FLUOROALKYLATION

作品数：14被引量：6H指数：1
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相关领域：理学更多>>
相关机构：上海大学兰州大学更多>>
相关期刊：《Science China Chemistry》《Science Bulletin》《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金上海市青年科技启明星计划更多>>
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Computational insights into the effects of reagent structure and bases on nucleophilic monofluoromethylation of aldehydes被引量：1
《Chinese Chemical Letters》2022年第5期2387-2390,共4页Meng-Meng Zheng Hao-Dong Tan Yueqian Sang Xiao-Song Xue Jin-Pei Cheng 
supported by the Natural Science Foundation of China(Nos.22122104,21933004 and 21702098).
Although fluorobis(phenylsulfonyl)methane(FBSM)and its cyclic analog 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide(FBDT)possess similar physicochemical properties,Shibata et al.found that FBSM failed to undergo nucleo...
关键词：Nucleophilic monofluoromethylation Fluoroalkylation reagent DFT calculations Thermodynamic effect Lone pair repulsion 
Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF_(2)H: Facile Entry into gem-Difluoroalkenes
《Chinese Journal of Chemistry》2014年第8期703-708,共6页Xiao Shen Qinghe Liu Chuanfa Ni Jinbo Hu 
Support of our work by the National Basic Research Program of China(Nos.2012CB215500 and 2012CB821600);the NNSFC(No.21372246);Shanghai QMX program(No.13QH1402400);the Chinese Academy of Sciences is gratefully acknowledged.
An efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF_(2)H has been developed.It is particularly remarkable that,when 1.5 equiv.of alkyl bromides ar...
关键词：nucleophilic fluoroalkylation β-elimination difluoroalkene SULFOXIMINE 
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