supported by the National Natural Science Foundation of China(21525102,21690062);the Natural Science Foundation of Jiangsu Province(BK20140014)
Two tetraazacyclophane dications(1^(2+) and 2^(2+)) with different remote substituents have been synthesized, isolated and characterized.Their electronic structures and physical property were studied by various spectr...
supported by the National Natural Science Foundation of China(21525102,2169002);the Natural Science Foundation of Jiangsu Province(BK20140014)
By using weakly coordinating anions we succeeded in the stabilization and isolation of two Wfirster's blue-based diradicaloid dications with saturated spacers. Their geometries and electronic structures were investig...
supported by the National Natural Science Foundation of China (20873017);the Program for Changjiang Scholars and Innovative Research Teams in University (IRT0714)
The polarizabilities and hyperpolarizabilities of the tetrahydropyrrole diradical in different electronic states have been investigated using ab initio and density functional theory (DFT) methods combined with the f...