EPOXIDE

作品数：90被引量：176H指数：6
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相关作者：刘林华蒋义国樊娜高显区泽堂更多>>
相关机构：上海应用技术学院河北工业大学广州医学院湖南工程学院更多>>
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A stable acyl cobalt-based catalyst with exceptionally elevated activity for the carbonylation of epoxides intoβ-lactones
《Chinese Journal of Catalysis》2025年第1期336-344,共9页Jianwei Jiang Vinothkumar Ganesan Inrack Choi Jeongcheol Shin Sungho Yoon Kiyoung Park 
Polyhydroxyalkanoate(PHA),a well-known biodegradable polymer,featuresβ-lactones as its monomers,which can be selectively synthesized through ring-expansion carbonylation of epoxides using well-defined[Lewis acid]^(+)...
关键词：Epoxide carbonylation β-Lactone Cobalttetracarbonyl Acyl cobalt carbonyl High-temperature catalytic activity 
Facet and dual vacancy engineering-boosting BiOBr for enhanced CO_(2)and epoxide cycloaddition reaction under mild and cocatalyst-free conditions:Double substrate active sites and activated surface bromine ions synergy
《Journal of Materials Science & Technology》2024年第35期39-49,共11页Li Xia Huanping Chen Wenzhen Wang Xingang Jia Dake Zhang Li Wang Panfeng Wu Leilei Li Jian Huang 
supported by the National Science Basic Research Program of Shaanxi(Nos.2024JC-YBQN-0103,2024JC-YBMS-127,2022JQ-102);the National Natural Science Foundation of China(No.52073228);the Xi’an Shiyou University Postgraduate Innovation and Practical Ability Training Project(No.YCS23213089).
Among the many strategies for CO_(2)resource utilization,the synthetic technology of cyclic carbonates with 100%atom economy through CO_(2)and epoxide is one of the most industrially viable routes,but its efficiency h...
关键词：CO_(2)cycloaddition reaction Vacancy engineering Facet engineering Heterogeneous catalysis 
Diastereo-selective synthesis of CF_(3)-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide
《Green Synthesis and Catalysis》2023年第4期334-337,共4页Chenxin Ge Chao Chen 
This work was supported by the National Key Research and Development Program of China(No.2016YFB0401400);the National Natural Science Foundation of China(Nos.21871158 and 21672120);the Fok Ying Tong Education Foundation of China(No.151014).
The first example for the generation of 2,2,2-trifluoroethylidene ylide from corresponding iodonium salt is reported,which has been successfully applied in the epoxidation of aldehydes,achieving the corresponding tri-...
关键词：TRIFLUOROMETHYL EPOXIDATION EPOXIDES Iodonium ylide Trifluoroethylidenation 
Functionalization of nitrogen-doped graphene quantum dot:A sustainable carbon-based catalyst for the production of cyclic carbonate from epoxide and CO_(2)被引量：1
《Journal of Environmental Sciences》2023年第4期408-422,共15页Zahra Eshaghi Gorji Abbas Ali Khodadadi Siavash Riahi Timo Repo Yadollah Mortazavi Marianna Kemell 
supported by Iran National Science Foundation(No.97015707)。
A series of organic compounds were successfully immobilized on an N-doped graphene quantum dot (N-GQD) to prepare a multifunctional organocatalyst for coupling reaction between CO_(2)and propylene oxide (PO).The simul...
关键词：Heterogeneous organocatalyst CO_(2) Propylene carbonate N-doped graphene quantum dot Nanomaterials 
Unity Makes Strength:Constructing Polymeric Catalyst for Selective Synthesis of CO_(2)/Epoxide Copolymer被引量：2
《CCS Chemistry》2023年第3期750-760,共11页Ruoyu Zhang Qingxian Kuang Han Cao Shunjie Liu Xuesi Chen Xianhong Wang Fosong Wang 
The authors greatly appreciate the financial support from the National Natural Science Foundation of China(grant no.51988102);Key Research Program of Frontier Sciences,Chinese Academy of Sciences(CAS,grant no.QYZDJ-SSW-JSC017).
