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Supported by the Fundamental Research Funds for the Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, China(No.130028652), the Natural Science Foundation of Liaoning Province, China(No.201602002), the Foundation of Liaoning Province Education Administration, China(No.L2015003) and the National Natural Science Foundation of China(No.20902010).
A FeCl3-6H2O-catalyzed synthesis of β-ketothioesters from the hydrolysis reaction of chain α-oxoketene dithioacetals was carried out. Subsequently, we explored the FeCl3-6H2O-catalyzed Friedel-Crafts alkylation of t...
Supported by the National Natural Science Foundation of China(No. 29862004) ;Scientific and Technological DevelopmentProgram Foundation of Jilin Province(No. 20040565).
α-Oxoketene dithioacetals( compound 1 ) are versatile synthons for organic synthesis due to their specially structural characteristic, that is, the masked ketene is conjugated with the convertible carbonyl in their...