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作品数:1132被引量:1374H指数:10
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相关领域:理学更多>>
相关作者:滕怀龙祝诗发陈自立姚小泉石先莹更多>>
相关机构:中国科学院南开大学郑州大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>
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  • 期刊=Chinese Journal of Catalysisx
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A round-trip journey of electrons:Electron catalyzed direct fixation of N_(2)to azos
《Chinese Journal of Catalysis》2025年第1期386-393,共8页Baijing Wu Jinrui Li Xiaoxue Luo Jingtian Ni Yiting Lu Minhua Shao Cunpu Li Zidong Wei 
国家重点研发计划(2022YFC2105904);国家自然科学基金(22478043,2209003052021004,U21A20312,22075033)。
The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...
关键词:Fixed N_(2) AZO Electron catalyzed strategy "Brick trowel"transition state Arylradicals 
Ab initio molecular dynamics simulation reveals the influence of entropy effect on Co@BEA zeolite-catalyzed dehydrogenation of ethane
《Chinese Journal of Catalysis》2024年第10期195-205,共11页Yumeng Fo Shaojia Song Kun Yang Xiangyang Ji Luyuan Yang Liusai Huang Xinyu Chen Xueqiu Wu Jian Liu Zhen Zhao Weiyu Song 
国家自然科学基金(22035009,22178381);国家重点研发计划(2021YFA1501301,2021YFC2901100)。
The C–H bond activation in alkane dehydrogenation reactions is a key step in determining the reaction rate.To understand the impact of entropy,we performed ab initio static and molecular dynamics free energy simulati...
关键词:Ethane dehydrogenation C-H bond activation Ab initio molecular dynamics simulation ENTROPY Heterogeneous catalysis 
Electrocatalytic ammonia synthesis catalyzed by mesoporous nickel oxide nanosheets loaded with Pt nanoparticles被引量:1
《Chinese Journal of Catalysis》2022年第5期1371-1378,共8页Wei Xiong Min Zhou Hao Li Zhao Ding Da Zhang Yaokang Lv 
国家自然科学基金(21703161);浙江省自然基金(LY19B010003).
Owing to its cost‐effectiveness and adjustable eight‐electron distribution in the 3d orbital,nickel oxide(NiO)is considered an effective electrocatalyst for an ambient electrochemical nitrogen reduction reaction(NRR...
关键词:Platinum nanoparticles NiO nanosheets Nitrogen reduction reaction ELECTROCATALYSIS 
M/C_(3)N_(4)/AC(M=Au,Pt,Ru)‐catalyzed acetylene coupling with ethylene dichloride:How effective are the bifunctionalities?被引量:1
《Chinese Journal of Catalysis》2022年第3期820-831,共12页Qing Yu Shiyi Wang Mengru Wang Xiaoling Mou Ronghe Lin Yunjie Ding 
浙江师范大学科研启动经费(KYJ51020910,YS304320036).
Acetylene coupling with ethylene dichloride,which uses both coal and oil resources,is attractive for sustainable PVC manufacturing.Herein,highly active and stable carbon nitride‐based catalysts were developed by a no...
关键词:Acetylene hydrochlorination Bi‐functional catalyst DEHYDROCHLORINATION Ethylene dichloride Vinyl chloride 
Oxidation of 2,5‐bis(hydroxymethyl)furan to 2,5‐furandicarboxylic acid catalyzed by carbon nanotube‐supported Pd catalysts被引量:2
《Chinese Journal of Catalysis》2022年第3期793-801,共9页Zhenyu Li Liyuan Huai Panpan Hao Xi Zhao Yongzhao Wang Bingsen Zhang Chunlin Chen Jian Zhang 
国家自然科学基金(22072170);中国科学院前沿科学重点研究项目(QYZDB-SSW-JSC037);宁波市重大专项(2018B10056,2019B10096).
The selective oxidation of 2,5‐bis(hydroxymethyl)furan(BHMF)in this work was proven as a promising route to produce 2,5‐furandicarboxylic acid(FDCA),an emerging bio‐based building‐block with wide application.Under...
