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Chlorinated Polythiophene-Based Donors with Reduced Energy Loss for Organic Solar Cells
《Chinese Journal of Chemistry》2024年第24期3405-3413,共9页Huixue Li Junzhen Ren Lijiao Ma Zhihao Chen Yue Yu Jianqiu Wang Shaoqing Zhang 
supported by the National Natural Science Foundation of China(22075017).
The industrialization of organic solar cells(OSCs)faces challenges due to complex synthesis routes and high costs of organic photovoltaic materials.To address this,we designed and synthesized a series of polythiophene...
关键词：Organic solar cell Low energy loss Simple chemical structure Conjugated polymers Poly(thienylene vinylene) 
Recent Advances of Imide-Functionalized Polymer Donors for Non-fullerene Solar Cells
《Chinese Journal of Chemistry》2024年第15期1759-1780,共22页Huijuan Wang Songmin Mo Dongyan Li Qinghe Wu 
supported by the National Natural Science Foundation of China(22179076);the Natural Science Foundation of Guangdong Province(2022A1515011803,2023B1212120011);the Department of Education of Guangdong Province(2021KCXTD032).
In recent years,there has been a shift towards using non-fullerene electron acceptors in organic solar cells(osCs)as a replacement for fullerene derivatives.This change requires polymer donors that possess compatible ...
关键词：IMIDE Polymer donors Organic solar cells Synthetic routes Polymer structure evolution 
Stereoselectiveα-Glycosylation with GlcN_(3)Donors Enabled Collective Syntheses of Acinetobacter baumannii Capsular Polysaccharides K43,K47 and K88 Repeating Units
《Chinese Journal of Chemistry》2024年第14期1593-1598,共6页Kunxiu Shou Shanshan Liu Yunqin Zhang Guozhi Xiao 
supports from National Natural Science Foundation of China(22322110);the CAS Pioneer Hundred Talents Program(No.2017-128);Yunnan Province Science and Technology Department(202305AH340005);the Young Talents Project of High-level Talent Introduction Program of Yunnan Province are greatly acknowledged。
Collective syntheses of A.baumannii CPS K43,K47 and K88 repeating units have been accomplished via a newα-glycosylation method with GlcN_(3) as donors,which features:1)mild reaction conditions,2)good to high yields,3...
关键词：A baumanni CPS α-Glycosylation method One-pot glycosylation 1 2-GlcN bonds Glycosyl ortho-(1-phenylvinyl)benzoates Carbohydrates OLIGOSACCHARIDES Total synthesis 
Semicrystalline Unfused Polymer Donors with Backbone Halogenation toward Cost-Effective Organic Solar Cells被引量：1
《Chinese Journal of Chemistry》2024年第7期752-759,共8页Yuxin Kong Shijie Ju Hongmei Qin Min Hun Jee Simeng Xia Jiaqi Ren Chao Gao Jianyu Yuan Wenyan Su Han Young Woo Yuxiang Li 
supported by the National Natural Science Foundation of China (52203241,21905225,22005121);the Science and Technology Program of Shaanxi Province (2022JM-229,2023-JC-QN-0448);Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Soochow University (KJS2208);H.Y.W.acknowledges the financial support from the National Research Foundation of Korea (2019R1A6A1A11044070,2020M3H4A3081814).
Developing novel unfused building blocks with simple synthesis and low cost is essential to advance and enrich cost-effective poly-mer donors;however,it remains a challenge due to the lack of efficient molecular strat...
关键词：Low-cost Polymer donors Backbone halogenation Molecular self-assembly Organic solar cells 
Revisiting the Bithiophene Imide-Based Polymer Donors: Molecular Aggregation and Orientation Control Enabling New Polymer Donors for High-Performance All-Polymer Solar Cells被引量：2
《Chinese Journal of Chemistry》2022年第24期2900-2908,I0002,共10页Jie Yang Bin Liu Jin-Woo Lee Yimei Wang Huiliang Sun Zhicai Chen Qingqing Bai Bumjoon J.Kim Yan Jiang Li Niu Xugang Guo 
support from the Songshan Lake Mate-rials Laboratory(2021SLABFK03);This work is supported by the National Natural Science Foundation of China(52173172,52173171,and 21801124);the Natural Science Foundation for Distinguished Young Scholars of Guangdong Province(2021B1515020027);the Guangdong Basic and Applied Basic Research Foundation(2021A1515110892);the China Postdoctoral Science Foundation(2021M700062);the Shenzhen Science and Technology Innovation Commission JCYJ202103243104813035 and JCYJ20180504165709042);the Open Fund of the State Key Laboratory of Luminescent Materials and Devices(South China University of Technology).
