Seven transition metal complexes of Mn2+, Ni2+, Co2+, Cu2+ and Zn2+ with 3-aminopyridine (3-APy) as ligand have been synthesized, characterized by different techn...
Reaction of zinc acetate, potassium thiocyanate and the ligand 3-ampy gave the discrete tetrahedral complex [Zn(NCS)2(3-ampy)2] in which 3-ampy chelates in a monodentate fashion through its pyrid...
supported by the National Natural Science Foundation of China(21473226,21773273);Key Research Program of Frontier Sciences,CAS(QYZDJ-SSW-SLH051);Natural Science Foundation of Jiangsu Province(BK20170420)~~
Three chiral aminopyridine ligands derived from L-proline were prepared. Careful evaluation of the corresponding aminopyridine manganese complexes in asymmetric epoxidation of olefins revealed a broad substrate scope ...
supported by the Research Council of the University of Mazandaran in Iran
The three-component reaction of 4-hydroxy-l-methyl-2(1H)-quinolinone, aromatic aldehydes and ethyl cyanoacetate was carried out in the presence of a catalytic amount of 4-dimethyl aminopyridine (DMAP) in aqueous e...
Supported by the National Natural Science Foundation of China (No. 20973172, 21071145);the National Basic Research Program of China (No. 2009CB220009)
Two diiron dithiolate complexes, (μ-pdt)Fe2(CO)5(C7H10N2) 3 and (μ-edt)-Fe2(CO)5(C7H10N2) 4 (pdt = -S(CH2)3S-, edt = -S(CH2)2S-), have been synthesized and characterized by single-crystal X-ray dif...
This paper explores the correlation of electro-optical properties with dielectric properties of an organic single crystal. The optical constants of the organic aminopyridine single crystal have been studied. The secon...
Supported by the National Natural Science Foundation of China(No.20972132)
The three-component reaction of aromatic aldehyde,malononitrile and aliphatic amine in a mixed solvent of methanol and water exhibited very interesting molecular diversity and gave the derivatives of polysubstituted N...
supported by the Science Foundation for the Excellent Youth Scholars of Higher Education of Shanghai;Innovation Foundation of Shanghai University
Hydrothermal reaction of 3-aminopyridine, NaSCN and cadmium cation led to the formation of complex [Cd(3-ampy)(NCS)2]n 1 (3-aminopyridine = 3-ampy), and its crystal structure was determined by X-ray diffraction ...
the Natural Science Found Council of China (Nos. 20671011, 20331010, 90406002 and 90406024) ;the Key Laboratory of Structural Chemistry Foundation (No. 060017)
A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2), b =...
supported by the National Natural Science Foundation of China (Grant Nos. 20272028 and 90306009).
An inclusion complex (1) has been prepared by β-cyclodextrin with α-aminopyridine. The result of X-ray crystallographic analyses showed that the α-aminopyridine molecules in the β-cyclodextrin cavities possess two...