SUZUKI-MIYAURA

作品数:32被引量:54H指数:4
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相关领域:理学更多>>
相关作者:张道刘国华张玉利陈友彭晖更多>>
相关机构:国立中兴大学湖南师范大学四川大学复旦大学更多>>
相关期刊:《石河子大学学报(自然科学版)》《Chemical Research in Chinese Universities》《精细化工》《International Journal of Organic Chemistry》更多>>
相关基金:国家自然科学基金天津市自然科学基金浙江省自然科学基金江西省自然科学基金更多>>
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基于电喷雾-离子淌度质谱技术检测铃木-宫浦的反应中间体
《质谱学报》2024年第1期165-173,I0006,共10页李哲 邱朝辉 王伟民 徐福兴 丁传凡 
科技部重大科学仪器设备开发(2020YFF01014601);国家自然科学青年基金(22104067)。
本研究主要以铃木-宫浦反应(Suzuki-Miyaura)中的C—C偶联反应为研究对象,使用四(三苯基膦)钯作为催化剂,将3-溴吡啶、3-溴喹啉、3-溴-5-苯基吡啶分别与苯硼酸、2-甲基苯硼酸、3,5-二甲基苯硼酸在甲苯溶剂环境中进行“一锅法反应”。反...
关键词:捕集离子淌度飞行时间质谱(TIMS-TOF MS) 反应中间体 离子迁移率 铃木-宫浦反应(Suzuki-Miyaura) 
Topochemical polymerization of hydrogen-bonded organic framework for supporting ultrafine palladium nanoparticles
《Science China Chemistry》2023年第7期2019-2027,共9页Xu Ding Bin Han Baoqiu Yu Hailong Wang Jianzhuang Jiang 
supported by the Natural Science Foundation of China(22235001,22175020,22131005,22011540002,21631003);the Xiaomi Young Scholar Program;the Fundamental Research Funds for the Central Universities;University of Science and Technology Beijing
Topochemical polymerization of molecular crystals into porous materials is of significance due to their promising applications in the field of adsorption and catalysis,yet rarely reported due to the synthesis difficul...
关键词:hydrogen-bonded organic frameworks topochemical polymerization palladium nanoparticles nitrophenol degradation organic dyes degradation Suzuki-Miyaura coupling reaction 
One-step assembly of Pd-Keggin-polyoxometalates for catalytic benzothiadiazole generation and derived cell-imaging probe application被引量:1
《Chinese Chemical Letters》2023年第6期545-550,共6页Xianqiang Huang Weilong Cui Sen Liu Gang Liu Yalin Zhang Zhihao Zhang Guodong Shen Zhen Li Jianyong Wang Yifa Chen 
financially supported by National Natural Science Foundation of China(Nos.21871125,22171139,21801145 and 21901122);the Natural Science Foundation of Shandong Province,China(Nos.ZR2019MB043 and ZR2019QB022);Shandong Provincial Key R&D Program/Major Science and Technology Innovation Project of Shandong Province(No.2019JZZY020230);the Construction Project of Quality Curriculum for Postgraduate Education of Shandong Province(No.SDYKC19057)。
One-step assembly of organic-ligand modified Pd-Keggin-POMs has been rarely reported,so as for their applications in catalytic benzothiadiazole generation and derived cell-imaging probing.Herein,three PdKeggin-POMs(co...
关键词:Metal-organic-pallidum-POMs Crystal structure SUZUKI-MIYAURA Fluorescent probe LDs 
Improved Catalytic Reaction of Biotemplated Palladium Nanoparticles through Immobilized Metal Affinity Purification
《Advances in Nanoparticles》2023年第1期22-31,共10页Shadrach Ibinola Hazim Aljewari Imann Mosleh Robert Beitle 
To investigate the effect purification plays on nanoparticle (NP) synthesis and catalytic activity, three copies of Pd4 (TSNAVHPTLRHL) fused to the N-terminus of Green Fluorescent Protein (GFP) was produced recombinan...
关键词:Protein Expression Nanoparticle Synthesis Turnover Frequency SUZUKI-MIYAURA 
Single-atom Pd catalyst anchored on Zr-based metal-organic polyhedra for Suzuki-Miyaura cross coupling reactions in aqueous media被引量:7
《Nano Research》2021年第2期486-492,共7页Seongsoo Kim Seohyeon Jee Kyung Min Choi Dong-Sik Shin 
the Basic Science Research Program(No.NRF-2019R1A2C4069764);by Convergent Technology R&D Program for Hum an Augm entation(No.2019M3C1B8077549)through the National Research Foundation of Korea(NRF)funded by Ministry of Science and ICT.