关键词:2 5‐Bis(hydroxymethyl)furan 2 5‐Furandicarboxylic acid Palladium hydride 5‐Hydroxymethylfurfural Catalytic oxidation 
Iron phthalocyanine-catalyzed radical phosphinoylazidation of alkenes:A facile synthesis of β-azido-phosphine oxide with a fast azido transfer step
《Chinese Journal of Catalysis》2021年第10期1634-1640,共7页Xiaoxu Ma Mong-Feng Chiou Liang Ge Xiaoyan Li Yajun Li Li Wu Hongli Bao 
国家重点基础研究发展计划(2017YFA0700103);国家自然科学基金(21922112,21871258,22001251);中国科学院战略性重点研究计划(XDB20000000).
Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization o...
关键词:Iron phthalocyanine Phosphinoylazidation Difunctionalization Radical group transfer Density functional theory calculation 
Synthesis of α-hydroxy ketones by copper(Ⅰ)-catalyzed hydration of propargylic alcohols: CO2 as a cocatalyst under atmospheric pressure
《Chinese Journal of Catalysis》2019年第9期1345-1351,共7页Zhi-Hua Zhou Xiao Zhang Yong-Fu Huang Kai-Hong Chen Liang-Nian He 
supported by National Natural Science Foundation of China(21672119);China Postdoctoral Science Foundation(2018M641624)~~
Inexpensive and efficient Cu(Ⅰ) catalysis is reported for the synthesis of α-hydroxy ketones from propargylic alcohols, CO2, and water via tandem carboxylative cyclization and nucleophilic addition reaction. Notably...
关键词:Copper catalysis Propargylic alcohols HYDRATION α-Hydroxy ketones Carbon dioxide COCATALYST 
Silver-catalyzed carboxylative cyclization of alkynic hydrazones with carbon dioxide
《Chinese Journal of Catalysis》2019年第8期1153-1159,共7页Wenzhen Zhang Yuqian Sun Min Zhang Hui Zhou Xiaobing Lu 
supported by the National Natural Science Foundation of China(21878038);the Natural Science Foundation of Liaoning Province(20170540156);the Program for Changjiang Scholars and Innovative Research Team in University(IRT-17R14)~~
The development of new catalytic methodologies to synthesize heterocyclic fine chemicals using carbon dioxide as a synthon has attracted considerable attention. Herein, we report the silver( I)-catalyzed carboxylative...
关键词:Carbon dioxide Silver catalysis Carboxylative cyclization Alkynic hydrazine Oxadiazinone Homogeneous catalysis 
Br?nsted acidic ionic liquid catalyzed synthesis of benzo[a]carbazole from renewable acetol and 2-phenylindoles in a biphasic system被引量:1
《Chinese Journal of Catalysis》2019年第8期1135-1140,共6页Minghao Li Fengtian Wu Yanlong Gu 
supported by the National Natural Science Foundation of China(21761132014,21872060);the Fundamental Research Funds for the Central Universities of China(2016YXZD033);the Fundamental Research Funds for the Central Universities(2019kfyXJJS072);Opening fund of Hubei Key Laboratory of Material Chemistry and Service Failure(2017MCF01K)~~
An efficient metal-free strategy for the synthesis of pharmaceutically relevant benzo[α]carbazoles from the derivatives of readily available 2-phenylindole and bio-renewable acetol in an aqueous biphasic system was d...
关键词:Benzo[α]carbazole Bronsted acid ionic liquid Bio-renewable acetol 2-Phenylindole 
Amine formylation with CO2 and H2 catalyzed by heterogeneous Pd/PAL catalyst被引量:8
《Chinese Journal of Catalysis》2019年第8期1141-1146,共6页Xingchao Dai Bin Wang Aiqin Wang Feng Shi 
supported by the National Natural Science Foundation of China(91745106,21633013);the Major Projects of the National Natural Science Foundation of Gansu,China(18JR4RA001);the Youth Innovation Promotion Association CAS(2019409);Fujian Institute of Innovation,CAS and Key Research Program of Frontier Sciences of CAS(QYZDJ-SSW-SLH051)~~
For the first time, Pd supported on natural palygorskite was developed for amine formylation with CO2 and H2. Both secondary and primary amines with diverse structures could be converted into the desired formamides at...
关键词:FORMYLATION Carbon dioxide AMINE Heterogeneous palladium catalyst FORMAMIDE 
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