This work was supported by the National Natural Science Foundation of China(22102012);the Changzhou Science and Technology Plan Applied Basic Research Project(CJ20210159 and CJ20210129);Henan University.
We have developed a practical and mild electrochemical protocol for cyanation and cyanomethylation of trimethylammonium salts through a pathway involving C–N bond cleavage without the need for an exter-nal stoichiome...
support was provided by the National Natural Science Foundation of China(21971165,21921002,21772035,22101189);National Key R&D Program of China(2018YFA0903500);National Natural Science Foundation of Hunan(2021JJ40150).
We present a phosphonium-containing catalyst generated in situ from phosphine and tert-butyl acrylate that serves as an unusual Lewis base catalyst.It was applied for the promotion of a remote 1,6-cyanation reaction o...