Project supported by the National Natural Science Foundation of China (No. 20271036), the Natural Science Foundation of Jiangsu Province (No. BK2004205), the Natural Science Foundation of the Education Committee of Jiangsu Province (No. 03KJD 150241 ), and the Key Laboratory of 0rganic Synthesis of Jiangsu Province (No. JSK001 ) in China.
Reaction of a preformed cluster (Et4N)2[MoS4(CuCN)2]·H2O(1) with acetic acid in MeCN gave rise to an interesting 2D polymeric cluster (Et4N)3 {[MoS4Cu2(μ-CN)]2(μ^1-CN)}·2MeCN (2). Compound 2 was char...
granted by NNSFC(No.29733090,39970177 and 29973047).
Complex (Et4N) [VFe3S4Cl3 (CH3CN)(3)] (1) has been obtained from (NH4)(3) VS4/FeCl2/NaHS/Et-4 NCl reaction system in CH3CN solvent and structurally characterized by X-ray diffraction analysis. It crystallizes in ortho...
Et4N)2pd(i-mnt)2.fw = 647. 04, monoclinic,space group P21/c;a =9.511(1), b = 11.612(2), c=14.820(3)A,g= 94.38(1)',I'= 1631.9(5)A;7=2' D.=1.32g.cnl-;F (000)=672, R=0 0324, R. = 0'0298.Tills is a new e,\alil[)le ot' X-r...
A hexamolybdenum complex, [Et_4N]_2[Mo_6O_(19)H_4] crystal, with pentavalent and hexavalent molybdenum has been obtained in the solution of DMF and CH_3OH as organic solvents using MoCl_5 as a starting material. The c...