The precise synthesis of subporphyrinoid hybrids withπ-expanded topologies and unique material properties plays a promising role in the design of functional macrocycles.Easy,selective,and controllable routes to boron...
support by the National Natural Science Foundation of China(grant nos.22022510 and 51873039);the Science and Technology Innovation Program of Hunan Province(grant no.2021RC2086).
The efficient synthesis of ultrathin crystalline twodimensional(2D)polymers with well-defined repeating units is essential to realize their broad applications but remains a great challenge.Herein,we report a new strat...
This work was financially supported by National Key R&D Program of China(No.2021YFA1500100);the NSF of China(Grants 21821002,21772222,and 91956112);the S&TCSM of Shanghai(Grants 18JC1415600 and 20JC1417100);Bayer AG(Germany).
Electrochemical nickel-catalyzed syntheses of triphenylenes by a)reductive trimerization of ortho-dibromobenzenes or ortho-bromoarylsulfurofluoridates,or b)reductive cross-coupling of ortho-dibromobenzenes to 2,2’-di...
support from the Research Program of the Chinese Academy of Sciences(No.XDB30000000);the National Natural Science Foundation of China(Nos.21633012,61890940,and 21922511);the National Basic Research Program of China the Strategic Priority(2016YFA0200101 and 2018YFA0703200);the CAS Key Research Program of Frontier Sciences(QYZDY-SSWSLH029).
The synthesis of new C–C bonded two-dimensional(2D)covalent organic frameworks(COFs)is highly desirable.Here,a simple but effective synthetic strategy has been developed using an irreversible Brønsted acid-catalyzed ...
support from the Research Program of the Chinese Academy of Sciences(No.XDB30000000);the National Natural Science Foundation of China(Nos.21633012,61890940,and 21922511);the National Basic Research Program of China the Strategic Priority(2016YFA0200101 and 2018YFA0703200);the CAS Key Research Program of Frontier Sciences(QYZDY-SSWSLH029).
The synthesis of new C–C bonded two-dimensional(2D)covalent organic frameworks(COFs)is highly desirable.Here,a simple but effective synthetic strategy has been developed using an irreversible Brønsted acid-catalyzed ...
Supported by the Research Grants Council of Hong Kong (Grant Nos. 602707, 602706, HKU2/05C and 603505);the National Science Foundation of China (Grant No. 20634020);the Ministry of Science and Technology of China (Grant No. 2002CD613401).
This paper presents a new synthetic route to hyperbranched polymer. An arylene bipropiolate monomer,dimethylmethylenebis(1,4-phenylene) bipropiolate,was prepared by a one-step esterification reaction of bisphenol A wi...
Project supported by the National Natural Science Foundation of China(No. G2000048).
Aliphatic aldehydes such as ethanal, propanal, n-butanal, isobutyraldehyde, n-valeraldehyde, isovaleraldehyde, n-hexanal and n-octanal were converted into the corresponding 2.4,6-trialkyl-1,3,5-trioxanes through cyclo...
Project supported by the National Natural Science Foundation of China (No. 20202002); Hunan Province Education Department (No. 02C211); and Hunan Normal University (2001).
Carbon dioxide was found as a selective agent to promote the palladium-catalyzed cyclotrimerization of alkynes in water. Both aryl and alkylacetylenes afforded the corresponding cyclotrimerization products regioselect...
Nitriles were unexpectedly trimerized into s-triazines or amino-pyrimidines in high yields in the presence of catalytic amount of Li3N, resulting in a simple, solvent-free and easy-to-scale-up one-pot way to synthesiz...