Chirality is ubiquitous in many fields such as biology,pharmacology,chemistry,and physics.It therefore is of great significance to research on chirality generation,chirality transfer,and chirality amplification effect...
the financial support of the Department of Science and Technology of Inner Mongolia (No.2020GG0192);Grassland Talents (No. CYYC10031);Inner Mongolia Normal University (No. 112/1004031962);the financial support of Collaborative Innovation Center for Water Environment Security of Inner Mongolia Autonomous Region,China (No. XTCX003)。
Quaternary approach has been receiving more and more attention due to its effectiveness in improving solar cell performance, while synthesis/selection of the fourth component is yet a key issue. Herein, we report a ch...
supported by the National Science Foundation of China (Nos. 51522308, 21421061);Chinese Academy of Sciences(No.QYZDB-SSW-SLH025)
Self-assembly of homo-polymers has rarely been reported. Herein, PAA-NH_4 assemblies varying from nanospheres to large particles and yolk-shell vesicles were obtained by adding different amount of HCI solution into th...
the National Natural Science Foundation of China(No. 21302095);Research Fund for the Doctoral Program of Higher Education of China(No. 20133221120003);Jiangsu Provincial NSFC(Nos. BK20130945, BK20130924);Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP);Nanjing Tech University for financial support
The nucleophilic ring opening reaction of propargyl epoxides by amines based on a silver catalyst is presented, The reaction takes place under mild conditions and features a high regioselectivity to provide an effecti...
National Natural Science Foundation of China (Nos. 21002041 and 21262014);Natural Science Foundation of Jiangxi Province (No. 20114BAB203008);Project of the Science Funds of Jiangxi Education Office (No. GJJ12589);Key Project of Chinese Ministry of Education (No. 212092);Scientific Research Foundation of Chinese Ministry of Human Resources and Social Security for Returned Chinese Scholars for financial support
The triphosphates and homodinucleotides of AZT and d4T have been efficiently synthesized from the corresponding nucleoside 5-H-phosphonate monoesters via the reactive pyridinium phosphoramidate intermediates.
the National Natural Science Foundation of China(Nos20772025 and 20972042);Innovation Scientists and Technicians Troop Construction Projects of Henan Province(No104100510019);Natural Science Foundation of Henan Province(No092300410237);the Natural Science Foundation of Department of Education of Henan Province(Nos2009A150017 and 2008A150013)
A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones.The advantag...
N-Phosphoryl peptide libraries were constructed by transformation from homo-oligopeptide libraries, which was synthesized by self-assembly of amino acids with the assistance of phosphorus oxychloride. Electrospray ion...
Semiempirical quantum chemical method AM1 was employed to calculate the highest occupied molecular orbital (HOMO) energy levels (E-HOMO) for various types of antioxidants. It was verified that the correlation between ...
Chemically, N-phosphoryl homo-serine was much more stable than the homologous compound phosphorylated serine. The latter was very reactive to undergo N -->O migration, formation of peptide and cyclophosphoroamidate bu...
The frontier orbitals HOMO and LUMO of the fullerene C_(60) has been given in a system of 60 motion-coordinates, of which each origin is at each C atom of fullerene C_(60) and each z-axis is in the direction perpendic...