-KETOESTERS

作品数：12被引量：9H指数：2
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相关领域：理学更多>>
相关作者：孟令国陈龙更多>>
相关机构：淮北师范大学中国科学技术大学安徽工业大学华东理工大学更多>>
相关期刊：《Science China Chemistry》《Green Synthesis and Catalysis》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划更多>>
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Nickel(II)-Catalyzed Diastereo- and Enantioselective [3+2] Cycloaddition of a-Ketoesters with 2-Nitrovinylindoles and 2-Nitrovinylpyrroles被引量：4
《Chinese Journal of Chemistry》2019年第3期216-220,共5页Wu-Lin Yang Zhong-Tao Sun Hao Sun Wei-Ping Deng 
Summary of main observation and conclusion The catalytic asymmetric [3+2] cycloaddition of a-ketoesters w让h 2-nitrovinylindoles and 2-nitrovinylpyrroles has been established. This strategy allowed the construction of...
关键词：CATALYTIC ASYMMETRIC ENANTIOSELECTIVE 
Pentafluoroethylbenziodoxole （BIX-C2Fs）： A Shelf-Stable Reagent for Pentafluoroethylation of β-Ketoesters and Arylboronic Acids被引量：1
《Chinese Journal of Chemistry》2016年第7期662-668,共7页Jiansheng Zhu Yuguang Li Chuanfa Ni Qilong Shen 
National Basic Research Program of China （No. 2012CB821600）, National Natural Science Foundation of China （Nos. 21372247, 21572258, 21421002） and SIOC.
An improved method for the preparation of pentafluoroethylating reagent pentafluoroethyl-substituted benzio- doxole （BIX-C2Fs） was described. Under mild conditions, BIX-C2F5 was able to react with β-ketoesters or a...
关键词：fluorine pentafluoroethyl HYPERVALENT ELECTROPHILIC CROSS-COUPLING 
Chiral Sulfinamide-Olefin Ligands： Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic α-Ketoesters
《Chinese Journal of Chemistry》2013年第3期321-328,共8页Ting-Shun Zhu Ming-Hua Xu 
Financial support from the National Natural Science Foundation of China
Simple and readily available chiral N-（sulfinyl）allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic a-keto...
关键词：asymmetric catalysis rhodium sulfur-o｜efin ligand 1 2-addition stereoselectivity reversal 
Mechanism of Gold（I）-Catalyzed Conia-ene Reaction of β-Ketoesters with Alkynes： A DFT Study
《Chinese Journal of Chemistry》2011年第11期2320-2326,共7页尹艳春 王勉 王坚毅 周龙昌 段文贵 
Density functional calculations have been performed to comparatively investigate two possible pathways of Au（I）-catalyzed Conia-ene reaction of β-ketoesters with alkynes. Our studies find that, under the assistance...
关键词：Au（I） catalyst ISOMERIZATION ALKYNE Conia-ene reaction density functional calculation 
Proline Catalyzed Asymmetric Aldol Reaction between Methyl Ketones and a-Ketoesters
《Chinese Journal of Chemistry》2006年第9期1196-1199,共4页王亚军 沈宗旋 李斌 张雅文 
Direct asymmetric aldol additions of acetone/and butanone to a-ketoesters were achieved using L-proline as a chiral catalyst. Various optically active a-hydroxyesters were obtained in the yields of 43%-93% with enanti...
关键词：PROLINE CATALYSIS ASYMMETRIC aldol addition α-ketoester 
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