We gratefully acknowledge National Natural Science Foundation of China(22101291,22171277,21821002);National Key R&D Program of China(2021YFA1500200);Shanghai Rising-Star Program(20QA1411400);Shanghai Institute of Organic Chemistry,and State Key Laboratory of Organometallic Chemistry for finan cial support.
Comprehensive Summary A novel transient SET mediator approach has been developed for the photoinduced radical-radical cross coupling reaction.Using the in-situ generated thianthrene radical cation as the transient SET...
supported by the National Natural Science Foundation of China(51873077,91833304,and 51803071);the National Basic Research Program of China(2016YFB0401001);the Postdoctoral Innovation Talent Support Project(BX20180121);the China Postdoctoral Science Foundation(2018M641767),and JLUSTIRT(2019TD-33).
In order to develop pure organic single-molecule white-light emitters(SMWLE),the oxidation of thianthrene(TA)was performed on sulfur atoms at different degrees to tune room temperature phosphorescence(RTP)emission.Wit...
the National Natural Science Foundation of China (Nos. 20372077 and 90206005).
Trans-5,10-bis(1-bromodifluoroacetyl-1-ethoxycarbonyl-methylidene)thianthrene (1b) was prepared from the reaction of BrCF2COC(N2)CO2Et with thianthrene. X-ray single crystal diffraction analysis showed that the inter-...
Project supported by the National Natural Science Foundation of China.
Significant 1H/2H and 32S/ 33S isotope effect has been found in the electron transfer reaction of thianthrene and its radical cation perchlorate. This effect may be used to establish a new effective approach to isotop...