ARENES

作品数:103被引量:70H指数:3
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相关领域:理学更多>>
相关作者:高明春王刚伟洪小虎李兴伟杨尚东更多>>
相关机构:中国检验检疫科学研究院中国科学院北京桑普生物化学技术有限公司北京宝洁技术有限公司更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金上海市自然科学基金更多>>
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Cobalt-Catalyzed C-H Allylation of Arenes with Allylic Amines被引量:1
《Chinese Journal of Chemistry》2021年第5期1205-1210,共6页Rui Yan Hang Yu Zhong-Xia Wang 
the National Natural Science Foundation of China(No.21372212);the National Basic Research Program of China(No.2015CB856600)is greatly acknowledged.
[Cp^(*)Co(CO)l_(2)]effectively catalyzes pyridyl-directed C-H allylation of arenes with allylic amines in the presence of AgOAc and CF_(3)COOAg.The reaction features ortho-position monoallylation of 2-pyridylarenes,gi...
关键词:C-H activation C-N activation Homogeneous catalysis Cobalt catalysis ALLYLATION 
Rhodium(Ⅲ)-Catalyzed C-H Vinylation of Arenes:Access to Functionalized Styrenes被引量:3
《Chinese Journal of Chemistry》2018年第12期1143-1146,共4页Jun Zhou Xin Li Gang Liao Bing-Feng Shi 
Metal Chlorides Supported Solid Catalysts for F-C Acylations of Arenes
《Transactions of Tianjin University》2015年第5期400-405,共6页李阳 刘云龙 穆曼曼 陈立功 
Supported by the National Basic Research Program of China("973"Program,No.21476163)
A series of metal chlorides supported solid catalysts were prepared by simple wet impregnation method. Their catalytic performances for Friedel-Crafts acylation of toluene with benzoyl chloride were evaluated and the ...
关键词:ACYLATION heterogeneous catalyst silica gel ferric chloride 
Photoinduced C–H direct arylation of unactivated arenes
《Science China Chemistry》2015年第8期1329-1333,共5页Jian Kan Shijun Huang Huaiqing Zhao Jin Lin Weiping Su 
financially supported by the National Basic Research Program of China(2011CB932404,2011CBA00501);the National Natural Science Foundation of China(21332001,21431008,21301173)
Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond...
关键词:C-H bond activation PHOTOINDUCED free radical aryl iodide 
Quantum Chemistry Studies on the Free-radical Growth Mechanism of Polycyclic Arenes from Benzene Precursors
《Chinese Journal of Chemical Engineering》2009年第3期394-400,共7页章日光 王宝俊 田亚峻 凌丽霞 
Supported by the National Basic Research Program of China (2005CB221203);the National Natural Science Foundation of China (20576087, 20776093, 50534070);the Natural Science Foundation of Shanxi Province (2006011022, 2009021015)
The free-radical growth mechanisms for the formation of polycyclic arenes (PCAs) were constructed based on the block unit of benzene, and were calculated by the quantum chemistry PM3 method. Two kinds of reaction path...
关键词:BENZENE polycyclic arene mechanism quantum chemistry calculation 
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