Bithiophene imide (BTI)-based polymers have been promising photovoltaic materials due to their high mobility and tunable energy levels. However, BTI polymers have rarely been revisited since organic solar cells (OSCs)...
关键词：Bithiophene imide Molecular orientation ISOMERIZATION Polymer donors All-polymer solar cells 
Halogen Bond Catalysis on Carbonyl-Olefin Ring-Closing Metathesis Reaction:Comparison with Lewis Acid Catalysis
《Chinese Journal of Chemistry》2022年第11期1275-1284,共10页Ying Li Yuanyuan Sun Lingpeng Meng Qingzhong Li Yanli Zeng 
This work was supported by the Natural Science Foundation of Hebei Province(B2019205113,B2019205061);the National Natural Science Foundation of China(21973025);the Science Foundation of Hebei Normal University(L2020Z04).
The carbonyl-olefin ring-closing metathesis reactions have become a powerful tool for carbon-carbon bond formation.In this work,the halogen bond catalysis and classical Lewis acid catalysis on the carbonyl-olefin ring...
关键词：Halogen bond donors Lewis acids Electrostatic interactions Orbital interaction Carbonyl-olefin ring-closing metathesis 
Tuning the Molecular Weight of Chlorine-Substituted Polymer Donors for Small Energy Loss被引量：2
《Chinese Journal of Chemistry》2021年第6期1651-1658,共8页Tingxing Zhao Huan Wang Mingrui Pu Hanjian Lai Hui Chen Yulin Zhu Nan Zheng Feng He 
the National Natural Science Foundation of China(51773087,21975115,21733005);the Shenzhen Fundamental Research program(JCYJ20180302180238419,JCYJ20190809163011543,KQJSCX20180319114442157);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Guangdong Innovative and Entrepreneurial Research Team Program(2016ZT06G587);Shenzhen Sci-Tech Fund(KYTDPT20181011104007);We also thank the SUSTech Core Research Facilities for the AFM and TEM measurements.
The molecular weight of polymers plays a major role in their aggregation and miscibility in active layer,which eventually dominate the energy loss and device performance.A series of chlorine-substituted PBD-CI polymer...
关键词：Molecular weight CHLORINE MISCIBILITY Energy loss Renewable resources 
Recent Advances in Wide Bandgap Polymer Donors and Their Applications in Organic Solar Cells被引量：5
《Chinese Journal of Chemistry》2021年第2期243-254,共12页Xiaopeng Xu Liyang Yu Qiang Peng 
This work was supported by the NSFC(21825502,22075190,21905185);the Foundation of State Key Laboratory of Polymer Materials Engineering(sklpme 2017-2-04);the Fundamental Research Funds for the Central Universities.
Organic solar cells(OSCs)have attracted wide research interests in the past decades.In recent years,our group mainly focused on the new photovoltaic materials design and device engineering technologies for highly effi...
关键词：Organic solar cells Energy conversion POLYMERS Donor-acceptor systems Wide bandgap donors 
Design and Application of Indole-Based Allylic Donors for Pd-Catalyzed Decarboxylative Allylation Reactions被引量：1
《Chinese Journal of Chemistry》2020年第12期1612-1618,共7页Qing-Qing Hang Si-Jia Liu Lei Yu Ting-Ting Sun Yu-Chen Zhang Guang-Jian Mei Feng Shi 
We are grateful for financial support from NSFC(Nos.21772069,21831007 and 21702077);the Natural Science Founda-tion of Jiangsu Province(No.BK20170227);Six Kinds of Talents Project of Jiangsu Province(No.SWYY-025).
of main observation and conclusion A new class of indole-based allylic donors have been designed and developed for palladium-catalyzed decarboxylative allylations.In addition,the first application of these indole-base...
关键词：palladium catalyzed ALLYL 
Conjugated Random Tpeoilymer Donors towards High-Efficiency Polymer Solar Cells被引量：3
《Chinese Journal of Chemistry》2020年第6期601-624,共24页Xuyu Gao Yijing Wu Youtian Tao Wei Huang 
the National Natural Science Foundation of China(Grant Nos.61761136013 and 91833304)for financial support;the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX19_0831)for financial support.
Over the past decades,polymer solar cells(PSCs)which contain conjugated polymers as electron donor and/or acceptor materials in active layers have achieved the power con version efficiency(PCE)over 17%.Among them,trem...
关键词：DONOR CONJUGATED MONOMER 
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