Carbon-carbon bond formation is the core of organic synthesis.Transition metal-catalyzed cross-coupling reaction between organohalides and organometallic reagents is one of the most important and straightforward metho...
An ideal strategy for catalyst immobilization is taking advantage of the widely well studied homogeneous molecular catalysts and transforming them directly into highly efficient and recyclable heterogeneous catalysts....
Ecole Polytechnique;CNRS;DGA;MNRT;The Fondation Alfred Kastler;the Royal Commission for the Exhibition of 1851;the China Research Council;Aventis(now Sanofi);Rhodia(now Solvay);Syngenta
This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. Itsummarizes the various approaches to the synthesis of tertiary xanthates then describes ...
Project supported by the National Natural Science Foundation of China (Grant No. 29672004)
Tandem asymmetric double Michael addition/internal nucleophilic substitution of the novel chiral source, 5-(l-menthyloxy)-3-bromo-2(5H)-furanone with nucleophilic alcohol compounds has been investigated. The tandem as...
Project supported by the National Natural Science Foundation of China.
High temperature (from room temperature to 773 K) thermoluminescence of BaFCl: Eu2+ is reported. Three new glow peaks have been found to be caused respectively by F2-, F3 - and F4- centers which are the aggregates of ...
Project supported by the National Natural Science Foundation of China.
V centers (hole centers) and hole-photostimulated luminescence of BaFCl crystal are reported for the first time. The absorption bands of V1, V2 and V3 centers are peaking at 205, 238 and 355 nm respectively. V2 center...