Scientific Research Project of General Universities in Guangdong Province(2023KTSCX036);Science and Technology Planning Program of Zhanjiang(2023B01015)for support.
Ketenimine zwitterionic salt(KZS),a novel and stable ketenimine precursor,is still underexplored in the realm of chemical synthesis.In this study,we demonstrate the transformation of pyrrole derivatives through the cy...
the National Natural Science Foundation of China(22101215);the Independent Research Foundation of Key Laboratory of Green and Precise Synthetic Chemistry and Applications in Huaibei Normal University,Ministry of Education(KLGPSCA202208);the University Top Talents Academic Funding Project of Anhui Province(gxbjzD2021097),the Natural Science Foundation of Educational Committee from Anhui Province and Huaibei Normal University(KJ2020A0045;2023ZK078;2023ZK079);University Outstanding Young Talents Support Program of Anhui Province(2023AH030078);the Crosswise Tasks of Huaibei Normal University(22100280).
Although various routes have been reported for haloazidation,unavoidable problems exist,such as environmentally unfriendly monomer halogen,the need for in situ generation of unstable halogen azides(XN3),applicability ...
We gratefully acknowledge National Natural Science Foundation of China(22101291,22171277,21821002);National Key R&D Program of China(2021YFA1500200);Shanghai Rising-Star Program(20QA1411400);Shanghai Institute of Organic Chemistry,and State Key Laboratory of Organometallic Chemistry for finan cial support.
Comprehensive Summary A novel transient SET mediator approach has been developed for the photoinduced radical-radical cross coupling reaction.Using the in-situ generated thianthrene radical cation as the transient SET...
Support by the National Natural Science Foundation of China(No.21901052);the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(2019);the Guangzhou Education Bureau University Scientific Research Project(No.201831845);Guangdong Basic and Applied Basic Research Foundation(No.2020A1515010722)is most gratefully acknowledged.
Main observation and conclusion The electrochemical thiocyanation/cyclization of aldehyde hydrazones was developed under external oxidant-free and catalyst-free conditions.In contrast to previous thiocyanation,this el...
We are grateful for financial support from the National Natural Science Foundation of China(Nos.21772081,21825105,21801117);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);the Guangdong Innovative Program(No.2019BT02Y335);the Shenzhen Special Funds(No.JCYJ2018030-5123508258);Shenzhen Nobel Prize Scientists LaboratoryProject(No.C17213101).
of main observation and conclusion Privileged 2-amino-2,-hydroxy-l/l,-binaphthyl(NOBIN)frameworks were constructed through a novel domino arylation of naphthylhydroxylamines with diarylhalonium salts and sigmatropic r...
This work was supported by the National Key Research and Development Program of China(2019YFA0905100);the National Natural Science Foundation of China(Nos.21772142,21901181,and 21971186);Tianjin Municipal Science&Technology Commission(19JCQNJC04700).
Aryl diazonium salts occupy a privileged role in synthetic chemistry owing to their ready availability and versatile reactivity.While their applications in accessing diversely functionalized arene derivatives via deni...
The authors gratefully acknowledge the finalncial support from the National Natural Science Foundation of China(Nos.21421002,201871283,21737004,21672239);Science and Tech-nology Commission of Shanghai Municipality(No.17ZR1437000);the Foundation of Science and Technology on Sanming Insti-tute of Fluorochemical Industry(FCIT201701BR).
Summary of main observation and conclusion The limited availability of highly valuable arenesulfonyI fluorides seriously hinders their further applica-tion in many research fields including medicinal chemistry and che...
The solubilities of benzene and diphenyl in mixed solvents of t-butyl alcohol(TBA) and water with different salts have been determined at T = 298.15, 303.15, 308.15 and 313.15K. The molar fraction of TBA [x(TBA)] in m...
Project supported by the National Natural Science Foundation of China (No. 29790120);Chinese Academy of Sciences (No. KJ951-A1-506-04)
Photolysis of diethyl ether-oxygen charge transfer complex in the presence of Sn(Ⅱ)or Cu(Ⅱ)salts gave higher yields of the oxidation products,ethyl acetate,acetaldehyde,ethanol,ethyl formate and methanol compared w...
Several new tetrahydroisoquinolinium salts, analogues of atracurium, were designed and synthesized. These compounds were prepared from optically pure tetrahydropapaverine and hexamethylene diglycidate.