financial support from National Natural Science Foundation of China(Nos.21801129,22078153 and22378201);National Key Research and Development Program of China(No.2022YFB3805603);Natural science research projects in Jiangsu Higher Education Institutions(No.18KJB150018);Open Research Fund of School of Chemistry and Chemical Engineering;Henan Normal University(No.2024Y16);Nanjing Tech University(Start-up Grant Nos.39837137,39837101 and 3827401739)for financial support。
Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,p...
A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,elemen...
financial support from the National Natural Science Foundation of China(No.82003585);the Program for Science&Technology Innovation Talents in Universities of Henan Province(No.24HASTIT069);the Technical Innovation Team of Henan Normal University(No.2022TD03);the Special Project for Fundamental Research in University of Henan Province(No.23ZX009);the Henan Science and Technology Program(No.232102310364);the Key Project of Henan Educational Committee(No.22A150041);Excellent Youth Foundation of Henan Scientific Committee(No.222300420012);the Young Core Instructor Training Program of Xinyang Agriculture and Forestry University(2023)。
A transition-metal-and oxidant-free amination/cyclization reaction to access 1,2,4-triazolo[1,5-a]pyridines was realized in water by using amino diphenylphosphinate as amino source.A broad array of readily accessible ...
To expand the study on the structures and biological activities of the anthracyclines anticancer drugs and reduce their toxic side effects,the new anthraquinone derivatives,9‑pyridylanthrahydrazone(9‑PAH)and 9,10‑bisp...
supported by the RA MESCS Science Committee and Belarusian Republican Foundation for Fundamental Research in the frames of the joint research project SC No.21SC-BRFFR-1F007 and BRFFR Grant No.21ARM-014 accordingly,as well as from the Ministry of Science and Higher Education of Russian Federation within the framework of a state assignment(project No.FSRR-2023-0007)。
Using a photosensitizer(PS),light,and oxygen,photodynamic therapy creates cytotoxic reactive oxygen species,such as singlet oxygen(1O2),that kill cancer cells.Many cancer cell lines have up to 300 times more folic aci...
financially supported by the National Natural Science Foundation of China(Nos.21731002,21871172,21975104,22171106,22301103,22375075,and 82227802);the Guangdong Major Project of Basic and Applied Research(No.2019B030302009);Guangdong Natural Science Foundation(No.2022A1515011937);the Guangzhou Science and Technology Program(Nos.202002030411,202201020022);Guangdong Basic and Applied Basic Research Foundation(No.2022A1515110523);the China Postdoctoral Science Foundation(Nos.2023T160269,2023M741374);Jinan University。
Post-synthetic installation strategy is an effective approach to improve the functions of metal-organic frameworks(MOFs).Herein,a pair of chiral MOFs is successfully constructed through solvothermal subcomponent self-...
supported by the National Natural Science Foundation of China(Nos.22271046,21971038,21975044);the Fujian Provincial Department of Science and Technology(No.2019L3004);the Foundation of National Key Laboratory of Human Factors Engineering(No.HFNKL2023W04)。
Hydrogen-bonded organic frameworks(HOFs)are a promising candidate for optical sensing,but the lack of effective design strategies poses significant challenges to the construction of HOFs for organic acid sensing.In th...
financially supported by the National Natural Science Foundation of China(Nos.22271021,21971024);Liao Ning Revitalization Talents Program(XLYC1902011),which are gratefully acknowledged.
By employing a new semi-rigid pyrazole-amide-derived bis(pyridyl)ligand[N,N'-bis(4-picolylamine)-1-hydropyrazole(4-dpap)],a new homopolymolybdate-based two-dimensional(2D)plate-like complex[Co(4-dpap)(H_(2)O)(β-Mo_(8...
carried out according to the program of Fundamental Scientific Research of the Russian Federation
The article describes ethylene polymerization reactions with transition metal catalysts based on complexes of CoCl_(2) and FeCl_(2) with an N,N,N-tridentate ligand 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine. Th...
supported by the National Natural Science Foundation of China(22271100,21973113);the Key-Area Research and Development Program of Guangdong Province(2020-B010188001);the Guangdong Basic and Applied Basic Research Foundation(2023A1515010070);the China Postdoctoral Science Foundation(2021M701243)。
We disclose the development of the Rh-catalyzed amine-directed remote 5,6-carboamination protocol of pyridines via dual Csp^(2)-H functionalizations.A variety of readily available 2-aminopyridines and 1,2,3-triazoles ...