The challenge for single-atom catalysts in various C-C cross coupling reaction exists in the development of solid supporting materials.It has been desired tofind a supporting material designed in molecular level to an...
关键词:metal-organic polyhedra Suzuki-Miyaura cross coupling reaction structure characterization aqueous phase reaction high-degree of dispersion 
Synthesis of Enaminone-Pd(Ⅱ)Complexes and Their Application in Catalysing Aqueous Suzuki-Miyaura Cross Coupling Reaction被引量:6
《Chinese Journal of Chemistry》2020年第3期254-258,共5页Leiqing Fu Xiaoji Cao Jie-Ping Wan Yunyun Liu 
the National Natural Sci-ence Foundation of China(No.21861019);the Education Department of Jiangxi Province(No.GJJ170213).
A series of Pd(Ⅱ)-enaminone complexes,termed Pd(eao)2,have been synthesized and characterized.The investigation on the catalytic activities of these new Pd(Ⅱ)-reagents has proved that the Pd(ea0)2-1 possesses excell...
关键词:SUZUKI Pd(Ⅱ) BORON 
钯碳催化Suzuki-Miyaura反应合成芳杂环取代三苯胺衍生物被引量:4
《精细化工》2019年第5期1016-1020,共5页闫营营 刘春 
国家自然科学基金(21776036;21421005;21276043)~~
以芳杂环卤代物和4-硼酸三苯胺为原料,以Pd/C为催化剂,在乙醇水溶液中经Suzuki-Miyaura(SM)反应合成了芳杂环取代三苯胺衍生物。以2-溴吡啶与4-硼酸三苯胺的反应为模型反应,考察了溶剂、碱、温度及催化剂用量对反应的影响。得到的最优...
关键词:钯碳 Suzuki-Miyaura反应 三苯胺衍生物 水相 精细化工中间体 
Synthesis, Crystal Structure and Catalytic Activity of a Pd-PEPPSI Complex Bearing Bromine Group被引量:1
《Chinese Journal of Structural Chemistry》2019年第3期429-433,共5页LI Ying HAN Fang-Wai XU Zi-Yang WANG Ru YAN Chen-Xin OU You-Jing LU Qian LIU Gui-Yan ZENG Yong-Fei 
Supported by the Natural Science Foundation of Tianjin(No.16JCYBJC19700);the National Natural Science Foundation of China(No.21771138);the Foundation of Development Program of Future Expert in Tianjin Normal University(No.WLQR201704)
A new Pd-PEPPSI complex(2) with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-crystal diffraction. Complex 2 crystallizes in monoclinic...
关键词:Pd-PEPPSI COMPLEX crystal structure catalytic activity SUZUKI-MIYAURA CROSS-COUPLING aryl chlorides 
Cobalt Schiff base complexes: Synthesis characterization and catalytic application in Suzuki–Miyaura reaction被引量:1
《Chinese Journal of Chemical Engineering》2019年第3期556-563,共8页Rasheeda M.Ansari Lolakshi K.Mahesh Badekai Ramachandra Bhat 
the National Institute of Technology Karnataka for the financial support
3-Methoxysalicylaldehyde was condensed with the amines 4-aminoacetophenone and 2-amino-5-bromopyridine to obtain Schiff base ligands, 1 and 2, which were coordinated to cobalt salts as complex 1 and complex 2, respect...
关键词:Transition metal complex Schiff base Suzuki-Miyaura coupling reaction COBALT 
钯催化2-溴-1,3,5-三甲基苯和异丙基硼酸Suzuki-Miyaura偶联反应中配体对产物选择性调控的理论研究被引量:1
《中国科学:化学》2019年第2期380-390,共11页章雨桐 曹梦娜 戈光琼 项楚越 宋志军 马香娟 房升 雷群芳 方文军 谢湖均 
国家自然科学基金(编号:21203166;21473157);浙江省自然科学基金(编号:LY17B050001);浙江工商大学食品科学与工程一流学科建设(编号:2017SICR112)资助项目
采用密度泛函理论(DFT)计算,我们研究了钯催化2-溴-1,3,5-三甲基苯和异丙基硼酸发生Suzuki-Miyaura偶联反应的机理,并考察了催化剂中的膦配体对产物选择性的影响.计算结果表明,反应机理主要包含3个步骤,涉及氧化加成、转金属化和还原消...
关键词:钯催化 DFT计算 反应机理 SUZUKI-MIYAURA 选择性 
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