Complexes Cl-RuⅡ(dppe)2(Fe Cl4)·2CH2Cl2(2) and Br-RuII(dppe)2(Fe Br4)·2CH2Cl2(3) were prepared by the reaction of trans-RuII(dppe)2Cl2(1) with FeX 3(X = Cl, Br). More interestingly, the central Ru...
Supported by the National Natural Science Foundation of China (20573114);the MOST (2006DFA43020);Natural Science Foundation of Fujian Province (2006F3133)
Mixed-metal carbonyl clusters of W2Ir2(CO)10(η^5-C5H4Me)2 1 and W2Ir2(μ-L)(CO)8(η^5-C5H4Me)2 (L = dppe 2, dppf 3) have been studied by TDDFT method focusing on their electronic and nonlinear optical pro...