INTERMOLECULAR

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相关作者：李国华陈自立黄建滨阎云叶龙武更多>>
相关机构：北京大学厦门大学上海交通大学西南民族大学更多>>
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Dynamic Intermolecular Space for Reversible CO_(2)Capture and Release
《Chinese Journal of Chemical Physics》2025年第1期8-16,I0001-I0005,I0055,共15页Jin Zhou Yanan Wang Xiang Zhu Jin Zhao Hrvoje Petek Shijing Tan Bing Wang 
supported by the Innovation Program for Quantum Science and Technology(2021ZD0303302);the CAS Project for Young Scientists in Basic Research(YSBR-054);the National Natural Science Foundation of China(Nos.22425206,21972129);NSF grant CHE-2303197;the New Cornerstone Science Foundation.
Molecular constructs define the elementary units in porous materials for efficient CO_(2)capture.The design of appro-priate interpore and intermolecular space is crucial to stabilize CO_(2)molecules and maximize the c...
关键词：CO_(2)capture SELF-ASSEMBLY Intermolecular interactions Scanning tunneling microscopy 
Intermolecular reductive coupling of aliphatic ketones with alkynes and alkenes by BCN photocatalysts
《Science China Chemistry》2025年第1期181-185,共5页Yanping Xia Luyang Sun Jiajia Cheng Sibo Wang Meifang Zheng Xinchen Wang 
supported by the National Key Technologies R&D Program of China(2021YFA1502100);the National Natural Science Foundation of China(22071026,22372035,22072020,22302039,2247020090);the Science Foundation of the Fujian Province(2022HZ027004,2022L3082);the 111 Project(D16008)。
A photocatalytic process was developed for intermolecular reductive coupling of aliphatic ketones with alkynes/alkenes to furnish tertiary alcohols.Mechanistic studies support that boron carbonitrides(BCN)promote the ...
关键词：aliphatic ketones ketyl radical intermolecular cross-coupling tertiary alcohols 
π-Bridge mediated coupling between inter-and intra-molecular charge transfer in aggregates for highly efficient near-infrared emission
《Aggregate》2024年第6期340-351,共12页Jingyi Xu Jie Xue Yu Dai Jinyuan Zhang Jiajun Ren Chengyu Yao Shaman Li Qingyu Meng Xueliang Wen Haoyun Shao Juan Qiao 
National Key R&D Program of China,Grant/Award Number:2020YFA0715000;National Natural Science Foundation of China,Grant/Award Number:51773109。
Intermolecular charge transfer(inter-CT)is commonly considered to quench luminescence in molecular aggregates,especially for near-infrared(NIR)emission.Herein,by elaborate comparison ofπ-bridge effects in donor/accep...
关键词：intermolecular charge transfer molecular aggregates near-infrared emission organic light-emitting diodes thermally activated delayed fluorescence 
Ultralong thermally activated delayed fluorescence based on intermolecular charge transfer induced by isomer in carbazole derivative
《Aggregate》2024年第6期392-399,共8页Junru Chen Xianhe Zhang Zongliang Xie Bin Liu 
National University of Singapore,Grant/Award Number:A-0001423-06-00;The Singapore National Research Foundation,Grant/Award Number:A-0009163-01-00。
Ultralong thermally activated delayed fluorescence(UTADF)materials play an important role in realizing time-dependent color-tunable afterglow.Some typical carbazole(Cz)derivatives have been reported to exhibit UTADF p...
关键词：energy transfer intermolecular charge transfer ultralong organic phosphorescence ultralong thermally activated delayed fluorescence 
Intermolecular Acid-Base-Pairs Containing Poly(p-Terphenyl-co-lsatin Piperidinium)for High Temperature Proton Exchange Membrane Fuel Cells
《Energy & Environmental Materials》2024年第3期406-414,共9页Xiaofeng Hao Zhen Li Min Xiao Zhiheng Huang Dongmei Han Sheng Huang Wei Liu Shuanjin Wang Yuezhong Meng 
supported by the National Key Research and Development Program(2018YFA0702002);the National Key Research and Development Program(Japan-China Joint Research Program)(2017YFE0197900)
How to optimize and regulate the distribution of phosphoric acid in matrix,and pursuing the improved electrochemical performance and service lifetime of high temperature proton exchange membrane(HT-PEMs)fuel cell are ...
