the“Thousand Talents Program”of China;the National Natural Science Foundation of China(No.21101170 and 21573139);the Fundamental Research Funds for the Central Universities;the Research Funds of Shaanxi Normal University。
In this work,three stable dumbbell-shaped silver clusters 1~3,formed by a novel bifunctional ligand Ph2P-C6H4-3-C=CH,are presented.All three complexes have cage structures constructed with thirty-six silver atoms,whic...
the sponsorship and financial support from the Key Laboratory of Organic Synthesis of Jiangsu Province
A 2D plane coordination compound [Ag_2(Dpya)_2.(NO_3)_2]n was synthesized and characterized by FT-IR,elemental analysis and TG analysis.The red crystal was obtained via solvent diffusion method at room temperature...
supported by the National Natural Science Foundation of China(No.21173197)
Two silver(I)-sulfonate complexes,[Ag(NO3)(4,4'-bipy)][Ag(HL)(4,4'-bipy)]·2H2O(1) and[Ag(H2O)(4,4'-bipy)][AgL(4,4'-bipy)]·2H2O(2),have been synthesized by in situ reaction(H2L = 2-formylbenz...
supported by the Natural Science Foundation of Fujian Province(2012J06006,2006L2005)
A new metal-organic coordination polymer, [Ag(L)(NO3)]H (1, L = β-amino-β- (pyrid-2-yl)acrylonitrile), has been synthesized by solvent method at ambient temperature and characterized through single-crystal d...
Supported by the National Natural Science Foundation of China(No.21373132);the Science Foundation of Shaanxi University of Technology(No.SLGKY-36)
A new AgO) coordination polymer, {[Ag(1,3-BIP)(H20)][Ag(1,3- BIP)(PMA)0.5.- 4H20}n (PMA = 1,2,4,5-benzenetricarboxylic acid, 1,3-BIP = 1,3-bis(imidazole)propane), have been synthesized and characterized b...
supported by the National Natural Science Foundation of China(51172232)
A three-coordinate Ag(I) complex, [Ag(Mepzpy)(PAr3)]BF4·H2O(1, Mepzpy = 3-methyl-1-(2-pyridyl)pyrazole, PAr3 = tri(o-tolyl)phosphine), was synthesized from the reaction of Ag(CH3CN)4BF4, PAr3 and Mepzpy...
supported by the National Natural Science Foundation of China(No.21373178);the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China(No.13JS124)
A new 3D Ag(I) coordination polymer, [Ag8(btc)2(bpp)2]n(1, H4btc = biphenyl- 2,2ˊ,4,4ˊ-tetracarboxylic acid, bpp = 1,2-bis(4-pyridyl)propane), has been hydrothermally synthesi- zed and characterized by sin...
supported by the National Natural Science Foundation of China(Nos.21101075 and 21201081);the Research Foundation for Excellent Young and Middle-aged Scientists of Shandong Province(No.BS2011CL009 and BS2012CL008);China Postdoctoral Science Foundation funded project(No.2012M521321);High Educational Science&Research Foundation of Shandong Province(No.J11LB52 and J13D58);Post Doctoral Innovation Project of Shandong Province(201303097)
One new AgI complex, [Ag(apca)(H2O)]n (Hapca = 3-aminopyrazine-2-carboxylic acid), has been prepared and structurally and spectroscopically characterized. The title complex (1) crystallizes in the monoclinic s...
Supported by the Key Scientific Research Foundation of Shaanxi Provincial Education Office of China(Nos.2010JS061 and 11JS114);Natural Scientific Research and Overall Innovation Plan Major Project of Shaanxi Provincial Education Office of China(No.2012KTCL03-16);Natural Scientific Research Foundation of Shaanxi Provincial Science and Technology Office of China(Nos.2013Jk0668 and 09JK823)
A new coordination polymer, [Ag(3,3-pybz)(3,3-Hpybz)]n (1, 3,3-Hpybz = 3-pyri- din-3-yl-benzoic acid), has been synthesized and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray dif...
supported by the National Natural Science Foundation of China (20871099);the Natural Science Foundation of Gansu Province (0710RJZA113)
A novel binuclear Ag(I) complex [Ag2(C6H6NaO)2(C6H7N3O)2]·2CH3CN (1) was synthesized by the evaporation reaction of silver nitrate and (E)-1-(pyrazin-2-yl)ethanone oxime (HL). The complex was characteri...