ALLYLSILANE

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相关期刊：《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
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An Efficient Cationic Cyclization Approach for the Construction of Labdane Diterpenoid Decalin Ring Skeleton
《Chinese Chemical Letters》2005年第4期433-436,共4页JinHuiYANG WeiDongZ.LI 
financial support from the National Outstanding Youth Fund(No.29925204)
An effective approach for the construction of the decalin ring skeleton of labdane diterpenoids was developed based on a key biomimetic cationic polyene cyclization of an epoxy allylsilane precursor. The synthetic a...
关键词：ALLYLSILANE labdane skeleton cationic cyclization biomimetic synthesis. 
Asymmetric allylation of aldehydes and alkylation using "carbon-centered" chiral organosilicon compounds
《Chinese Journal of Chemistry》1999年第5期429-437,425,共9页王东 
National Natural Science Foundation of China.
The effects of the chiral substituents attached to silicon on the stereoselectivity of the reactions of C-centered chiral silicon compounds wm examined. The investigation was focused on the asymmetric C—C bond format...
关键词：Carbon-centered chiral organosilicon compound asymmetric C—C bond formation reaction ALLYLSILANE α-silylallyl anion 
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