supported by the National Basic Research Program of China (2010CB732404, 2010CB923303);the National Natural Science Foundation of China (21175020, 90713023, 20925104);the Project of High Technology Research and Development Program of China (2007AA022007);Gongdong Province (2011B090400357);the Natural Science Foundation of Jiangsu Province (BK2008149, BK2010052);C. W. acknowledges the Fundamental Research Funds for the Central Universities (ZYGX2011J099);the support by the Open Research Fund of State Key Laboratory of Bioelectronics, Southeast University (2011E09)
The interactions between the new organometallic complexes, ferrocenesubstituted dithioocarborane conjugates (denoted as FcSB1, FcSB2 and FcSBCO) and hemoglobin (Hb) are investigated by electrochemistry, fluorescen...
the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303)
The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...