions. Adopting appropriate spectroscopic ...
The Sequence of homogeneous catalytic reactivity of triphenylphosphine complexes of Ru, Rh, Pd, Fe, Co, Ni in the maleic anhydride hydrogenation is:Rucl2 (PPh3)3> RhCI (PPh3)3> NiCI2 (PPh3)2>CoCl2 (PPh3) 2> FeCI2 (PPh...
Relative reactivities of polyhalofluoroalkanes toward bromophilic or chlorophilic attacks have been evaluated for the first time by comparing the rates of halophilic attacks by a carbanion derived from the addition of...