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作品数:1255被引量:1296H指数:13
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相关作者:陈建龙杨建成李旭锋刘志斌张华剑更多>>
相关机构:中国科学院大学中国科学院近代物理研究所东南大学中国科学院更多>>
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Reduced energetic disorder enables over 14%efficiency in organic solar cells based on completely non-fused-ring donors and acceptors被引量:1
《Science China Chemistry》2022年第12期2604-2612,共9页Chenyi Yang Lijiao Ma Ye Xu Junzhen Ren Jianhui Hou Shaoqing Zhang 
financially supported from the National Key Research and Development Program of China(2019YFE0116700);the Basic and Applied Basic Research Major Program of Guangdong Province(2019B030302007);the National Natural Science Foundation of China(21835006 and 22075017).
The large energetic disorder has been regarded as a limitation for the further advance of organic solar cells(OSCs).The intramolecular energetic disorder,which originates from the molecular conformational diversity,is...
关键词:completely non-fused-ring intramolecular energetic disorder charge transport energy loss low cost 
Highly insulating alkane rings with destructive σ-interference
《Science China Chemistry》2022年第9期1822-1828,共7页Jingyao Ye Alaa Al-Jobory Qian-Chong Zhang Wenqiang Cao Abdullah Alshehab Kai Qu Turki Alotaibi Hang Chen Junyang Liu Ali K.Ismael Zhong-Ning Chen Colin J.Lambert Wenjing Hong 
the financial supports by the National Natural Science Foundation of China(22173075,21933012,31871877,21703188 and 92061117);the National Key Research and Development Program of China(2017YFA0204902);the Fundamental Research Funds for the Central Universities(20720200068 and 20720190002);Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(2021ZR129);financial support from the UK EPSRC(EP/M014452/1,EP/P027156/1 and EP/N03337X/1);additionally supported by the European Commission is provided by the FET Open project 767187–QuIET;financial assistance from the Leverhulme Foundation(ECF-2020-638);Tikrit University(Iraq);the Iraqi Ministry of Higher Education(SL–20);financial assistance from Anbar University;financial assistance from King Faisal and Al-Jouf Universities(Saudi Arabia);the Saudi Ministry of Education。
Destructive quantum interference(DQI)provides a unique approach to controlling the leakage current in the OFF state of molecular devices.However,the DQI in π-conjugated molecular building blocks cannot exhibit ultral...
关键词:destructiveσ-interference charge transport single-molecule electronics insulating material alkane ring 
Phase transferring atomically precise gold nanoclusters to aqueous solution via single stranded DNA
《Science China Chemistry》2022年第6期1003-1004,共2页Qiangbin Wang 
Atomically precise gold nanoclusters (Au NCs) are an emerging class of quantum-sized nanomaterials. The intrinsic discrete electronic energy levels endowed them with fascinating electronic and optical properties [1]. ...
关键词:MATERIALS PRECISE CLUSTERS 
Phase transferring luminescent gold nanoclusters via single-stranded DNA被引量:1
《Science China Chemistry》2022年第6期1212-1220,共9页Yu Li Hui Lu Zhibei Qu Mingqiang Li Haoran Zheng Peilin Gu Jiye Shi Jiang Li Qian Li Lihua Wang Jing Chen Chunhai Fan Jianlei Shen 
supported by the National Key R&D Program of China (2020YFA0908104);the National Natural Science Foundation of China (91953106, 92056117, 21904087, 21705159);the Shanghai Municipal Science and Technology Commission (19JC1410300,19ZR1474600, 20dz1101000, 21QA1404800);the Fundamental Research Funds for the Central Universities and Shanghai Jiao Tong University。
Atomically precise gold nanoclusters(Au NCs) are an emerging class of quantum-sized nanomaterials with discrete electronic energy levels, which has led to a range of attractive electronic and optical applications. Nev...
关键词:gold nanoclusters DNA MONODISPERSED phase transfer biological application 
Low-cost polymer acceptors with noncovalently fused-ring backbones for efficient all-polymer solar cells被引量:3
《Science China Chemistry》2022年第5期926-933,共8页Xiaobin Gu Yanan Wei Xingzheng Liu Na Yu Laiyang Li Ziyang Han Jinhua Gao Congqi Li Zhixiang Wei Zheng Tang Xin Zhang Hui Huang 
supported by the National Natural Science Foundation of China (52103352, 52120105006, 21774130, 51925306);the National Key R&D Program of China (2018FYA 0305800);the Key Research Program of the Chinese Academy of Sciences (XDPB082);the Strategic Priority Research Program of Chinese Academy of Sciences (XDB28000000)。
The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,...
