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作品数：103被引量：70H指数：3
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Synergistic asymmetric diarylation of tethered alkenes via C–H functionalization of simple(hetero)arenes
《Science China Chemistry》2024年第8期2710-2718,共9页Jian Yao Can Zhao Lili Shao Xiaohong Huo Xiaoming Wang 
supported by the National Key R&D Program of China (2021YFA1500100);the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0610000);the National Natural Science Foundation of China (92256303, 22171278, 21821002);the Shanghai Science and Technology Committee (23ZR1482400);the Natural Science Foundation of Ningbo (2023J034)。
By virtue of the atom-and step-economy, utilization of simple arenes as a supplant of pre-prepared aryl metal species or aryl halides for the synthesis of arylated chiral molecules has attracted great attention from t...
关键词：asymmetric Pd/Ag dual metal catalytic system simple arenes C–H functionalization bifunctional role chiral oxindoles 
Photocatalytic vinyl radical-mediated multicomponent 1,4-/1,8-carboimination across alkynes and olefins/(hetero)arenes
《Science China Chemistry》2024年第2期558-567,共10页Shan-Shan Li Yu-Shi Jiang Xue-Ling Luo Xuming Ran Yuqiang Li Dong Wu Cheng-Xue Pan Peng-Ju Xia 
supported by the National Natural Science Foundation of China (22101059);the Guangxi Natural Science Foundation of China (2023GXNSFBA026275);the Innovation Project of Guangxi Graduate Education (YCSW2023125);partially supported by the National Key R&D Program of China (2022ZD0160100);in part by Shanghai Committee of Science and Technology(21DZ1100100)。
We developed a highly selective and efficient multicomponent transformation by utilizing alkynes and olefins/(hetero)arenes through photoinduced energy-transfer catalysis.The reaction involves the formation of three d...
关键词：alkyne-olefin coupling DFT studies regio-and anti-stereoselectivity multisubstituted alkenes 
Lighting up nonbenzenoid acepleiadylene with ultra-narrowband emission through aromaticity modulation
《Science China Chemistry》2023年第12期3506-3510,共5页Pengcai Liu Xiao-Yu Tang Cheng-Zhuo Du Rui Xue Xing-Yu Chen Jiawen Cao Xiao-Ye Wang 
supported by the National Natural Science Foundation of China (22071120,92256304,22221002);the National Key R&D Program of China (2020YFA0711500);the Fundamental Research Funds for the Central Universities。
Nonbenzenoid polycyclic arenes have attracted great attention because of their unique topological structures and appealing properties;however,they are generally considered as poor luminescent materials due to the ring...
关键词：nonbenzenoid arenes LUMINESCENCE narrowband emission acepleiadylene 
The role of organic electron donors in the initiation of BHAS base-induced coupling reactions between haloarenes and arenes
《Science China Chemistry》2019年第11期1425-1438,共14页Andrew J.Smith Darren L.Poole John A.Murphy 
EPSRC;GSK;the University of Strathclyde for funding(AJS)
Coupling reactions between haloarenes and arenes(including heteroarenes)that are conducted without added transition metals but in the presence of KOtBu or NaOtBu,have been a topic of great interest since their discove...
关键词：ORGANIC ELECTRON donor potassium tert-butoxide ELECTRON transfer base-promoted homolytic AROMATIC substitution(BHAS) coupling BENZYNE 
Making pillar[6]arenes to lean: an art of tuning a supramolecular host被引量：1
《Science China Chemistry》2019年第3期289-290,共2页Dinesh Shetty Ali Trabolsi 
Symmetry and pattern are valuable forms of beauty that can be cherished on both the macroscopic and molecular levels. Scientists have always appreciated the intimate connections between symmetry and molecular structur...
关键词：Symmetry Scientists SYMMETRICAL 
Copper-catalyzed arenes amination with saccharins被引量：1
《Science China Chemistry》2015年第8期1354-1358,共5页Kai Sun Yan Li Qian Zhang 
financially supported by the National Natural Science Foundation of China(21172033,21372041,21302017)
A novel copper-catalyzed direct C–N formation reaction of simple arenes with cheap and pharmacological saccharin derivatives under relatively mild conditions was developed with arenes as limiting reagents.This work p...
关键词：aromatic amines C-N bond formation ARENES saccharins arenes as limiting reagents 
Photoinduced C–H direct arylation of unactivated arenes
《Science China Chemistry》2015年第8期1329-1333,共5页Jian Kan Shijun Huang Huaiqing Zhao Jin Lin Weiping Su 
financially supported by the National Basic Research Program of China(2011CB932404,2011CBA00501);the National Natural Science Foundation of China(21332001,21431008,21301173)
Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond...
关键词：C-H bond activation PHOTOINDUCED free radical aryl iodide 
Synthesis and host-guest properties of pillar[6]arenes被引量：3
《Science China Chemistry》2012年第2期223-228,共6页TAO HongQi CAO DeRong LIU LuZhi KOU YuHui WANG LingYun MEIER Herbert 
supported by the National Natural Science Foundation ofChina (20872038,21072064)
A facile method for the synthesis of pillar[6]arenes was developed. A series of pillar[6]arenes were prepared with FeC13 as catalyst and chloroform as solvent at room temperature in moderate yields （30%-40%）. Their ...
关键词：CALIXARENE pillararene FECL3 supramolecular chemistry host-guest property 
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