The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...
The C–H bond activation in alkane dehydrogenation reactions is a key step in determining the reaction rate.To understand the impact of entropy,we performed ab initio static and molecular dynamics free energy simulati...
Owing to its cost‐effectiveness and adjustable eight‐electron distribution in the 3d orbital,nickel oxide(NiO)is considered an effective electrocatalyst for an ambient electrochemical nitrogen reduction reaction(NRR...
Acetylene coupling with ethylene dichloride,which uses both coal and oil resources,is attractive for sustainable PVC manufacturing.Herein,highly active and stable carbon nitride‐based catalysts were developed by a no...
The selective oxidation of 2,5‐bis(hydroxymethyl)furan(BHMF)in this work was proven as a promising route to produce 2,5‐furandicarboxylic acid(FDCA),an emerging bio‐based building‐block with wide application.Under...
Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization o...
supported by National Natural Science Foundation of China(21672119);China Postdoctoral Science Foundation(2018M641624)~~
Inexpensive and efficient Cu(Ⅰ) catalysis is reported for the synthesis of α-hydroxy ketones from propargylic alcohols, CO2, and water via tandem carboxylative cyclization and nucleophilic addition reaction. Notably...
supported by the National Natural Science Foundation of China(21878038);the Natural Science Foundation of Liaoning Province(20170540156);the Program for Changjiang Scholars and Innovative Research Team in University(IRT-17R14)~~
The development of new catalytic methodologies to synthesize heterocyclic fine chemicals using carbon dioxide as a synthon has attracted considerable attention. Herein, we report the silver( I)-catalyzed carboxylative...
supported by the National Natural Science Foundation of China(21761132014,21872060);the Fundamental Research Funds for the Central Universities of China(2016YXZD033);the Fundamental Research Funds for the Central Universities(2019kfyXJJS072);Opening fund of Hubei Key Laboratory of Material Chemistry and Service Failure(2017MCF01K)~~
An efficient metal-free strategy for the synthesis of pharmaceutically relevant benzo[α]carbazoles from the derivatives of readily available 2-phenylindole and bio-renewable acetol in an aqueous biphasic system was d...
supported by the National Natural Science Foundation of China(91745106,21633013);the Major Projects of the National Natural Science Foundation of Gansu,China(18JR4RA001);the Youth Innovation Promotion Association CAS(2019409);Fujian Institute of Innovation,CAS and Key Research Program of Frontier Sciences of CAS(QYZDJ-SSW-SLH051)~~
For the first time, Pd supported on natural palygorskite was developed for amine formylation with CO2 and H2. Both secondary and primary amines with diverse structures could be converted into the desired formamides at...