SALTS

作品数:329被引量:429H指数:8
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相关领域:理学更多>>
相关作者:刘红霞李润涛余爱农胡卫兵向必坤更多>>
相关机构:北京大学合肥通用机械研究院浙江中广电器有限公司湖北民族大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家民委科研基金更多>>
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Solvent-or Base-Controlled Diastereoselectivity and Chemoselectivity for the Reaction of Ketenimine Zwitterionic Salts
《Chinese Journal of Chemistry》2025年第1期67-72,共6页Weiguang Yang Guanrong Li Zixin Huang Qiaoli Luo Hui Luo 
Scientific Research Project of General Universities in Guangdong Province(2023KTSCX036);Science and Technology Planning Program of Zhanjiang(2023B01015)for support.
Ketenimine zwitterionic salt(KZS),a novel and stable ketenimine precursor,is still underexplored in the realm of chemical synthesis.In this study,we demonstrate the transformation of pyrrole derivatives through the cy...
关键词:DIASTEREOSELECTIVITY CHEMOSELECTIVITY Ketenimine zwitterionic salts Solvent-controlled Base-controlled α-Aminoketones 2-Aminopyrrole 3-Hydroxypyrrolidine Cyclization 
Controlling the Reactivity of IBA-N_(3)by Switching Halogen Salts:Providing a Universal Strategy for Haloazidation of Alkenes
《Chinese Journal of Chemistry》2024年第16期1839-1845,共7页Chen-Xi Xia Xin-Lei Sun Jinfeng Zhang Yue Ren Yan Yu Kuai Wang Ling-Guo Meng 
the National Natural Science Foundation of China(22101215);the Independent Research Foundation of Key Laboratory of Green and Precise Synthetic Chemistry and Applications in Huaibei Normal University,Ministry of Education(KLGPSCA202208);the University Top Talents Academic Funding Project of Anhui Province(gxbjzD2021097),the Natural Science Foundation of Educational Committee from Anhui Province and Huaibei Normal University(KJ2020A0045;2023ZK078;2023ZK079);University Outstanding Young Talents Support Program of Anhui Province(2023AH030078);the Crosswise Tasks of Huaibei Normal University(22100280).
Although various routes have been reported for haloazidation,unavoidable problems exist,such as environmentally unfriendly monomer halogen,the need for in situ generation of unstable halogen azides(XN3),applicability ...
关键词:Haloazidation ALKENE IBA-N_(3) Halogen salts Difunctionalization Selectivity Radicals Synthetic methods 
Thianthrene Radical Cation as a Transient SET Mediator:Photoinduced Thiocyanation and Selenocyanation of Arylthianthrenium Salts被引量:1
《Chinese Journal of Chemistry》2023年第16期1979-1986,共8页Xiao-Yue Chen Xin Kuang Yichen Wu Jian Zhou Peng Wang 
We gratefully acknowledge National Natural Science Foundation of China(22101291,22171277,21821002);National Key R&D Program of China(2021YFA1500200);Shanghai Rising-Star Program(20QA1411400);Shanghai Institute of Organic Chemistry,and State Key Laboratory of Organometallic Chemistry for finan cial support.
Comprehensive Summary A novel transient SET mediator approach has been developed for the photoinduced radical-radical cross coupling reaction.Using the in-situ generated thianthrene radical cation as the transient SET...
关键词:Transient SET mediator Thiocyanation and selenocyanation Arylthianthrenium salts Radical reaction Photosynthesis 
Direct Electrochemical Synthesis of Sulfur-Containing Triazolium Inner Salts被引量:1
《Chinese Journal of Chemistry》2021年第4期942-946,共5页Yueheng Li Zhixing Huang Guangquan Mo Wei Jiang Chengwei Zheng Pengju Feng Zhixiong Ruan 
Support by the National Natural Science Foundation of China(No.21901052);the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(2019);the Guangzhou Education Bureau University Scientific Research Project(No.201831845);Guangdong Basic and Applied Basic Research Foundation(No.2020A1515010722)is most gratefully acknowledged.
Main observation and conclusion The electrochemical thiocyanation/cyclization of aldehyde hydrazones was developed under external oxidant-free and catalyst-free conditions.In contrast to previous thiocyanation,this el...
