In the search for new drugs with more efficient active ingredients, various transition metals are being explored as potential metallopharmaceuticals. These compounds, which combine drugs with metals, have shown promis...
financially supported by the National Natural Science Foundation of China(grant nos.22161021,22261002,21890382,and 22375079);the Key Project of Jiangxi Provincial Department of Science and Technology(grant nos.S2023ZRZDL0164,20232ACB203016,and S2023ZRMSL0668);the Key Laboratory of Jiangxi University for Functional Materials Chemistry(grant no.FMC21702);the Education Department of Jiangxi Province(grant nos.GJJ201427 and SZUGSHX2022-1043);C.-T.H.acknowledges the support of Jiangxi Province(grant no.20224ACB214001).
Converting low-concentration carbon dioxide(CO_(2))into value-added chemicals meets the demand of carbonneutral technologies,yet efficient and stable catalysts for CO_(2)absorption and activation are urgently desired....
the Bureau of International Cooperation Chinese Academy of Sciences(grant no.121522KYSB20200029);National Natural Science Foundation of China(grant nos.22222509,52025035,52003268,and 51973215);Jilin Province Science and Technology Development Plan(grant nos.YDZJ202101-ZYTS131 and 20220402037GH);Jilin Provincial International Cooperation Key Laboratory of Biomedical Polymers(grant no.20210504001GH);Changchun Science and Technology Development Plan(grant no.21ZY09);the Youth Innovation Promotion Association of Chinese Academy of Sciences(grant no.2020232).
We report herein an interesting finding that heterocyclic molecules tethered branched polymers exhibit innate immune stimulating activity.When we conjugated a series of five-,six-,or seven-membered heterocyclic molecu...
the National Key R&D Program of China(grant no.2022YFA1503200);NSFC(grant nos.92156004,22271146,and 22271143);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University,the Open Research Fund of the Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs,the China Postdoctoral Science Foundation(grant no.2021M701655);the Jiangsu Funding Program for Excellent Postdoctoral Talent(grant no.20220ZB24).
Asymmetric migratory hydrofunctionalization of isomeric mixtures of alkenes provides a complementary approach for the selective introduction of a functional group into a remote C(sp3)-H position.However,the simultaneo...
the Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(No.KQTD20150717103157174);Stable Support Plan Program of Shenzhen Natural Science Fund(Program Contract No.20200925161222002);Key-Area Research and DevelopmentPt rogramofGuangdong Province((No.2020B010188001);Innovative Team of Universities in Guangdong Province(No.2020KCXTD016);National Natural Science Foundation of China(No.21991113);the National Natural Science Foundation of China(No.22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support.
Transition metal-catalyzed asymmetric transfer hydrogenation has been proven to be a powerful approach for the synthesis of chiral alcohols.Herein,a highly efficient and enantioselective transfer hydrogenation of dibe...
the Ministry of Science and Technology of China(No.2016YFA0200100);the Beijing National Laboratory for Molecular Sciences(No.BNLMS-CXTD-202001);the National Natural Science Foundation of China(Nos.52102035,52021006,T2188101,51720105003,and 21790052);the Strategic Priority Research Program of CAS(No.XDB36030100).
Heterocyclic aramid fibers,a typical kind of high-performance fibers,have been widely used in aerospace and protection fields because of their excellent mechanical properties.However,the application of heterocyclic ar...
supported by the National Natural Science Foundation of China(41625009 and U20B6001);Research support to Qi Fu from United States National Science Foundation CAREER program(OCE-1652481);American Chemical Society Petroleum Research Fund(54474-DNI2);the support from the Tencent Foundation through the XPLORER PRIZE,China。
In order to assess the dynamics of molecular conversion,scientists simulated the low-temperature synthesis of polycyclic aromatic hydrocarbons(PAHs)in Titan’s atmosphere[1],and noticed the transformation(hydrogenatio...
financial support from the National Natural Science Foundation of China(22075144);the Natural ScienceFoundationof Jiangsu Province(BK20200459).
Comprehensive Summary 2,4,6,8-Tetraazanoradamantane skeleton is a unique rigid cage-like organic structure that has not been established.In this article,a facile protocol to build all-bridge-position-functionalized 2,...
supported by the National Natural Science Foundation of China(92056107,22271199,21801175);the Sichuan University(2020SCUNL204)。
N-heterocyclic olefins(NHOs)possess an electron-rich and highly polarized C=C double bond due to the donating property of nitrogen atoms.This feature imparts exocyclic carbon atom of NHOs with strong basicity and high...
This work was supported by the National Natural Science Foundation of China(Grant Nos.22125802,22078010 and U1862113);the Big Science Project from BUCT(Grant No.XK180301).
A nitrogen-containing ionic liquid was synthesized using an aromatic nitrogen-containing heterocyclic and an amino acid,and applied to the extractive desulfurization process to remove benzothiophene,dibenzothiophene,a...