关键词：bifunctional copolymer high temperature proton exchange membrane intermolecular acid-base-pairs phosphonic acid retention phosphonic acid uptake level 
Molecule-based vertical transistor via intermolecular charge transport throughπ-πstacking
《Nano Research》2024年第5期4573-4581,共9页Cheng Liu Cheng Fu Lingyu Tang Jianghua Wu Zhangyan Mu Yamei Sun Yanghang Pan Bailin Tian Kai Bao Jing Ma Qiyuan He Mengning Ding 
support by the National Natural Science Foundation of China(Nos.22172075,92156024);the Fundamental Research Funds for the Central Universities in China(Nos.0210/14380174,14380273);Beijing National Laboratory for Molecular Sciences(No.BNLMS202107);Thousand Talents Plan of Jiangxi Province(No.jxsq2019102002);support by the National Natural Science Foundation of China(No.22033004);support from Early Career Scheme Project(No.21302821);General Research Fund Project(No.11314322)from the University Grants Committee of Hong Kong.
Theπ-πstacking is a well-recognized intermolecular interaction that is responsible for the construction of electron hopping channels in numerous conducting frameworks/aggregates.However,the exact role ofπ-to-πchan...
关键词：π-πstacking electrochemical intercalation organic semiconductor electrical transport tunneling field effect transistor 
Terminal-selective C(sp^(3))-H borylation of unbranched alkanes enabled by intermolecular radical sampling and LMCT photocatalysis
《National Science Review》2024年第5期89-91,共3页Zhexuan Lei Jie Wu 
The selective functionalization of C(sp^(3))–H bonds with subtle differences in alkanes is highly sought after due to its atom-and step-efficiency.The activation of C(sp^(3))–H bonds through hydrogen atom transfer(H...
关键词：BONDS ALKANES STERIC 
Ligand-dependent aggregation-enhanced photoacoustic of atomically precise metal nanocluster
《Aggregate》2024年第1期196-203,共8页Changlin Zhou Meng Wang Qiaofeng Yao Yu Zhou Chuantao Hou Jianfei Xia Zonghua Wang Jishi Chen Jianping Xie 
Natural Science Foundation of Shandong Province,Grant/Award Number:ZR2020MB063;Taishan Scholar Program of Shandong Province,Grant/Award Number:ts201511027。
Atomically precise metal nanoclusters(MNCs),as a potential type of photoacoustic(PA)contrast agent,are limited in application due to their low PA conversion efficiency(PACE).Here,with hydrophilic Au25SR18(SR=thiolate)...
关键词：aggregation-enhanced photoacoustic gold nanocluster intermolecular excited state energy transfer intramolecular motion ligand effect 
Rh(Ⅱ)-catalyzed intermolecular carboamination of pyridines via double Csp^(2)-H bond activations
《Science China Chemistry》2024年第1期374-382,共9页Zhongfeng Luo Jingxing Jiang Lifang Zou Xiaoyu Zhou Junshan Liu Zhuofeng Ke Fengjuan Chen Huanfeng Jiang Wei Zeng 
supported by the National Natural Science Foundation of China(22271100,21973113);the Key-Area Research and Development Program of Guangdong Province(2020-B010188001);the Guangdong Basic and Applied Basic Research Foundation(2023A1515010070);the China Postdoctoral Science Foundation(2021M701243)。
We disclose the development of the Rh-catalyzed amine-directed remote 5,6-carboamination protocol of pyridines via dual Csp^(2)-H functionalizations.A variety of readily available 2-aminopyridines and 1,2,3-triazoles ...
关键词：Rh-catalysis AZAINDOLES pyridyl Csp^(2)-H bond carboamination coupling-cyclization 
Self-assembly of partially oxidized pillar[5]arenes induced by intermolecular charge transfer interactions
《Chinese Chemical Letters》2023年第12期220-224,共5页Shuai Cao Leqian Song Huacheng Zhang Jie Han Yanli Zhao 
support from the“Young Talent Support Plan”(No.050700-71240000000046)of Xi'an Jiaotong University and Natural Science Foundation of Shaanxi Province(No.2021JM-006);J.Han acknowledges the 111 Project(No.B12015).
Supramolecular interactions such as t-stacking interaction and charge transfer interaction have drawn much attention in the design and construction of various supramolecular assemblies.Herein,partially oxidized pillar...
关键词：Charge transfer Pillararenes SELF-ASSEMBLY Supramolecular chemistry Theoretical calculations 
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