grateful for the financial support from the National Natural Science Foundation of China(No.22271083);the Open Project Funding of the State Key Laboratory of Biocatalysis and Enzyme Engineering(No.SKLBEE2021026);the Innovation and Entrepreneurship Training Program for Undergraduates of Hubei University(No.X202210512001).
A series of unreported fullerodihydropyridine-3-ones were synthesized as a new family of fullerene derivatives in moderate to good yields by a simple one-step reaction of[60]fullerene with cheap and readily available ...
supported by the National Natural Science Foundation of China(No.22031008);the Science Foundationof Wuhan(No.2020010601012192).
Mechanistic studies of the palladium catalyst activation with halide additives are of great importance to palladium catalysis.In this work,XAFS spectroscopy and cyclic voltammetry were utilized to study real structure...
This work was supported by the National Natural Science Foundation of China(No.21520102003);the Hubei Province Natural Science Foundation of China(No.2017CFA010);The Program of Introducing Talents of Discipline to Universities of China(111 Program)is also appreciated.All the XAFS data were collect-ed at beam line 44A of the TPS.
Pd(OAc)_(2) is an extensively utilized palladium source in the palladium initiated transformations either directly or as a catalyst precursor. However, the comprehension of the real structure of Pd(OAc)_(2) in solutio...
This work was financially supported by the National Natural Science Foundation of China (No. 21306126).
1D compound [Zn(Im)(HIm)2(OAc)] was used as a single precursor of metal and imidazole to prepare several 3-dimensional (3D) Zn(Im)2 frameworks by solution-mediated transformation. Specifically, three known t...
The authors are grateful for financial supports from the National Natural Science Foundation of China (NSFC Grant Nos. 21475145 and 21472228) and Youth Innovation Promotion Association CAS (201317 !).
Degradation of the highly reactive hypervalent trifluoromethylation iodine reagent PhI(OAc)(CF3), which can only be generated in situ with mixing PhI(OAc)2 and TMSCF3 in the presence of CsF, was studied by ESI-M...
the National Natural Science Foundation of China(Nos.21272069,20672035);the Fundamental Research Funds for the Central Universities,and the Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences.
The Pd-catalyzed homodimerization with respect to arylsulfonyl chlorides as an efficient method for the synthesisof biaryls has been developed. This desulfonylative reaction which was performed at reflux in 1,4-dioxan...
This work was supported by the Team Innovation Project of Soochow University.
The classical Ullmann C-S cross coupling reaction of aryl iodides with aromatic/alkyl thiols under catalysis of 15 mol%Cu(OAc)_(2)·H_(2)O and 15 mol%2,2'-biimidazole works at 80℃in DMSO for 3 h to provide a variety ...
An efficient strategy for the synthesis of a variety of 3-methyleneisoindolin-1-ones has been developed. The re- action proceeded from coupling of 2-iodobenzamides (or 2-bromobenzamides) and terminal alkynes via Cu...
Project supported by the Key Project of Chinese Ministry of Education (No. 206102), Fok Ying Dong Education Foundation (No. 101012), Scientific Research Fund of Hunan Provincial Education Department (No. 05B038), Hunan Provincial Natural Science Foundation of China (No. 05JJ1002) and the National Natural Science Foundation of China (Nos. 20572020 and 20202002)
Excellent results have been achieved in the Cu(OAc)2-catalyzed Sonogashira cross-couplings of aryl iodides and activated aryl bromides utilizing TBAF (tetrabutylammonium fluoride) as the base and 4,6-dimethoxypyri...
The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)(2)/HQ/FePc was investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexen...