National Natural Science Foundation of China (Grant No. 20772009)
The fragmentation patterns of a series of dispirocyclopiperazinium dibromides with strong analgesic activity during positive ion electrospray ionization mass spectrometry were analyzed. The [M-Br]^+ 2 ions showed the...
Supported by the National Natural Science Foundation of China (Grant No. 10576017).
A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The...
Project supported by the National Natural Science Foundation of China(No.29872010);the Natural Science Foundation of Zhejiang Province(No.298067)
The ? ?vicinal dibromo carboxylic acid and its derivatives were debrominated with Sm/HOAc system to afford the corresponding cinnamic acid and its derivatives in good yields under mild conditions.
In the presence of equimolar triethylamine,vicinal dibromides were found to be easily debrominated by dibutyl telluride,forming the co- rresponding olefins.