THIANTHRENE

作品数:4被引量:2H指数:1
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相关期刊:《Science China Chemistry》《Chinese Journal of Chemistry》《CCS Chemistry》更多>>
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Thianthrene Radical Cation as a Transient SET Mediator:Photoinduced Thiocyanation and Selenocyanation of Arylthianthrenium Salts被引量:1
《Chinese Journal of Chemistry》2023年第16期1979-1986,共8页Xiao-Yue Chen Xin Kuang Yichen Wu Jian Zhou Peng Wang 
We gratefully acknowledge National Natural Science Foundation of China(22101291,22171277,21821002);National Key R&D Program of China(2021YFA1500200);Shanghai Rising-Star Program(20QA1411400);Shanghai Institute of Organic Chemistry,and State Key Laboratory of Organometallic Chemistry for finan cial support.
Comprehensive Summary A novel transient SET mediator approach has been developed for the photoinduced radical-radical cross coupling reaction.Using the in-situ generated thianthrene radical cation as the transient SET...
关键词:Transient SET mediator Thiocyanation and selenocyanation Arylthianthrenium salts Radical reaction Photosynthesis 
Modulating Room Temperature Phosphorescence by Oxidation of Thianthrene to Achieve Pure Organic Single-Molecule White-Light Emission被引量:1
《CCS Chemistry》2021年第7期1940-1948,共9页Yating Wen Haichao Liu Shi-Tong Zhang Guocui Pan Zhiqiang Yang Tong Lu Bao Li Jungang Cao Bing Yang 
supported by the National Natural Science Foundation of China(51873077,91833304,and 51803071);the National Basic Research Program of China(2016YFB0401001);the Postdoctoral Innovation Talent Support Project(BX20180121);the China Postdoctoral Science Foundation(2018M641767),and JLUSTIRT(2019TD-33).
In order to develop pure organic single-molecule white-light emitters(SMWLE),the oxidation of thianthrene(TA)was performed on sulfur atoms at different degrees to tune room temperature phosphorescence(RTP)emission.Wit...
关键词:single-molecule white light room temperature phosphorescence THIANTHRENE lone pair electrons spin–orbital coupling 
Co-existing Intermolecular Halogen Bonding and Hydrogen Bonding in the Compound Trans-5,10-bis(1-bromodifluoro- acetyl-1-ethoxycarbonyl-methylidene)thianthrene
《Chinese Journal of Chemistry》2004年第9期896-898,共3页祝诗发 朱士正 廖远熹 黄超峰 黎占亭 
the National Natural Science Foundation of China (Nos. 20372077 and 90206005).
Trans-5,10-bis(1-bromodifluoroacetyl-1-ethoxycarbonyl-methylidene)thianthrene (1b) was prepared from the reaction of BrCF2COC(N2)CO2Et with thianthrene. X-ray single crystal diffraction analysis showed that the inter-...
关键词:halogen bond hydrogen bond sulfur ylide X-ray diffraction study 
~1H/~2H and ^(32)S/^(33)S isotope effect in the electron transfer reaction of thianthrene and its radical cation
《Science China Chemistry》1995年第3期273-279,共7页刘中立 吕建明 杨立 陈平 王锡禄 刘有成 
Project supported by the National Natural Science Foundation of China.
Significant 1H/2H and 32S/ 33S isotope effect has been found in the electron transfer reaction of thianthrene and its radical cation perchlorate. This effect may be used to establish a new effective approach to isotop...
关键词:RADICAL CATION ELECTRON TRANSFER ISOTOPE effect. 
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