BIMETALLIC

作品数：481被引量：1015H指数：11
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Subnanometric bimetallic Pt-Pd clusters in zeolites for efficient hydrogen production and selective tandem hydrogenation of nitroarenes
《Science China Chemistry》2024年第9期2911-2917,共7页Jiafu Li Tao Cai Yanran Feng Xia Liu Ning Wang Qiming Sun 
supported by the National Key R&D Program of China(2022YFA1506000);the National Natural Science Foundation of China(22105110,22109110,22206094);the Natural Science Foundation of Shandong Province(ZR2021QB162,ZR2023YQ014);the Youth Innovation Team Project of Shandong Provincial Education Department(022KJ143);the Taishan Scholar Youth Expert Program in Shandong Province(tsqn202211122);the Gusu Innovation and Entrepreneurship Leading Talents Program(ZXL2022497);the Jiangsu Distinguished Professor Program;the Natural Science Foundation of Jiangsu Province(BK20210698)。
The solvolysis of ammonia borane(AB)and the hydrogenation of nitroarenes represent significant reactions for hydrogen generation and value-added chemical synthesis.The strategic engineering of the catalysts is imperat...
关键词：subnanometer bimetallic cluster zeolite synergistic effect ammonia borane solvolysis selective tandem hydrogenation 
Efficient photothermal CO_(2) methanation over Ni Fe alloy nanoparticles with enhanced localized surface plasmon resonance effect被引量：2
《Science China Chemistry》2023年第12期3518-3524,共7页Jiarong Li Qi Xu Yaoyao Han Zhiyong Guo Liangqun Zhao Kang Cheng Qinghong Zhang Ye Wang 
supported by the National Natural Science Foundation of China (92145301,22121001,22222206,and U22A20392);the Fundamental Research Funds for the Central Universities (20720220008 and 20720220021)。
The methanation of CO_(2) using green hydrogen not only consumes CO_(2) as a carbon resource but also stores H_(2) with high density.However,the activation of CO_(2) molecules under mild conditions is challenging due ...
关键词：photothermal catalysis BIMETALLIC LSPR effect CO_(2)utilization hydrogen storage 
Asymmetric annulations based on cycloisomerization of cyclopropyl tethered allenyl ketones by bimetallic relay catalysis被引量：1
《Science China Chemistry》2023年第10期2803-2809,共7页Jun He Wen Liu Jing Zhang Ziwei Zhong Lili Lin Xiaoming Feng 
supported by the National Natural Science Foundation of China(21890723,22171189);the Fundamental Research Funds for the Central Universities(YJ201819)。
The diastereo-and enantioselective tandem cycloisomerization/[4+2]-cycloaddition reaction of cyclopropyl tethered allenyl ketones withα,β-unsaturated carbonyl compounds was realized firstly under mild reaction condi...
关键词：asymmetric catalysis bimetallic relay cyclopropyl tethered allenyl ketones [4+2]-cycloaddition furopyran 
Asymmetric synthesis of bedaquiline based on bimetallic activation and non-covalent interaction promotion strategies被引量：1
《Science China Chemistry》2022年第10期1968-1977,共10页Feng Gao Jing Li Tanveer Ahmad Yicong Luo Zhenfeng Zhang Qianjia Yuan Xiaohong Huo Tao Song Wanbin Zhang 
supported by the Bill and Melinda Gates Foundation (INV-008413);the National Natural Science Foundation of China (21831005);Shanghai Jiao Tong University
Bedaquiline(BDQ),approved by Food and Drug Administration(FDA)in 2012 as the first anti-tuberculosis-specific drug in the last 40 years,is viewed as one of the world’s most promising treatments for tuberculosis(TB).D...
关键词：asymmetric synthesis bedaquiline bimetallic system industrial synthetic process DFT computation 
Heterostructured NiS_(2)@SnS_(2) hollow spheres as superior high-rate and durable anodes for sodium-ion batteries被引量：3
《Science China Chemistry》2022年第7期1420-1432,共13页Chongwei Li Jinchuan Hou Jingyi Zhang Xiaoyue Li Shiqi Jiang Guoqing Zhang Zhujun Yao Tiancun Liu Shenghui Shen Zhiqi Liu Xinhui Xia Jie Xiong Yefeng Yang 
funded by Zhejiang Provincial Natural Science Foundation of China (LY21E020010);the National Natural Science Foundation of China (52102315);the Fundamental Research Fund of Zhejiang Sci-Tech University (2021Y005)。
Tin-based sulfides have attracted increasing attention as anodes for sodium-ion batteries(SIBs) owing to their high theoretical capacity;however, the poor rate capability and inferior cycling stability caused by the l...
