ACYLSILANES

作品数：5被引量：2H指数：1
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Versatile Synthesis ofα-Oxygen Organoboron Compounds via Photo-Induced Siloxycarbene
《Chinese Journal of Chemistry》2024年第22期2712-2716,共5页Xiongxiong Lu Qingbin Zhao Dehai Cao Pan Xu Xuenian Chen Zhenxing Liu 
supported by the National Natural Science Foundation of China(22101261);the Natural Science Foundation of Henan Province(232300421087,232301420045);the Zhengzhou University of China(2023ZZUJGXM168).
A novel method for synthesizingα-oxygen organoboron compounds has been developed through acylsilane-based carbene insertion reactions into C—B bonds.As coupling partners,readily available organoboron compounds(alken...
关键词：ACYLSILANES Siloxy carbenes Organoboron compounds ISOMERIZATION PHOTOCATALYSIS REARRANGEMENT 
Synthesis of Organofluorine Compounds with Acylsilanes被引量：1
《Chinese Journal of Chemistry》2024年第8期887-902,共16页Youyuan Guo Gang Zhou Xiao Shen 
financial support from the National Key R&D Program of China(2022YFA1506100);Fundamental Research Funds for the Central Universities(2042023kf1010,2042023kf0202).
Comprehensive Summary,Organofluorine compounds are central in synthetic chemistry,medicinal chemistry and material chemistry.In this review,we summarize the investigations on the synthesis of organofluorine compounds ...
关键词：ACYLSILANES Organofluorine compounds Brook rearrangement Radical rearrangement β-Fluoride elimination Asymmetric catalysis PHOTOCATALYSIS Defluoroalkylation 
Visible-Light-Induced[4+1]Cyclization-Aromatization of Acylsilanes andα,β-Unsaturated Ketones被引量：1
《CCS Chemistry》2023年第2期325-333,共9页Zhihong Zhu Weilu Zhang Yizhi Zhang Shanshan Liu Xiao Shen 
the National Natural Science Foundation of China(grant no.21901191);the Fundamental Research Funds for the Central Universities,and Wuhan University for financial support.
Herein we report the first[4+1]cyclization-aromatization reaction of acylsilanes andα,β-unsaturated ketones.The unprecedented visible-light-induced reaction proceeded through mild conditions without addition of any ...
关键词：acylsilane α β-unsaturated ketone CARBENE photo chemistry cyclization-aromatization FURAN 
Carbon-oxygen bond formation via visible-light-induced O-H insertion between acylsilanes and oximes
《Green Synthesis and Catalysis》2022年第2期194-197,共4页Bao Gui Cai Qian Li Lei Li Jun Xuan 
We are grateful to the National Natural Science Foundation of China(Nos.21971001,22101002,and 21702001)for financial support.
Visible light promoted C-O bond formation reaction through O-H insertion of acylsilanes with oximes has been developed.The reaction occurred under mild reaction conditions(sole blue LED irradiation in the absence of a...
关键词：Visible light ACYLSILANES Siloxy carbene OXIMES C-O bond formation 
Theoretical Study on Pd-Catalyzed Acylation of Allylic Esters with Acylsilanes and Acylstannanes
《International Journal of Organic Chemistry》2015年第4期246-255,共10页Shohei Sanada Michinori Sumimoto Kenji Hori 
Acylation of allylic esters with acylsilanes and acylstannanes in the presence of a palladium complex was investigated theoretically using the DFT (B3PW91) method. We examined along the reaction that was reported by T...
关键词：ACYLATION PALLADIUM Complex Theoretical Calculation CATALYTIC Cycle 
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