supported by the National Key R&D Program of China (2022YFA1503200);the National Natural Science Foundation of China (22371149, 22301144, 22188101);the Fundamental Research Funds for the Central Universities (63223015);the Frontiers Science Center for New Organic Matter, Nankai University (63181206);Nankai University;the Haihe Laboratory of Sustainable Chemical Transformations for financial support。
Electroreduction offers an alternative to generate high active intermediates from electrophiles(halides, alkenes, etc.) in organic synthesis. However, it still remains challenge to enable the transformations in contro...
supported by Council of Scientific and Industrial Research(CSIR);and New Delhi(02(0307)/17/EMR-II);University Grants Commission(UGC)(DSK)for his fellowship
A new visible-light-promoted oxidative coupling of vinylarenes with cyclic ethers has been developed using rose bengal as photocatalyst and tert-butyl hydrogenperoxide(TBHP)as oxidant under ambient air at room tempera...
Styrene(ST)is one of the most important chemicals in the world because of its widely applications in the syntheses of rubbers or thermoplastics.However,ST is mainly produced through catalytic dehydrogenation of ethylb...
supported by the Ministry of Science and Technology of China(2017YFA0206903);the National Natural Science Foundation of China(21871280,21861132004);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17000000);the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences(QYZDY-SSW-JSC029);K.C.Wong Education Foundation
Stiff-stilbene derivatives have been widely explored as molecular rotors, molecular force probes and optical switches with excellent performance. However, their function as fluorophores is poorly understood. In the pr...
supported by the US National Science Foundation (CHE-1566636);UCMEXUS-CONACYT Doctoral Fellowship
Cavity ring-down spectroscopy(CRDS)was utilized in combination with chemical titration with sulfur dioxide(SO_2)to quantify stabilized Criegee intermediates(s CIs)produced at low pressures(4–20 Torr)in ozonolysis rea...
Cationic polymerization of styrene has been achieved using several novel acidic initiators in room temperature ionic liquids (ILs) under mild reaction conditions to obtain polymers of low molecular weight with narrow ...
the National Natural Science Foundation of China (Grant Nos. 20374013 and 20674019);Program for New Century Excellent Talents in University (Grant No. NCET-04-0413);Science and Technology Commission of Shanghai Municipality (Grant Nos. 03JC14023 and 05DJ14005);"Shu Guang" Project of Shanghai Municipal Education Commission and Specialized Research Fund for the Doctoral Program of Higher Education (Grant No.20060251015)
The electron-withdrawing groups (EWGs) in the electrophilic alkenes employed in the Michael addition reaction are almost only CO2R, CN, COR, NO2, and SO2Ph. Although amides (CONR1R2) are also typical electron-withdraw...
The postulated intermediates in the base-free and base-assisted addition of OsO4 to styrene have been investigated at the B3LYP/6-311G** level of the theory. N(CH3)2(Ph) was chosen as the base of the resin-OsO4. Accor...
Project supported by the National Natural Science Foundation of China
1H NMR studies have been made on the effects of complexation of tweezer molecule (2s, 8s)-bis(2-naphthoyl aminomethyl)-1,5,9-triazabicyclo[4,4,0] dec-5-ene chloride with the salts of p-nitrobenzoate, p-methoxybenzoate...
The study on coordination copolymerization of styrene (S) with maleic anhydride (MA) by rare-earth coordination catalysts, NdL_3-Al(i-Bu)_3, has been successfully carried out for the first time. Some features, kinetic...