Catalyst design strategies such as bi-functional and di-nuclear catalysts have been developed based on intramolecular interactions,achieving excellent catalytic performance.However,most of these catalysts work in a st...
关键词：polymeric catalyst CO_(2)/epoxide copolymerization metal-synergistic effect Lewis pair effect 
Comparative Study on Properties of PBAT/PBSA Film Modified by a Multi-Functional Epoxide Chain Extender or Benzoyl Peroxide
《Journal of Renewable Materials》2023年第3期1303-1319,共17页Yanfeng Zhu Huidong Shi Qing Ju Dong Zhao Yucai Shen Tingwei Wang 
supported by Science and Technology Support Plan of Suqian(H201510);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);Nanjing Wurui Biodegradable Materials Research Institute.
Poly(butylene adipate-co-terephthalate)(PBAT)and poly(butylene succinate-co-adipate)(PBSA)blend films were prepared with different contents of a multifunctional epoxide chain extender Joncryl ADR-4468(ADR)or benzoyl p...
关键词：PBAT PBSA chain extend in-situ compatibilization 
Potassium Acetate/18-Crown-6 Pair:Robust and Versatile Catalyst for Synthesis of Polyols from Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides
《Chinese Journal of Chemistry》2023年第1期83-92,共10页Xiaoqing Dou Xiao-Hui Liu Bin Wang Yue-Sheng Li 
financial support from the National Natural Science Foundation of China(Nos.52222302 and 51973156).
Efficient synthesis of polyester polyols with tunable molecular weight and microstructures from cyclic anhydride/epoxide mixtures by taking advantage of chain transfer reaction remains a great challenge,because most o...
关键词：Ring-opening polymerization Macrocyclic ligands Block copolymer Cyclic Anhydride EPOXIDE 
Partners in Epoxide Copolymerization Catalysis:Approach to High Activity and Selectivity被引量：2
《Chinese Journal of Polymer Science》2022年第11期1331-1348,共18页Xiao-Bing Lu Bai-Hao Ren 
financially supported by the National Natural Science Foundation of China(No.21920102006)。
The ring-opening alternating copolymerization processes of epoxides with small-molecule monomers,such as carbon dioxide(CO_(2)),carbonyl sulfide(COS)and cyclic anhydrides,are powerful strategies for preparing polymeri...
关键词：EPOXIDE Ring-opening copolymerization Synergistic catalysis CO_(2) Stereochemistry control 
Environmentally benign metal catalyst for the ring-opening copolymerization of epoxide and CO_(2): state-of-the-art, opportunities, and challenges被引量：5
《Green Chemical Engineering》2022年第2期111-124,共14页Han Cao Shunjie Liu Xianhong Wang 
The authors greatly appreciated the financial support from National Natural Science Foundation of China(Grant No.51988102).
Carbon dioxide(CO_(2))is the main greenhouse gas,whereas it is also a nontoxic,abundant,cheap carbon and oxygen resource.The copolymerization of CO_(2) with epoxide presents a sustainable approach to the synthesis of ...
关键词：Green catalysis Aluminum catalyst Sustainable polymer CO_(2)valorization Ring-opening polymerization 
Tandem Lewis acid catalysis for the conversion of alkenes to 1,2‐diols in the confined space of bifunctional TiSn‐Beta zeolite被引量：4
《Chinese Journal of Catalysis》2021年第7期1176-1184,共9页Qifeng Lei Chang Wang Weili Dai Guangjun Wu Naijia Guan Michael Hunger Landong Li 
天津市自然科学基金(18JCJQJC47400,18JCZDJC37400);中央高校基本科研业务经费.
The generation of multifunctional isolated active sites in zeolite supports is an attractive method for integrating multistep sequential reactions into a single‐pass tandem catalytic reaction.In this study,bifunction...
关键词：Tandem catalysis Confinement effect ZEOLITE Alkene epoxidation Epoxide hydration 
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