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Inclusion of methylviologen dication in a cadmium tetracyanoplatinate host clathrate showing photochromism and photoluminescence modulation: 《Chinese Chemical Letters》2023年第3期498-501,共4页Jiang-Zhen Qiu Ye Yu Zhuo-Fan Chen Min Zhu Yongxia Lu Qinwu Wu Long-Fei Wang Jiang Liu; National Natural Science Foundation(No.21801258)for financial support。; A cadmium tetracyanoplatinate host clathrate,(MV)[Cd_(2){Pt(CN)_(4)}_(3)]·2(H_(2)O)(1),including a methylviologen dication (MV^(2+)) was synthesized,and the crystal structures,photochromic and photoluminescence prope...; 关键词：Methylviologen dication CADMIUM Polycyanidometallate clathrate PHOTOCHROMISM Photoluminescence

Construction and Functionalization of Highly Strained N-Doped Zigzag Hydrocarbon Belts被引量：1: 《CCS Chemistry》2023年第1期117-123,共7页Ming Xie Shuo Tong Mei-Xiang Wang; We thank the National Natural Science Foundation of China(grant nos.22050005,21732004,and 21821001);the Tsinghua University Initiative Scientific Research Program(grant no.2019Z07L01004)for generous financial support.; Recent years have witnessed breakthroughs in the study of zigzag hydrocarbon belts.However,the synthesis of heterocycle-containing zigzag molecular belts remains very rare and challenging despite their interesting str...; 关键词：zigzag molecular belt cyclacene arene[4]pyridine meta-bromination of Nacylaniline palladium-catalyzed C-N bond formation diradical dication salt

Fragmentation Dynamics of a Carbon Dioxide Dication Produced by Ion Impact: 《IMP & HIRFL Annual Report》2022年第1期74-74,共1页Yuan Hang Xu Shenyue Wang Enliang Xu Jiawei Gao Yue Zhu Xiaolong Guo Dalong Ma Binghui Zhao Dongmei Zhang Shaofeng Yan Shuncheng Zhang Ruitian Gao Yong Xu Zhongfeng Ma Xinwen; National Key Research and Development Program of China(2017YFA0402300);National Natural Science Foundation of China(11674332,U1432122)。; The three-body fragmentation of CO_(2)^(2+)to C++O++O induced by 1 keV/u Ar^(2+)impact is investigated employing the Reaction microscope.Three different dissociation mechanisms are clearly identified,and their branchi...; 关键词：FRAGMENTATION BONDS branching

Dication-accelerated anion transport inside micropores for the rapid decontamination of pertechnetate被引量：1: 《Nuclear Science and Techniques》2022年第4期19-32,共14页Peng Zhang Yi-Zhi Chen Han-Qin Weng Zi-Fang Guo Jia-Liang Chen Xing Zhao Guo-An Ye Ming-Zhang Lin; supported by the National Natural Science Foundation of China(Nos.51803205,11775214,and 21790371);China Scholarship Council(No.201906345006).; Over 70%of the treated contaminated water at the Fukushima Daiichi Nuclear Power Station contains radionuclides beyond the regulatory standard for discharge that need to be re-purified.Technetium-99(^(99)Tc),mainly in...; 关键词：Quaternary pyridinium Dicationic pyridyl derivatives PERTECHNETATE Intraparticle diffusion

Observation of CO2^++ dication in the dayside Martian upper atmosphere被引量：1: 《Earth and Planetary Physics》2020年第4期396-402,共7页Hao Gu Jun Cui DanDan Niu LongKang Dai JianPing Huang XiaoShu Wu YongQiang Hao Yong Wei; supported by the B-type Strategic Priority Program No.XDB41000000;funded by the Chinese Academy of Sciences,and the pre-research projects on Civil Aerospace Technologies No.D020105 and D020103;funded by China's National Space Administration;the National Science Foundation of China through grants 41525015 and 41774186 to JC,41904154 to WXS,and 41525016 to YW.; Doubly charged positive ions(dications)are an important component of planetary ionospheres because of the large energy required for their formation.Observations of these ions are exceptionally difficult due to their l...; 关键词：MAVEN Martian ionosphere DICATION

Para-selective borylation of monosubstituted benzenes using a transient mediator被引量：1: 《Science China Chemistry》2020年第3期336-340,共5页Jie Wu Zengwei Wang Xiao-Yue Chen Yichen Wu Daoming Wang Qian Peng Peng Wang; supported by Shanghai Institute of Organic Chemistry,State Key Laboratory of Organometallic Chemistry,the National Natural Science Foundation of China(21890722,21702109,11811530637);the Natural Science Foundation of Tianjin City(18JCYBJC21400);the Fundamental Research Funds for the Central Universities(63191515,63196021,63191523).; Herein,we conceptualized a transient mediator approach that has the capability of para-selective C–H functionalization of monosubstituted aromatics.This approach is enabled by in situ generation of a versatile sulfon...; 关键词：para-borylation monosubstituted ARENE TRANSIENT MEDIATOR thianthrenation sulfide DICATION

Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes: 《Chemical Research in Chinese Universities》2019年第2期229-234,共6页LIU Qianqian GUO Yuan WU Tun CHEN Mingzhao XIE Tingzheng WANG Pingshan; By utilizing terpyridine-bridged parallel metallo-complexes as dication metallo-bisviologens,herein we present the synthesis and characterization of two novel supramolecular complexes.1-Methylpyridin-1-ium-terpyridine...; 关键词：Supramolecular complex HOST-GUEST interaction Metallo-viologen Dibenzo-24-croyvn-8 ether TERPYRIDINE

Gas Phase Activation of Methane Molecule with Lead Benzene Dication Complex Ion, [Pb(Benzene)<sub>2</sub>]<sup>2+</sup>被引量：1: 《Materials Sciences and Applications》2019年第2期105-117,共13页Joseph K. Koka; Motivated by the search for ways of a more efficient usage of the ubiquitous, and unexploited resources of methane, recent progress in the gas-phase activation of methane by metal dication complex ion is discussed. Th...; 关键词：LEAD BENZENE Binding Energy METHANE ACTIVATION DICATION Complex Ion Density Functional Calculations Potential Energy Curve

Air-stable diradical dications with ferromagnetic interaction exceeding the thermal energy at room temperature: from a monomer to a dimer被引量：1: 《Science China Chemistry》2018年第3期300-305,共6页Wenqing Wang Lei Wang Sheng Chen Wenbang Yang Zaichao Zhang Xinping Wang; supported by the National Natural Science Foundation of China(21525102,21690062);the Natural Science Foundation of Jiangsu Province(BK20140014); Two tetraazacyclophane dications(1^(2+) and 2^(2+)) with different remote substituents have been synthesized, isolated and characterized.Their electronic structures and physical property were studied by various spectr...; 关键词：DIRADICAL DICATION triplet ground state ferromagnetic interaction X-ray crystal structure

Theoretical Study on Resonance Raman Spectra of Tetraoxaporphyrin Dication by TDDFT Calculation: 《Chinese Journal of Chemical Physics》2015年第5期-,共9页Guo-bing Wang Hui-qing Zhao Zhen-lin Zhang Wen-lou Wang Dong-ming Chen; 关键词：Tetraoxaporphyrin Resonance Raman TDDFT Excited state structure Franck-Condon mechanism

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