关键词：ANODE metal-organic frameworks HETEROSTRUCTURE bimetallic sulfide sodium ion battery 
Bimetallic anchoring catalysis for C–H and C–C activation被引量：3
《Science China Chemistry》2021年第11期1923-1937,共15页Jiang-Fei Li Yu-Xin Luan Mengchun Ye 
supported by the National Natural Science Foundation of China(91856104,21871145);the Tianjin Applied Basic Research Project and Cutting-Edge Technology Research Plan(19JCZDJC37900);“Frontiers Science Center for New Organic Matter”,Nankai University(63181206)。
Following the age of directing group,anchoring catalysis starts coming to the center of the stage.Different from the directinggroup strategy that needs a preinstalled directing group in substrates,anchoring catalysis ...
关键词：C–H activation C–C activation bimetallic catalysis ENANTIOSELECTIVE anchoring catalysis 
Effective conversion of cellobiose and glucose to sorbitol using non-noble bimetallic NiCo/HZSM-5 catalyst被引量：3
《Science China Chemistry》2018年第9期1167-1174,共8页Bakht Zada Long Yan Yao Fu 
supported by the National Natural Science Foundation of China (21732006, 21572212);the Strategic Priority Research Program of the CAS (XDB20000000, XDA21060101);Ministry of Science and Technology of China (2017YFA0303502);the Fundamental Research Funds for the Central Universities (WK3530000001);the Major Program of Development Foundation of Hefei Center for Physical Science and Technology (2017FXZY001)
The tandem hydrolysis and hydrogenation of saccharides into sorbitol is an especially attractive reaction in the conversion of biomass. Here, an economical and efficient bimetallic catalyst for the transformation of g...
关键词：BIOMASS SORBITOL GLUCOSE CELLOBIOSE bimetallic catalyst 
Copolymer of lactide and ε-caprolactone catalyzed by bimetallic Schiff base aluminum complexes被引量：3
《Science China Chemistry》2016年第11期1384-1389,共6页Jingwei Yang Zhiqiang Sun Ranlong Duan Lili Li Xuan Pang Xuesi Chen 
A series of copolymers of lactide(LA) and e-caprolactone(ε-CL) with different monomer feed ratios were achieved using three kinds of bimetallic Schiff aluminum complexes as catalysts. The ratios of LA and ε-CL units...
关键词：bimetallic catalyst lactide ε-caprolactone ring opening copolymerization 
Syntheses of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands and their catalytic activity toward the hydrophosphonylation reaction of aldehydes and ketones
《Science China Chemistry》2015年第9期1451-1460,共10页Kun Nie Chengwei Liu Yong Zhang Yingming Yao 
supported by the National Natural Science Foundation of China(21132002,21372172,21402138);the Major Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions(14KJA150007);the Qing Lan Project
A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthe...
关键词：bimetallic lanthanide complex bridged bis（guanidinate） ligand hydrophosphonylation reaction aldehyde ketone 
Bimetallic amine-bridged bis(phenolate) lanthanide aryloxides and alkoxides: synthesis, characterization, and application in the ring-opening polymerization of rac-lactide and rac-β-butyrolactone被引量：3
《Science China Chemistry》2014年第8期1106-1116,共11页NIE Kun FENG Tao SONG FengKui ZHANG Yong SUN HongMei YUAN Dan YAO YingMing SHEN Qi 
financial supported by the National Natural Science Foundation of China (20972108, 21174095, 21132002);a project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD);the Qing Lan Project is gratefully acknowledged
A series of neutral bimetallic lanthanide aryloxides p-C6H4[OLnL(THF)n]2 [Ln = Y(1), Yb(2), Sm(3)(n = 1) and La(4)(n = 2), L = Me2NCH2CH2N{CH2-(2-O–C6H2–tBu2-3,5)}2] and alkoxides p-C6H4CH2[OLnL(THF)]2 [Ln = Y(5), Y...
关键词：amine-bridged bis（phenolate） ligand bimetallic lanthanide aryloxides and alkoxides ring-opening polymerization stereoselectivity 
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