关键词:ELECTROCHEMISTRY THIOCYANATION CYCLIZATION Aldehyde Hydrazone Triazolium 
Direct Construction of NOBINs via Domino Arylation and Sigmatropic Rearrangement Reactions被引量:3
《Chinese Journal of Chemistry》2020年第12期1503-1514,共12页Ji-Wei Zhang Liang-Wen Qi Shaoyu Li Shao-Hua Xiang Bin Tan 
We are grateful for financial support from the National Natural Science Foundation of China(Nos.21772081,21825105,21801117);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);the Guangdong Innovative Program(No.2019BT02Y335);the Shenzhen Special Funds(No.JCYJ2018030-5123508258);Shenzhen Nobel Prize Scientists LaboratoryProject(No.C17213101).
of main observation and conclusion Privileged 2-amino-2,-hydroxy-l/l,-binaphthyl(NOBIN)frameworks were constructed through a novel domino arylation of naphthylhydroxylamines with diarylhalonium salts and sigmatropic r...
关键词:process. REARRANGEMENT SALTS 
Aryl Diazonium Salt-Triggered Cyclization a nd Cycloaddition Reactions: Past, Present, and Future被引量:3
《Chinese Journal of Chemistry》2020年第10期1132-1152,共21页Fa-Guang Zhang Zhen Chen Chi Wai Cheung Jun-An Ma 
This work was supported by the National Key Research and Development Program of China(2019YFA0905100);the National Natural Science Foundation of China(Nos.21772142,21901181,and 21971186);Tianjin Municipal Science&Technology Commission(19JCQNJC04700).
Aryl diazonium salts occupy a privileged role in synthetic chemistry owing to their ready availability and versatile reactivity.While their applications in accessing diversely functionalized arene derivatives via deni...
关键词:SALTS summarized retaining 
Arenesulfonyl Fluoride Synthesis via Copper-free Sandmeyer-type Fluorosulfonylation of Arenediazonium Salts被引量:2
《Chinese Journal of Chemistry》2020年第10期1107-1110,共4页Qiongzhen Lin Zhanhu Ma Changge Zheng Xiao-Jun Hu Yong Guo Qing-Yun Chen Chao Liu 
The authors gratefully acknowledge the finalncial support from the National Natural Science Foundation of China(Nos.21421002,201871283,21737004,21672239);Science and Tech-nology Commission of Shanghai Municipality(No.17ZR1437000);the Foundation of Science and Technology on Sanming Insti-tute of Fluorochemical Industry(FCIT201701BR).
Summary of main observation and conclusion The limited availability of highly valuable arenesulfonyI fluorides seriously hinders their further applica-tion in many research fields including medicinal chemistry and che...
关键词:FLUORINE ATTRACTIVE SALTS 
Effect of Different Salts on the Solubilities of Benzene and Diphenyl in t-Butyl Alcohol-Water Mixture and Hydrophobic Interaction被引量:2
《Chinese Journal of Chemistry》2002年第1期1-8,共8页邹立壮 王晓玲 朱书全 韩布兴 刘瑞麟 阎海科 
theNationalNaturalScienceFoundationofChina (No.2 95 73144 )
The solubilities of benzene and diphenyl in mixed solvents of t-butyl alcohol(TBA) and water with different salts have been determined at T = 298.15, 303.15, 308.15 and 313.15K. The molar fraction of TBA [x(TBA)] in m...
关键词:hydrophobic interaction solubility BENZENE DIPHENYL t-butyl alcohol Gibbs energy salting effect 
Photolysis of oxygen saturated ethers in the presence of Sn(Ⅱ) or Cu(Ⅱ) salts
《Chinese Journal of Chemistry》2000年第6期936-939,共4页施敏 
Project supported by the National Natural Science Foundation of China (No. 29790120);Chinese Academy of Sciences (No. KJ951-A1-506-04)
Photolysis of diethyl ether-oxygen charge transfer complex in the presence of Sn(Ⅱ)or Cu(Ⅱ)salts gave higher yields of the oxidation products,ethyl acetate,acetaldehyde,ethanol,ethyl formate and methanol compared w...
关键词:PHOTOLYSIS Sn(Ⅱ) salt Cu(Ⅱ) salt ether oxidation products 
Asymmetric synthesis of some new tetrahydroisoquinolinium salts
《Chinese Journal of Chemistry》1998年第2期162-170,共9页尤启冬 
Several new tetrahydroisoquinolinium salts, analogues of atracurium, were designed and synthesized. These compounds were prepared from optically pure tetrahydropapaverine and hexamethylene diglycidate.
关键词:Tetrahydrooisoquinolinium salt neuromuscular blocking agent asymmetric synthesis 
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