关键词:all-polymer solar cells low-cost polymer acceptors noncovalently fused-ring backbones figure-of-merit values 
Fused-ring electron acceptors in China被引量:1
《Science China Chemistry》2020年第9期1179-1181,共3页Boyu Jia Xiaowei Zhan 
the National Natural Science Foundation of China(21734001)。
In recent years,organic photovoltaics(OPVs)as one of nextgeneration solar energy technologies have attracted intense interest since they are featured with low cost,light weight,flexibility and semi-transparency[1].At ...
关键词:TRANSPARENCY INTENSE ACCEPTOR 
Modulating morphology via side-chain engineering of fused ring electron acceptors for high performance organic solar cells被引量:1
《Science China Chemistry》2019年第6期790-796,共7页Fuwen Zhao Dan He Jingming Xin Shuixing Dai Han Xue Li Jiang Zhixiang Wei Wei Ma Xiaowei Zhan Yongfang Li Chunru Wang 
supported by the National Postdoctoral Program for Innovative Talents (BX201700253);the China Postdoctoral Science Foundation (2017M620068, 2018M630208);the National Natural Science Foundation of China (21673257, 21805288);the Ministry of Science and Technology (2016YFA0200700)
In this work, four fused ring electron acceptors(FREAs), 2F-C5, 2F-C6, 2F-C8 and 2F-C10, are developed to investigate the effect of side-chain size on the molecular properties and photovoltaic performance of FREA syst...
关键词:solar cells FUSED RING electron ACCEPTOR SIDE-CHAIN LENGTH MORPHOLOGY 
A strategic study towards constructing the nine-membered azonane ring system of palhinine A via an azidoketol fragmentation reaction
《Science China Chemistry》2016年第9期1188-1196,共9页Fang-Xin Wang Peng-Lin Zhang Hui-Bin Wang Guo-Biao Zhang Chun-An Fan 
supported by the National Natural Science Foundation of China (21572083, 21322201, 21290180);the Fundamental Research Funds for the Central Universities (lzujbky-2015-48, lzujbky2016-ct07);Program for Changjiang Scholars and Innovative Research Team in University (IRT_15R28);the 111 Project of MOE of China (111-2-17)
A proposed strategy for constructing the nine-membered azonane ring system embedded in the isotwistane framework of palhinine A has been preliminarily studied on the basis of an azidoketol fragmentation reaction toget...
关键词:ALKALOIDS azonane ring isotwistane natural product synthesis pinacol coupling fragmentation reaction 
The scaling behavior of the second virial coefficient of linear and ring polymer
《Science China Chemistry》2016年第5期619-623,共5页Bing Li Zhaoyan Sun Lijia An Zhen-Gang Wang 
supported by the National Basic Research Program of China (2012CB821500);the National Natural Science Foundation of China (21222407, 21474111)
The scaling behavior of the second virial coefficient of ring polymers at the theta temperature of the corresponding linear polymer(θ_L) is investigated by off-lattice Monte Carlo simulations. The effects of the solv...
关键词:second virial coefficient topological constraints 3-body interactions theta temperature scaling behavior 
Mechanism of Pd-catalyzed selective C–H activation of aliphatic amines via four-membered-ring cyclometallation pathway
《Science China Chemistry》2015年第8期1316-1322,共7页Qi Zhang Haizhu Yu Yao Fu 
supported by the National Natural Science Foundation of China(21325208,21172209,21361140372,21202006);the National Basic Research Program of China(2012CB215306);Financial Resources Federal Credit Union(WK2060190025,WK2060190040,FRF-TP-14-015A2);Chinese Academy of Sciences(KJCX2-EW-J02);Program for Changjiang Scholars and Innovative Research Team and the supercomputer center of Shanghai and USTC
A theoretical study is carried out on Gaunt's palladium-catalyzed selective C(sp3)-H activation of unprotected aliphatic amines. In this reaction, the methyl group is proposed to be activated through a four-membere...
关键词:C(sp3)-H activation CHEMOSELECTIVE density functional theory 
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