气相色谱-质谱法测定食品用纸制品中五氯酚含量  

Determination of pentachlorophenol by gas chromatography mass spectrometry in paper packaging materials for foodstuffs

作　　者：云鹏[1] 刘印平[1] 路杨[1] 陈福尊[1] 王丽英[1] YUN Peng;LIU Yin-Ping;LU Yang;CHEN Fu-Zun;WANG Li-Ying(Hebei Provincial Center for Disease Control and Prevention,Shijiazhuang 050021,China)

机构地区：[1]河北省疾病预防控制中心,石家庄050021

出　　处：《食品安全质量检测学报》2021年第5期1699-1704,共6页Journal of Food Safety and Quality

摘　　要：目的建立气相色谱-质谱法测定食品用纸制品中五氯酚含量的分析方法,了解食品用纸制品中五氯酚的残留状况。方法纸制品试样加入2,4,6-三溴酚内标后,经液-液萃取, SLC柱净化,乙酸酐-吡啶溶液衍生后,采用气相色谱-质谱法测定,内标法定量。结果在50~1000ng范围内,相关系数均>0.9995。方法的检出限为0.008mg/kg,定量限为0.025mg/kg。加标回收率为89.3%~109.8%,相对标准偏差(relativestandard deviations, RSDs)分别为3.2%、8.6%和4.4%。106份市售纸制品中, 8份样品检出五氯酚,阳性率为7.5%,含量范围为0.011~0.045 mg/kg,阳性样品五氯酚含量的平均值为0.027 mg/kg。结论该方法灵敏度较高,精密度好,适用于纸制品中五氯酚的准确定量检测。检测数据表明,食品用纸制品中五氯酚风险较小。Objective To establish an analytical method for the determination of pentachlorophenol in food paper products by gas chromatography-mass spectrometry.Methods After adding 2,4,6-tribromophenol internal standard to paper products,the samples were extracted by liquid-liquid extraction,purified by SLC column,and derivatized by acetic anhydride pyridine solution.The samples were determined by gas chromatography-mass spectrometry,and quantified by internal standard method.Results The correlation coefficients were over 0.9995 in the range of 50‒1000 ng.The limit of detection was 0.008 mg/kg and the limit of quantification was 0.025 mg/kg.The recoveries were 89.3%‒109.8%,and the relative standard deviations(RSDs)were 3.2%,8.6%and 4.4%,respectively.Pentachlorophenol was detected in 8 samples of 106 paper products,and the positive rate was 7.5%.The content range was 0.011‒0.045 mg/kg,and the average content of pentachlorophenol was 0.027 mg/kg.Conclusion The method has high sensitivity and good precision,and is suitable for the accurate quantification of pentachlorophenol in paper products.The test data showed that the risk of pentachlorophenol in food paper products was low.

关 键 词：五氯酚 食品用纸制品 衍生 内标法 气相色谱-质谱法 

分 类 号：O657.63[理学—分析化学] TS201.6[理学—化学] TS77[轻工技术与工程—食品科学]