financially supported by the National Natural Science Foundation of China (No.21274041)。
A series of C1-symmetric ethylene-bridged ansa-(3-R-cyclopentadienyl)(fluorenyl) metallocene complexes(Zr: 1-5;Hf: 6) have been synthesized, characterized and investigated as catalyst precursors for the high temperatu...
supported by the National Natural Science Foundation of China(NSFC)(22179037,21788102,and 21905091);Shanghai Municipal Science and Technology Major Project(2018SHZDZX03 and 21JC1401700);Shanghai Municipal Science and Technology(20120710200);the Fundamental Research Funds for the Central Universities and China Postdoctoral Science Foundation(No.2019M651418)
Improving light-harvesting efficiency and suppressing interfacial charge recombination are of paramount importance to the development of Cu(Ⅱ/Ⅰ)redox shuttle-based dye-sensitized solar cells(DSSCs).Here,we present a...
Project supported by National Natural Science Foundation of China(21805143);Natural Science Foundation of Zhejiang Province(LY21B040002);Natural Science Foundation of Ningbo(202003N4110);the K.C.Wong Magna Fund from Ningbo University。
The metathesis reaction between pyrrolidinyl-ethylene fluorenyl lithium salts with in situ prepared cationic rare-earth metal dialkyl species[Ln(CH_(2)SiMe_(3))_(2)(THF)_(x)][BPh_(4)]afford efficiently the correspondi...
support from the National Natural Science Foundation of China(Grant No.21971187);the Natural ScienceFoundationof Tianjin(19JCJQJC62700);the Haihe Laboratory of Sustainable Chemical Transformations。
The synthesis of stable open-shell hydrocarbon system comprising of pentagon defects and zigzag edges remains unexplored,which can be considered as model compounds for unraveling the spin-localized states in graphene ...
the National Natural Science Foundation of China(51873037 and 51503038)。
The cationic group distribution along the polymeric backbones of anion exchange membranes(AEMs)has significant influence on their microscopic morphology and anion conductivity.To develop high-performance AEMs for vana...
financially supported by Total. We thank G. Zannoni and D. Piovani (ISMAC) for their valuable cooperation in NMR and SEC analysis
Ethylene-propene copolymers have been synthesized by three C1-symmetric metallocene molecules(1,2,and 3),having tert-butyl substituents on the Cp moiety,on the fluorenyl moiety,or on both moieties,and methylaluminoxan...
financially supported by the National Natural Science Foundation of China (No. 21274041);the Key Project of Chinese Ministry of Education (No. 109064);the Fundamental Research Funds for the Central Universities (No. WK1214048)
Four C_1-symmetric ansa-metallocene complexes, C_2H_4(Ind)(2,7-~tBu_2-Flu)ZrCl_2(4), C_2H_4(3-Bn-Ind)(2,7-~tBu_2-Flu)ZrCl_2(5),C_2H_4(3-Bn-Ind)(3,6-~tBu_2-Flu)ZrCl_2(6), and C_2H_4(3-Bn-Ind)(2,7-~tBu_2-Flu)HfCl_2(7), ...
supported by the National Natural Science Foundation of China (51503038)
Membranes with high ion conductivity and selectivity are important for vanadium redox flow batteries.Herein, densely quaternized anion exchange membranes based on quaternary ammonium functionalized octa-benzylmethyl-c...
financially supported by the National Natural Science Foundation of China (No. 21174026);Program for New Century Excellent Talents in University;the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning;"Shu Guang" project supported by Shanghai Municipal Education Commission;Shanghai Education Development Foundation;the Fundamental Research Funds for the Central Universities (No. CUSF-DH-D-2017041)
Copolymerizations of ethylene and 1-dodecene were conducted with a series of ansa-fluorenylamidodimethyltitanium complexes, [t-BuNSiMe2Flu]TiMe2(1a), [t-BuNSiMe2(2,7-^tBu2Flu)]TiMe2(1 b), and [(1-adamantyl)NSi...
This research was supported by the National Natural Science Foundation of China (Nos. 21332002).
A variety of rigid ruthenium and osmium allenylidene, ruthenium alkynyl-allenylidene complexes have been prepared. These allenylidene complexes were derived from 9-ethynyl-9-fluorenol and 9-hydroxy-9-ethynyl-4,5-diaza...