国家自然科学基金(20925104)

作品数:4被引量:5H指数:1
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相关作者:蒋其柏燕红丁冠宇解铭时季一飞更多>>
相关机构:南京大学上饶师范学院更多>>
相关期刊:《Science China Chemistry》《无机化学学报》更多>>
相关主题:碳硼烷CHELATINGALKYNONESO-CARBORANEHALF-SANDWICH更多>>
相关领域:理学更多>>
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含碳硼烷膦氧配体镍、铱化合物的合成与表征被引量:1
《无机化学学报》2013年第5期910-914,共5页蒋其柏 季一飞 沈旭杰 燕红 
国家自然科学基金(No.20925104,21271102,21021062)资助项目
碳硼烷双膦配体L1分别与三苯基膦氯化镍(NiCl2(PPh3)2)和1,5-环辛二烯氯化铱(IrCl(COD))在空气中反应生成含巢式碳硼烷膦氧配体的镍、铱化合物1和2。本文对此两个化合物进行了核磁、质谱、红外及单晶衍射等表征。化合物1中溶剂分子氯仿...
关键词:碳硼烷   膦氧二齿配体 
Study on specific interaction of new ferrocene-substituted carborane conjugates with hemoglobin protein被引量:1
《Science China Chemistry》2012年第4期594-603,共10页WU ChunHui1,3, YE HongDe2, JIANG Hui1, WANG XueMei1 & YAN Hong2 1State Key Lab of Bioelectronics (Chien-Shiung Wu Lab), Southeast University, Nanjing 210096, China 2State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China 3School of Life Science and Technology, University of Electronic Science and Technology of China, Chengdu 610054, China 
supported by the National Basic Research Program of China (2010CB732404, 2010CB923303);the National Natural Science Foundation of China (21175020, 90713023, 20925104);the Project of High Technology Research and Development Program of China (2007AA022007);Gongdong Province (2011B090400357);the Natural Science Foundation of Jiangsu Province (BK2008149, BK2010052);C. W. acknowledges the Fundamental Research Funds for the Central Universities (ZYGX2011J099);the support by the Open Research Fund of State Key Laboratory of Bioelectronics, Southeast University (2011E09)
The interactions between the new organometallic complexes, ferrocenesubstituted dithioocarborane conjugates (denoted as FcSB1, FcSB2 and FcSBCO) and hemoglobin (Hb) are investigated by electrochemistry, fluorescen...
关键词:fluorescence  UV vis absorption spectroscopy  differential pulse voltammetry  biomolecular interaction  ferrocene substituted carborane conjugates  hemoglobin 
半夹芯16电子化合物CpCo(S_2C_2B_(10)H_(10))中B(3,6)位的选择性分步取代反应(英文)被引量:1
《无机化学学报》2011年第8期1601-1606,共6页叶红德 蒋其柏 解铭时 丁冠宇 李一志 燕红 
国家自然科学基金(No.20925104、21021062);国家基础研究计划(No.2007CB925101、2010CB923303);江苏省自然科学基金(No.BK2010052);教育部博士点基金(No.20090091110015)资助项目
16e半夹芯化合物CpCo(S2C2B10H10)(Cp:cyclopentadienyl)(1)与炔烃HC≡CC(O)Fc(Fc:ferrocenyl)在物质的量之比为1∶1时反应生成化合物CpCo(S2C2B10H9)(CH=CHC(O)Fc)(2)。在化合物2中,一分子HC≡CC(O)Fc偶合到原料化合物1的碳硼烷笼子的B...
关键词:过渡金属 碳硼烷 B-H键活化 晶体结构 
Reactions of a 16-electron Cp*Co half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand with alkynones HC≡C-C(O)R (R=OMe,Me,Ph)被引量:2
《Science China Chemistry》2010年第10期2129-2138,共10页GUOYIQIBAYI Gulnisa 
the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303)
The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...
关键词:ortho-carborane DITHIOLATE alkynone cobalt complex HALF-SANDWICH crystal structure 
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