A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazi...
the National Key Research and Development Program of China(2021YFC2101900,2022YFA1503200);the National Natural Science Foundation of China(22122103,22101130,22001117,22471121,22271144);the Fundamental Research Funds for the Central Universities(020514380327);the open project of state key laboratory of natural medicines(SKLNMKF202401)for financial support。
Selective modification of peptides has always been a challenging issue.The selective alkylation of peptides can alter the biological activity and physical properties of molecules,and it has gained significant research...
supported by the Natural Science Foundation of Shandong Province(No.ZR2021QB140);the Fundamental Research Funds for the Central Universities(No.202113051);F.S.thanks the Youth Talent Project support(Nos.202001013196,202101013108)from Ocean University of China;the Open Project support(No.202017)from the State Key Laboratory of Physical Chemistry of Solid Surfaces;Xiamen University and the Open Project support(No.M202317)from the State Key Laboratory of Microbial Technology,Shandong University.
A new family of trinuclear windwheel complexes with molecular formula [M^(II)_(3)(tpa)_(3)(μ-ttc)](ClO_(4))_(3)·n(sol) (ttc = 1,3,5-triazine-2,4,6-trithiol;tpa = tris(2-pyridylmethyl)amine;M = Mn,n = 2,sol = CH_(3)C...
This work was supported by the National Natural Science Foundation of China(21971142,21973046 and 22271171).
The reaction of DyCl_(3)·6H_(2)O with a rigid diacylhydrazone ligand(H_(2)L)afforded a trinuclear precursor[Dy_(3)L_(2)Cl_(3)(H_(2)O)_(2)(CH_(3)OH)]Cl_(2)·3CH_(3)OH(1).The replacement of the Cl-ions and the coordina...
This research is dedicated to the 10th anniversary of the Center of Basic Molecular Science(CBMS)at Tsinghua University.This work was financially supported by the National Science Foundation of China(grant nos.21933007 and 21873031).The authors appreciate the reviewers for their helpful comments.Q.-F.C.thanks Dr.Hai-Fang Li at Tsinghua University for the help on ESI-HRMS measurements.
We report a molecular trinuclear nickel(TNC-Ni)catalyst for water oxidation that exhibited high catalytic performance and stability under neutral conditions(pH 7).Electrochemical studies disclosed that cooperation amo...
This work was supported by the National Natural Sci-ence Foundation of China(No.52071171);Liaoning Revitalization Talents Program-Pan Deng Scholars(XLYC1802005);Liaoning BaiQianWan Talents Program(LNBQW2018B0048);Natural Science Fund of Liaoning Province for Excellent Young Scholars(2019-YQ-04);Key ProjectofScientificResearchoftheEducationDepartment of Liaoning Province(LZD201902);Shenyang Science and Technology Project(21-108-9-04);Australian Research Council(ARC)through Future Fellowship(FT210100298);Discovery Project(DP220100603);Linkage Project(LP210200504)schemes,CSIRO Energy Centre and Kick-Start Project.
Owing to the need for regenerant and self-reduction problem,the hydrogen performance of sub-nano-sized trinuclear iron-oxo complexes is still far from satisfied with affordability and practicality.Herein,two binary ph...
Supported by the National Natural Science Foundation of China (21975254, 21905280, 21950410532, 2019M662254);Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund (ES202080085);the Youth Innovation Promotion Association CAS (2018342)
Crystalline polyoxo-titanium clusters(PTCs),as a molecular model of TiO_(2)nanomaterials,have attracted unprecedented attention due to their designable structure,tunable band gap,catalysis,and photochromic properties....
supported by the Stable Support Plan Program of Shenzhen Natural Science Fund (20200925151834005);the National Natural Science Foundation of China (21671095);the China Postdoctoral Science Foundation (2020M682763)。
The engineering of switchable molecules with magnetic multistability is lying on the cutting-edge research topics for integrating multi-switches and ternary memory devices. Here we presented a cyanide-bridged {Fe_(2)^...
supported financially by the National Natural Science Foundation of China(nos.21731002,21975104,and 21901085);and the Guangdong Major Project of Basic and Applied Research(no.2019B030302009).G.-H.N.is thankful for the financial support from Guangdong Basic and Applied Basic Research Foundation(no.2019B151502024);Guangdong Province Pearl River Scholar Funded Scheme(2019),and the Fundamental Research Funds for the Central Universities(no.21619315).
Metal clusters exhibit diverse structures,emerging functions,and applications;thus,incorporating clusters into metal–organic frameworks(MOFs)brings tremendous merits.Although the construction of cluster-based MOFs is...
financially supported by the foundation of Key Laboratory of Ethnomedicine(Minzu University of China),Ministry of Education(No.KLEM-ZZ201804);the Young Teachers’Scientific Research Ability Promotion Program of Minzu University of China(No.2018QNPY57);Beijing Municipal Natural Science Foundation(No.2154049)。
The post-functionalization of gold nanoclusters with organic molecules into organic-inorganic hybrid functional materials is an efficient approach to develop multifunctional materials.By introducing 1-pyrenamine and 3...