financial support from the National Natural Science Foundation of China(Nos.22171072,21925103,and22301061)。
β-Amino sulfides hold significant biological importance,motivating the development of several methods for sulfenylamination of alkenes.However,these methods often involve a three-component system with limited alkene ...
supported by the Guangxi Science and Technology Base and Talent Project(High level Innovative Talents and Team Training)(Guike AD23026094);the Guangxi Natural Science Foundation of China(2021GXNSFFA220005);the National Natural Science Foundation of China(22161008,22061003);the Innovation and Entrepreneurship Training Programme for University Students(202310602013)。
The synthesis and modification of peptides occupy a unique position in the field of drug development,and the functionalization of amino acids is a valuable strategy as an alternative to peptide modification.Currently,...
A novel route for dinitrification of N-phenylbenzenesulfonamide to synthesize N-(2,4-dinitrophenyl)benzenesulfonamide has been developed.The method features convenient operation and good functional group tolerance.Thi...
supported by the National Key R&D Programs(No.2021YFA0910001);the Shenzhen Science and Technology Program(Nos.JCYJ20210324115804013,JCYJ2022081810160716,JCYJ20220531093604009);the Specific Research Assistant Funding Program of Chinese Academy of Sciences(No.E35902);the National Natural Science Foundation of China(Nos.22005343,32000982);the Guangdong Provincial Key Area R&D Program(No.2020B1111540001).
Carbon monoxide(CO)is a vital intracellular gas messenger known for its cytoprotective and homeostatic properties.It plays a pivotal role in a myriad of biological processes.Therefore,the precise detection of CO is of...
supported by the National Natural Science Foundation of China(22271097);the Guangdong Basic and Applied Basic Research Foundation(2022A1515240017)。
The chemoselective epoxidation of electron-deficient olefins in the presence of electron-rich alkene moieties is reported.This chemoselective epoxidation strategy undergoes a conjugated olefin epoxidation and BHT hydr...
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);Doctoral Research Foundation of Yan'an University(YDBK2019-60);the Training Program of Innovation and Entrepreneurship for Undergraduates of Yan'an University(D2022077);Research Program of Yan'an University(YDY2020-61);the Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
Herein,we present a method for the homogeneous hydrogenation of nitroarenes to produce anilines using low catalyst loading(1 mo%)of copper N-heterocyclic carbene complexes as the catalyst and ammonia borane as the sou...
the CAMS Innovation Fund for Medical Sciences(CIFMS)(grant nos.2019-I2M-5-074,2021-I2M-1-026,2021-I2M-3-001,and 2022-I2M-2-002);the National Natural Science Foundation of China(grant nos.81773564,82173678 and 22307052);the Program for Chang-Jiang Scholars and Innovative Research Team in University(grant no.IRT_15R27);the fellowship of China Postdoctoral Science Foundation(grant no.2021M701533);the Gansu Science and Technology Program(grant nos.23JRRA1103,22JR5RA502,and 21JR7RA449).
Late-stage peptide modification showcases a huge potential for the construction of peptide libraries,and the investigation of structure-activity relationships.Herein we report a dimethyl sulfoxide/visible light comedi...
the National Natural Science Foundation of China(Nos.22271244 and 21871226);the Postgraduate Scientific Research Innovation Project of Hunan Province(Nos.XDCX2021B151 and CX20210638);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2022C02)are gratefully acknowledged.
A strategy for the synthesis ofα-carboline derivatives from indole-3-carboxaldehydes and 3-aminocyclohex-2-enones under metal-free conditions has been developed.The combination use of phenyliodine(Ⅲ)diacetate(PIDA)a...
supported by the Ministry of Science and Technology of China,Major State Basic Research Development Program of China(2023YFA1506500,2021YFF0701704);Shanghai Pilot Program for Basic Research,Shanghai Jiao Tong University(21TQ1400223);WLA Laboratories for the financial support。
Herein we report the facile synthesis of a series of novel N-O reagents and identify N′-di-Boc-N′′-[(mesitylsulfonyl)oxy]-guanidine as an efficient imidating reagent.This reagent is synthetically scalable and bench...
the financial support from the Natural Science Foundation of Chongqing(CSTB2022NSCQ-MSX0458);the State Key Laboratory of Coal Mine Disaster Dynamics and Control(2011DA105287-MS202203);the Joint Fund for Innovation and Development of Chongqing(CSTB2022NSCQ-LZX0030);the financial support from the National Natural Science Foundation of China(22168027 and 22308169);the financial support from the Natural Science Foundation of Chongqing(cstc2021jcyj-msxmX0741);the financial support from the National Natural Science Foundation of China(22105028);the Natural Science Foundation of Chongqing(cstc2021jcyj-msxmX0572)。
Selective conversion of fructose to 1,2-propanediol(1,2-PDO)is considered as a sustainable and cost-effective alternative to petroleum-based processes,however,this approach still faces challenges associated with low e...