The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this wo...
Financial support from National Natural Science Foundation of China(Nos.21931013 and 22271105);Natural Science Foundation of Fujian Province(No.2022J02009);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University;the Instrumental Analysis Center of Huaqiao University for analysis support;the Subsidized Project for Cultivating Postgraduates’Innovative Ability in Scientific Research of Huaqiao University。
A practical method for the construction of difluoromethylene-containing 1,4-thiazine moieties using readily available diethyl bromodifluoromethanephosphonate(BrCF_(2)PO(OEt)_(2))as difluorocarbene precusor has been de...
supported by the National Natural Science Foundation of China(Grant Nos.:82030107 and 81872831);the National Science and Technology Major Projects for significant new drugs creation of the 13th five-year plan(Grant Nos.:2017ZX09101001 and 2018ZX09721002007).
During the analysis of benziamidazole-class irreversible proton pump inhibitors,an unusual mass spectral response with the mass-to-charge ratio at[Mt10]t intrigued us,as it couldn't be assigned to any literature known...
supported by the National Key Research and Development Program of China(No.2022YFB3805100);the National Natural Science Foundation of China(No.22222812 and 22178330);the Anhui Provincial Key Research and Development Plan(No.202104b11020030);the Natural Science Foundation of Anhui Province(No.2108085MB33).
A series of poly(alkyl-biphenyl pyridinium)anion exchange membranes(AEMs)with a hydrophobic side chain were prepared for mono-/divalent anion separation using electrodialysis(ED).A poly(alkyl-biphenyl pyridinium)polym...
supported by the National Natural Science Foundation of China(Nos.51803205,11775214,and 21790371);China Scholarship Council(No.201906345006).
Over 70%of the treated contaminated water at the Fukushima Daiichi Nuclear Power Station contains radionuclides beyond the regulatory standard for discharge that need to be re-purified.Technetium-99(^(99)Tc),mainly in...
This work was supported by the National Natural Science Foundation of China(Nos.21871027 and 21573016).
Aphotoactive metal-organic complex[Zn2(BCbpe)2(p-DBC)2]∙5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl]pyridinium chloride(HBCbpeCl), and cha...
the funding received from the Agencia Estatal de Investigación and FEDER(PID2019-105272GB-I00 and CTQ2017-89166-R);the Xunta de Galicia(ED431C 2018/39 and 508/2020);the European Research Council(grant agreement no.851179);I.N.and P.C.thank,respectively,the MECD(FPU program,FPU2016/02347);Xunta de Galicia(Axudas de ApoioáEtapa de Formación Predoutoral,ED481A-2020/019)for financial support.A.B.G.thanks Xunta de Galicia for a Postdoctoral Fellowship(ED481B-2021-099);E.P.thanks the Agencia Estatal de Investigación for her Ramón y Cajal contract(RYC2019-027199-I);H.Li wants to thank the financial supports from the National Natural Science Foundation of China(no.91856116,21772173,and 21922108);the Natural Science Foundation of Zhejiang Province(no.LR18B020001).
We present herein the implementation of pH-responsiveness into a new polycationic macrobicyclic structure,namely what we have termed the“red cage”.The hydrolytically-stable cryptand-like compound has been prepared i...
National Natural Science Foundation of China (Nos. 21971092, 21901014, 21472072, 21871018, 21732001 and 21672017);Shenzhen Science and Technology Innovation Committee (No. JCYJ20200109141808025);Characteristic Innovation Project of Guangdong Provincial Education Department (No. 2020KTSCX295) for the financial support。
Pyridinium 1,4-zwitterionic thiolates were applied to a formal [3+2] annulation reaction with modified activated alkynes, affording various tetrasubstituted thiophenes with aryl, alkenyl, alkyl or silyl group at the s...
This work was supported by the National Natural Science Foundation of China(22061003,21861006);the Guangxi Natural Science Foundation of China(2016GXNSFEA380001,2019GXNSFAA245027);the Guangxi Key R&D Program(AB18221005);the Science and Technology Major Project of Guangxi(AA17204058-21);Guangxi Science and Technology Base and Special Talents(guike AD19110027).
This study proposes two different methods of photocatalytic-controlled and visible light-induced selective oxidation of pyridiniums with air as the terminal oxidant.The key to these transformations is to choose the ap...
the joint financial support from the National Natural Science Foundation of China (No. U1705256, 51972123, 21771066 and 61804058);the Cultivation Program for Postgraduate in Scientific Research Innovation Ability of Huaqiao University (No. 18014087027)。
Perovskite solar cells have developed rapidly in the past decades.However,there are large amounts of ionic defects at the surface and grain boundaries of perovskte films which are detrimental to both the efficiency an...