DIOXOLANE

作品数：7被引量：5H指数：1
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相关领域：理学化学工程更多>>
相关作者：徐卫国张建君更多>>
相关机构：浙江省化工研究院有限公司更多>>
相关期刊：《Chinese Journal of Chemistry》《浙江化工》《Chemical Research in Chinese Universities》《Journal of Energy Chemistry》更多>>
相关基金：国家自然科学基金更多>>
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Stereoelectronic Control of Cleavage of Dioxolane Five-membered Ring on Carbohydrates
《Chemical Research in Chinese Universities》2013年第3期551-555,共5页PAN Xiao-liang ZHOU Yi-xuan LIU Wei LIU Jing-yao DONG Hai 
Supported by the National Natural Science Foundation of China（No.20973077）, the Program for New Century Excellent Talents in University of China（No.NCET-07-0358） and the Brain Gain Fund of Huazhong University of Science and Technology, China.
A mechanism about the origin of the selectivities for the cleavage of dioxolane five-membered rings on pyranoside rings was suggested. Quantum chemical studies were performed to testify the rationality of the mechanis...
关键词：Stereoelectronic effect CARBOHYDRATE Antiperiplanar lone-pair hypothesis 
Synthesis and Cleavage Studies of a 1,2-Dioxolane-type Peroxide
《Chinese Journal of Chemistry》2004年第9期1029-1033,共5页刘鹤华 金红霞 伍贻康 
the National Natural Science Foundation (Nos. 20025207, 20272071, 20372075 and 20321202), the Qinghaosu Science and Technology Foundation, the Chinese Academy of Sciences (KGCX2-SW-209) and the Major State Basic Research Develop
A [1,2]dioxolane-type peroxide was synthesized and tested for its cleavage behavior with Fe2+-cysteinate as a simple model of biological redox species. No S-alkylation product was observed.
关键词：cyclic peroxide ARTEMISININ free radical CLEAVAGE mechanism 
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